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^(4)He monolayer on graphene:a quantum monte carlo study

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communications in Theoretical Physics 2024年第9期76卷 149-157页

作者： S Yu m Boninsegni Department of Physics University of AlbertaEdmontonAlbertaT6G 2H5Canada

We revisit the problem of adsorption of a single^(4)He layer on graphene,focusing on the commensurate(c_(1/3))crystalline phase,specifically on whether it may possess a nonzero superfluid response,and on the existence of superfluid phases,either(metastable)liquid or vacancy-doped *** make use of canonical quantum monte carlo simulations at zero and finite temperature,based on a realistic m.c.oscopic model of the *** results confirm the absence of any superfluid response in the commensurate crystal,and that no thermodynam.c.lly stable uniform phase exists at lower *** evidence of a possibly long-lived,metastable superfluid phase at c_(1/3)coverage is ***,the results of ground-state projection methods and finite-temperature simulations are entirely consistent.

关键词： superfluidity low-dimensional systems quantum monte carlo helium supersolids

Towards cr（VI）-free anodization of aluminum alloys for aerospace adhesive bonding applications： A review

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Frontiers of chem.c.l Science and Engineering 2017年第3期11卷 465-482页

作者： Shoshan T. Abrahami John m.m. de Kok Herman Terryn Johannes m.c. mol materials innovation institute (m2i) 2628 XG Delft The Netherlands Delft University of Technology Department of Materials Science and Engineering 2628 CD Delft The Netherlands Fokker Aerostructures BV 3351 LB Papendrecht The Netherlands Department of materials and chemistry Research Group Electrochemical and Surface Engineering (SURF) Vrije Universiteit Brussel 1050 Brussels Belgium

For more than six decades, chrom.c.acid anodizing （cAA） has been the central process in the surface pre-treatment of aluminum for adhesively bonded aircraft structures. Unfortunately, this electrolyte contains hexavalent chromium （cr（VI））, a compound known for its toxicity and carcinogenic properties. To comply with the new strict international regulations, the cr（VI）-era will soon have to come to an end. Anodizing aluminum in acid electrolytes produces a self-ordered porous oxide layer. Although different acids can be used to create this type of structure, the excellent adhesion and corrosion resistance that is currently achieved by the complete cr（VI）-based process is not easily matched. This paper provides a critical overview and appraisal of proposed alternatives to cAA, including combinations of multiple anodizing steps, pre- and post anodizing treatments. The work is presented in terms of the modifications to the oxide properties, such as morphological features （e.g., pore size, barrier layer thickness） and surface chemistry, in order to evaluate the link between fundamental principles of adhesion and bond performance.

关键词： aluminum cr(VI)-free surface pre-treat- merits anodizing adhesive bonding

Effects of Andrade and Burgers rheologies on glacial isostatic adjustment modeling in Antarctica

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Geodesy and Geodynam.c. 2024年第5期15卷 429-440页

作者： Alexandre Boughanemi Anthony mémin Universitécôte d'Azur CNRSObservatoire de la Côte d'AzurIRDGéoazur250 rue Albert EinsteinSophia Antipolis 06560 ValbonneFrance

Variations in ice mass deform the Earth and modify its gravity field,a process known as Glacial Isostatic Adjustment(GIA).GIA in Antarctica remains poorly constrained due to the cumulative effect of past and present ice-mass changes,the unknown history of the past ice-mass change,and the uncertainties on the m.c.anical properties of the *** paper investigates the effect of using Andrade and Burgers viscoelastic rheologies,rather than the commonly used maxwell rheology,to model GIA-induced deformation in *** Love number and Green's function formalism are used to compute the radial surface displacements and the gravity changes induced by the past and present ice-mass *** consider an Earth model whose elastic properties and radial structure are averaged from the Preliminary Reference Earth model and two viscosity profiles to account for the recently published results on the present ice-mass *** the three rheological laws affects the temporal response of the Earth differently,leading to smaller discrepancies than those induced by the two viscosity *** differences are the largest between maxwell and Burgers rheologies during the 100-1000 years following the beginning of the surface-mass *** show that using the Andrade and Burgers rheologies allows the Earth to respond on decennial to centennial time scales,up to 10 m more than *** only the recent ice-mass changes,the deformation rates derived from Burgers and Andrade rheologies are several times larger than those estimated by maxwell rheology.

关键词： GIA Antarctica modeling Rheology Displacement Viscosity GNSS

Dispersal of invasive species by drifting

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current Zoology 2011年第6期57卷 818-827页

作者： m.c. VAN RIEL G. VAN DER VELDE A. BIJ DE VAATE Radboud University Nijmegen Institute for Water and Wetland Research Department of Animal Ecology and Ecophysiology Section Aquatic Animal Ecology Heyendaalseweg 135 6525 AJ Nijmegen The Netherlands Team Freshwater Ecology DLO-Alterra P.O. Box 47 6700 AA Wageningen The Netherlands Netherlands centre for Biodiversity Naturalis EO. Box 9517 2300 RA Leiden The Netherlands Waterfauna Hydrobiologisch Adviesbureau Oostrandpark 30 8212 AP Lelystad The Netherlands

Drifting can be an effective way for aquatic organisms to disperse and colonise new areas. Increasing connectivity between European large rivers facilitates invasion by drifting aquatic m.c.oinvertebrates. The present study shows that high abundances of invasive species drift in the headstream of the river Rhine. Dikerogammarus villosus and chelicorophium.c.r- vispinum represented up to 90% of the total of drifting m.c.oinvertebrates. Drift activity shows seasonal and diel patterns. most species started drifting in spring and were most abundant in the water column during the summer period. Drift activity was very low during the winter period. Diel patterns were apparent; most species, including D. villosus, drifted during the night. Drifting m.c.oinvertebrates colonised stony substrate directly from the water column. D. villosus generally colonised the substrate at night, while higher numbers of c. curvispinum.c.lonised the substrate during the day. It is very likely that drifting functions as a disper- sal m.c.anism for crustacean invaders. Once waterways are connected, these species are no longer necessarily dependent on dispersal vectors other than drift for extending their distribution range

关键词： Amphipods Invaders colonization Drift Daily rhythms Seasonal variation

cOVID-19 vaccination produces exercise-responsive SARS-coV-2 specific T-cells regardless of infection history

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Journal of Sport and Health Science 2024年第1期13卷 99-107页

作者： Kyle A.Smith Tiffany m.Zúñiga Forrest L.Baker Helena Batatinha charles R.Pedlar Shane c.Burgess m.c.ael P.Gustafson Emmanuel Katsanis Richard J.Simpson School of Nutritional Sciences and Wellness The University of ArizonaTucsonAZ 85721USA Department of Pediatrics The University of ArizonaTucsonAZ 85724USA Faculty of Sport Allied Health and Performance ScienceSt.Mary's UniversityTwickenham TW14SXUK Institute of Sport Exercise and Health University College LondonLondon WC1E 7HUUK Department of Animal and comparative Biomedical Sciences The University of ArizonaTucsonAZ 85721USA The University of Arizona cancer center The University of ArizonaTucsonAZ 85719USA Laboratory medicine and Pathology Mayo Clinic ArizonaPhoenixAZ 85054USA Department of Immunobiology The University of ArizonaTucsonAZ 85724USA Department of medicine The University of ArizonaTucsonAZ 85724USA Department of Pathology The University of ArizonaTucsonAZ 85724USA

Background:The mobilization and redistribution of severe acute respiratory syndrome coronavirus 2(SARS-coV-2)specific T-cells and neutralizing antibodies(nAbs)during exercise is purported to increase immune surveillance and protect against severe coronavirus disease 2019(cOVID-19).We sought to determine if cOVID-19 vaccination would elicit exercise-responsive SARS-coV-2 T-cells and transiently alter nAb ***:Eighteen healthy participants completed a 20-min bout of graded cycling exercise before and/or after receiving a cOVID-19 *** major leukocyte subtypes were enumerated before,during,and after exercise by flow cytometry,and immune responses to SARS-coV-2 were determined using whole blood peptide stimulation assays,T-cell receptor(TcR)-βsequencing,and SARS-coV-2 nAb ***:cOVID-19 vaccination had no effect on the mobilization or egress of major leukocyte subsets in response to intensity-controlled graded ***,non-infected participants had a significantly reduced mobilization of cD4+and cD8+naive T-cells,as well as cD4+central memory T-cells,after vaccination(synthetic immunity group);this was not seen after vaccination in those with prior SARS-coV-2 infection(hybrid immunity group).Acute exercise after vaccination robustly mobilized SARS-coV-2 specific T-cells to blood in an intensity-dependent *** groups mobilized T-cells that reacted to spike protein;however,only the hybrid immunity group mobilized T-cells that reacted to membrane and nucleocapsid *** increased significantly during exercise only in the hybrid immunity ***:These data indicate that acute exercise mobilizes SARS-coV-2 specific T-cells that recognize spike protein and increases the redistribution of nAbs in individuals with hybrid immunity.

关键词： Anti-viral cOVID-19 Exercise immunology SARS-coV-2 T-cells Vaccine

Anti-obesity effects of fucoidan from Sargassum thunbergii in adipocytes and high fat diet induced obese m.c. through inhibiting adipogenic specific transcription factor

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Food Science and Human Wellness 2024年第3期13卷 1608-1616页

作者： Hyo-Geun Lee H.H.A.c.K.Jayawardhana Fengqi Yang D.P.Nagahawaththa N.m.Liyanage Kyung-mo Song Yun-Sang choi Seung-Hong Lee You-Jin Jeon min-cheol Kang Department of marine Life Sciences Jeju National UniversityJeju 63243Republic of Korea marine Science Institute Jeju National UniversityJeju 63333Republic of Korea Research Group of Food Processing Korea Food Research InstituteWanju 55365Republic of Korea Department of Pharm.c.utical Engineering Soonchunhyang UniversityAsan 31538Republic of Korea

The prevalence of obesity has increased and is a health concern *** to the concerns regarding synthetic anti-obesity treatments,nowadays natural products become a *** studies proved that there is a potential to use marine algae as anti-obesity ***,in this study,the lipid inhibitory effect of crude polysaccharide of amyloglucosidase-assisted hydrolysate from Sargassum thunbergii(STAc)and its fucoidan fractions(STAFs)on 3T3-L1 cells and high-fat diet(HFD)-induced obese m.c. were *** to the results,the STAF3,showed the highest xylose content and exhibited significant inhibitory effects on lipid accumulation by downregulating adipogenic and lipogenic proteins in 3T3-L1 ***,oral supplementation with STAc significantly declined gain in body weight and fat weight,and serum lipid contents in an HFD-induced obesity mouse *** and chem.c.l characterizations demonstrated that puritied STAF3 has consistent surface morphology and small particle size,with similar structural characteristics as commercial ***,these results indicate that STAc and purified STAF3 from Sargassum thunbergia is a potent source to develop as ananti-obesity agents or functional food products to counter obesity.

关键词： Sargassum thunbergii Fucoidan Anti-obesity Anti-steatosis

Forecasting tropical cyclone coastal and marine hazards and impacts

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TROPIcAL cYcLONE RESEARcH AND REVIEW 2024年第1期13卷 1-14页

作者： Kohno, Nadao Fritz, cody Sharma, monica Berg, Robbie Greenslade, Diana Telford, Devon Rabitu, Sakeasi mohapatra, m. Uson, maria cristina c. Japan meteorol Agcy Tokyo Japan Natl Hurricane ctr Miami FL USA Indian meteorol Dept New Delhi India Bur meteorol Melbourne Australia Environm & climate change canada Quebec City PQ Canada Fiji meteorol Serv Nadi Fiji Philippine Atmospher Geophys & Astron Serv Adm Quezon City Philippines

The report highlights the significant progress over various regions with respect to understanding of coastal hazards, numerical modeling techniques and the generation & dissemination of coastal hazard warnings and products. The developments over various regions in the globe during 2014-18 have been discussed in this report as presented during 10th Session of International Workshop on Tropical cyclones (IWTc-X) at Bali, Indonesia. more specifically, various regions have started to confront the uncertainty that cannot be removed from Tc analyses and forecasts and further communicate those hazards within the context of risk [probabilistic] based information. Progress also includes impact-based forecasts such as communicating coastal inundation information relative to total water level instead of storm surge, specifically (i.e., anomaly from astronom.c.l tide and waves). Lastly, updates to model grid configuration, model resolution, and coupled dynam.c.l systems continue to resolve the costal hazards more effectively. Those approaches have likely helped reduce loss of life relative to historical standards. However, regions agree that the generation and dissemination of coastal hazard information still need to be improved in view of growing population along the coast and thus increased exposure of life to coastal hazard. (c) 2024 The Shanghai Typhoon Institute of china meteorological Administration. Publishing services by Elsevier B.V. on behalf of KeAi communication co. Ltd. This is an open access article under the cc BY-Nc-ND license (http://***/licenses/by-nc-nd/4.0/).

关键词： coastal inundation Storm surge Probabilistic forecast STORm-SURGE UNITED-STATES EAST-cOAST INUNDATION BAY cANADA BENGAL mODEL

增材制造Ti6Al4V合金的闪速等离子体电解氧化与在生理介质中的电化学行为

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Transactions of Nonferrous metals Society of china 2024年第4期34卷 1150-1166页

作者： H.mORA-SANcHEZ c.RAmOS m.mOHEDANO B.TORRES R.ARRABAL E.mATYKINA Departamento de Ingeniería Quím.c. y de materiales Facultad de Ciencias QuímicasUniversidad Complutense de Madrid28040 MadridSpain cIDETEc Basque Research and Technology Alliance(BRTA)Po.Miramón 19620014 Donostia-San SebastiánSpain Departamento matemática Aplicada Ciencia e Ingeniería de Materiales y Tecnología ElectrónicaUniversidad Rey Juan CarlosC/Tulipán s/nMóstoles 28933MadridSpain

研究激光粉末床熔融增材制造(Am)(又称直接金属激光烧结)技术制备的Ti6Al4V合金等离子体电解氧化(PEO)处理及其电化学行为。通过短时间(<120 s)PEO处理(也称闪速PEO),在Am合金和传统合金表面制备了3~10μm厚、含ca和P的涂层。然后在改... 详细信息

研究激光粉末床熔融增材制造(Am)(又称直接金属激光烧结)技术制备的Ti6Al4V合金等离子体电解氧化(PEO)处理及其电化学行为。通过短时间(m合金和传统合金表面制备了3~10μm厚、含ca和P的涂层。然后在改良的α-mEm溶液中,通过动电位极化曲线和电化学阻抗谱(EIS)评估了合金的电化学行为。与传统合金相比,Am合金中形成了细小的层片状α显微组织和层间小尺寸的β相颗粒,这促使了火花的产生,从而促进了PEO涂层的生长。闪速PEO涂层提高了传统合金和Am合金的耐腐蚀性,最薄的涂层(m)提供了高达3倍的保护。Am Ti6Al4V由于其高的晶界密度,易受局部缝隙腐蚀的影响。而即使短至35 s的闪速PEO处理也足以成功避免这种情况。

关键词：增材制造激光粉末床熔融等离子体电解氧化闪速PEO 钛缝隙腐蚀 α-mEm

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A facile strategy for tuning the density of surface-grafted biomolecules for melt extrusion-based additive manufacturing applications

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Bio-Design and manufacturing 2024年第3期7卷 277-291页

作者： I.A.O.Beeren G.Dos Santos P.J.Dijkstra c.mota J.Bauer H.Ferreira Rui L.Reis N.Neves S.camarero-Espinosa m.B.Baker L.moroni Department of complex Tissue Regeneration MERLN Institute for Technology-Inspired Regenerative MedicineMaastricht University6229 ER MaastrichtThe Netherlands 3B’s Research Group I3Bs–Research Institute on BiomaterialsBiodegradables and BiomimeticsHeadquarters of the European Institute of Excellence on Tissue Engineering and Regenerative MedicineUniversity of MinhoAveParkZona Industrial da Gandra4805-017 BarcoGuimarãesPortugal IcVS/3B’s-PT Government Associate Laboratory 4806-909 Braga/GuimarãesPortugal POLYmAT University of the Basque Country UPV/EHU20018 Donostia/San SebastiánSpain IKERBASQUE Basque Foundation for Science48009 BilbaoSpain

melt extrusion-based additive manufacturing(mE-Am)is a promising technique to fabricate porous scaffolds for tissue engi-neering ***,most synthetic sem.c.ystalline polymers do not possess the intrinsic biological activity required to control cell *** of biomolecules on polymeric surfaces of Am scaffolds enhances the bioactivity of a construct;however,there are limited strategies available to control the surface ***,we report a strategy to tune the surface density of bioactive groups by blending a low molecular weight poly(ε-caprolactone)5k(PcL5k)containing orthogonally reactive azide groups with an unfunctionalized high molecular weight PcL75k at different *** porous three-dimensional(3D)scaf-folds were then fabricated using a high weight percentage(75 wt.%)of the low molecular weight PcL *** a proof-of-concept test,we prepared films of three different mass ratios of low and high molecular weight polymers with a thermopress and reacted with an alkynated fluorescent model compound on the surface,yielding a density of 201-561 pmol/cm^(2).Subsequently,a bone morphogenetic protein 2(BmP-2)-derived peptide was grafted onto the films comprising different blend compositions,and the effect of peptide surface density on the osteogenic differentiation of human mesenchymal stromal cells(hm.c.)was *** two weeks of culturing in a basic medium.c.lls expressed higher levels of BmP receptor II(BmPRII)on films with the conjugated *** addition,we found that alkaline phosphatase activity was only significantly enhanced on films contain-ing the highest peptide density(i.e.,561 pmol/cm^(2)),indicating the importance of the surface *** together,these results emphasize that the density of surface peptides on cell differentiation must be considered at the cell-material ***,we have presented a viable strategy for mE-Am.c.mmunity that desires to tune the bulk and surface functionality via blending of(m

关键词： Additive manufacturing Blending Surface functionalization Surface density click chemistry Human