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Molecular Dynamics Simulation Studies on the Micromorphology and Proton Transport of Nafion/Ti_(3)C_(2)T_(x) Composite Membrane

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Chinese Journal of Polymer Science 2024年第3期42卷 373-387,I0009页

作者： Zhi-Yue Han su-Peng Pei chun-Yang Yu Yong-Feng Zhou School of Chemical and Environmental Engineering Shanghai Institute of TechnologyShanghai 201418China School of Chemistry&Chemical Engineering Frontiers Science Center for Transformative MoleculesShanghai Key Laboratory of Electrical Insulation and Thermal AgingShanghai Jiao Tong UniversityShanghai 200240China Key Laboratory of Green and High-end Utilization of Salt Lake Resources Chinese Academy of SciencesXining 810008China

The perfluorosulfonic acid(PFSA) membrane doped with two-dimensional conductive filler Ti_(3)C_(2)T_(x) is a fuel cell proton exchange membrane with high application potential. Experimental studies showed that the proton conductivity of Nafion/Ti_(3)C_(2)T_(x) composite membrane is improved significantly compared with that in pure Nafion. However, the microscopic mechanism of doping on the enhancement of membrane performance is remain unclear now. in this work, molecular dynamics simulation was used to investigate the microscopic morphology and proton transport behaviors of Nafion/Ti_(3)C_(2)T_(x) composite membrane at the molecular level. The results shown that there were significant differences about the diffusion kinetics of water molecules and hydroxium ions in Nafion/Ti_(3)C_(2)T_(x) at low and high hydration levels in the nanoscale *** the increase of water content, Ti_(3)C_(2)T_(x) in membrane was gradually surrounded by ambient water molecules to form a hydration layer, and forming a relatively continuous proton transport channel between Nafion polymer and Ti_(3)C_(2)T_(x) monomer. The continuous proton transport channel could increase the number of binding sites of proton and thus achieving high proton conductivity and high mobility of water molecules at higher hydration level. The current work can provide a theoretical guidance for designing new type of Nafion composite membranes.

关键词： Nafion/Ti_(3)C_(2)T_(x)composite membrane Proton transport Molecular dynamics simulation

Pulsations of Three Rapidly Oscillating Ap Stars TiC 96315731,TiC72392575,and TiC 318007796

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Research in Astronomy and Astrophysics 2024年第8期24卷 157-168页

作者： Hai-Jian Zhong Dong-Xiang Shen chun-Hua Zhu He-Lei Liu su-Fen Guo Guo-Liang Lü School of Physical Science and Technology Xinjiang UniversityUrumqi 830046China Xinjiang Astronomical Observatory National Astronomical ObservatoriesChinese Academy of SciencesUrumqi 830000China

We analyze the frequencies of three known roAp stars,TiC 96315731,TiC 72392575,and TiC 318007796,using the light curves from the Transiting Exoplanet survey *** TiC 96315731,the rotational and pulsational frequencies are 0.1498360 day^(-1)and 165.2609 day^(-1),*** the case of TiC 72392575,the rotational frequency is 0.25551 day^(-1).We detect a quintuplet of pulsation frequencies with a center frequency of135.9233 day^(-1),along with two signals within the second pair of rotational sidelobes of the quintuplet separated by the rotation *** two signals may correspond to the frequencies of a dipole *** TiC318007796,the rotational and pulsational frequencies are 0.2475021 day^(-1),192.73995 day^(-1),and196.33065 day^(-1),*** on the oblique pulsator model,we calculate the rotation inclination(i)and magnetic obliquity angle(b)for the stars,which provide the geometry of the pulsation *** the phases of the frequency quintuplets,the pulsation amplitude and phase modulation curves,and the results of spherical harmonic decomposition,we conclude that the pulsation modes of frequency quintuplets in TiC96315731,TiC 72392575,and TiC 318007796 correspond to distorted dipole mode,distorted quadrupole mode,and distorted dipole mode,respectively.

关键词： asteroseismology-techniques photometric-stars oscillations(including pulsations)-stars chemically peculiar

Two polyoxovanadoborates with over 100 nuclei assembled from a {V_(14)Co_(12)B_(72)} cluster

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Science China Chemistry 2024年第8期67卷 2578-2585页

作者： Shuang-Xue Wu Yu-Jiao Dong Yang Yang Chao Qin chun-Yi sun Wei Guan Xin-Long Wang Zhong-Min su Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education Northeast Normal UniversityChangchun 130024China School of Chemistry and Environmental Engineering Changchun University of Science and TechnologyChangchun 130013China Key Laboratory of Advanced Materials of Tropical island Resources Hainan UniversityHaikou 570228China

Combining theoretical prediction and experimental exploration, the first sandwich-type polyoxovanadoborate(POVB) with an odd number of nuclei, [V_(11)B_(26)O_(73)(OH)_(10)]^(8-)(1), was discovered under hydrothermal conditions. Density-functional theory(DFT)gives a rationalization for the existence of this structure and the structural feature is consistent with the {V_NB_(2N+X)}(X = 2, 4, 6, 8)general formula. Excitingly, when Co and 1,10-phenanthroline(phen) are introduced into the synthesis of vanadoborates system,a 100-nuclei [Co_6(phen)_(10)(H_(2)O)_8][V_(14)Co_(12)B_(72)O_(144)(OH)_(20)]·28H_(2)O(2) and a 102-nuclei [Co_6(phen)_(14)(H_(2)O)_(4)][V_(14)Co_(12)B_(72)O_(144)(OH)_(20)]·23H_(2)O(3) with the same core structure of [V_(14)Co_(12)B_(72)]^(12-)are obtained. The vase-shaped [V_(14)Co_(12)B_(72)] polyanion is a multilayered sandwich-type structure containing seven distinct structural layers and is the largest known POVB. Furthermore, 2demonstrates exceptional thermal and chemical stability and serves as an efficient and stable catalyst for the photoreduction of carbon dioxide.

关键词： boronate metallic materials polyoxovanadoborates density functional theory photocatalysis CO_(2)reduction

inquiry of modulatory role of sea buckthorn fruit oil on dyslipidemia and gut microbiota in hyperlipidemia mice

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Food Science and Human Wellness 2024年

作者： Pimiao Huang Zehua Chen Wenzi Li Aihua su chun Cui infinitus， (China) Co.， Ltd. School of Food Science and Engineering， South China University of Technology

Hyperlipidemia constitutes a critical factor in the pathogenesis of vascular disease and gut microbiota dysbiosis. This study aims to investigate the role of sea buckthorn fruit oil (SBFO) in ameliorating hyperlipidemia， modulating gut microbiota， and elucidating the underlying mechanisms of its lipid-lowering effects. SBFO intervention in hyperlipidemic mice significantly reduced body weight and visceral adiposity index while mitigating symptoms associated with hyperlipidemia， including dyslipidemia， inflammation， liver damage， and endothelial dysfunction. Real-time quantitative PCR and western blot analyses revealed that SBFO enhanced the response of free fatty acid oxidation and breakdown (AMPKα， CPTa-1， PPARα， and PPARγ) while suppressing the synthesis of triglycerides and fatty acids (SREBP-1， FAS， and ACC) at the gene and protein expression levels. Moreover， SBFO intervention enriched the gut microbiota of hyperlipidemic mice by increasing the relative abundances of Lactobacillus， Faecalibaculum， and Allobaculum， while decreasing the Firmicutes/Bacteroidetes ratio. These findings suggest that SBFO exhibits promising therapeutic potential in attenuating hyperlipidemia in mice through the regulation of lipid metabolism and modulation of gut microbiota.

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基于健康因子和混合Bi-LSTM-NAR模型的锂离子电池剩余寿命预测

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中国机械工程 2024年第5期35卷 851-859页

作者：夏然苏春东南大学机械工程学院南京211189

为准确预测锂离子电池剩余寿命、降低电池工作风险,提出一种新的锂离子电池剩余寿命在线预测模型。基于锂离子电池历史运行数据提取6种健康因子,用于表征电池的退化状态;采用随机森林(RF)算法完成健康因子的评价与筛选;利用经遗传算法... 详细信息

为准确预测锂离子电池剩余寿命、降低电池工作风险,提出一种新的锂离子电池剩余寿命在线预测模型。基于锂离子电池历史运行数据提取6种健康因子,用于表征电池的退化状态;采用随机森林(RF)算法完成健康因子的评价与筛选;利用经遗传算法优化的广义回归神经网络(GA-GRNN)完成锂离子电池剩余容量的估计。在此基础上,应用结合双向长短期记忆(Bi-LSTM)网络模型和非线性自回归(NAR)神经网络的混合模型(混合Bi-LSTM-NAR模型)预测锂电池剩余寿命。以NASA公开数据集为例完成案例研究,结果表明:通过因子筛选,可以为锂离子电池容量估计及剩余寿命预测的精度提供保障;与已有方法的预测结果相比,所提混合预测模型的预测精度显著提高。

关键词：锂离子电池健康因子神经网络剩余寿命预测

No incidence of Liver Cancer Was Observed in A Retrospective Studyof Patients with Aristolochic Acid Nephropathy

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Chinese Journal of integrative Medicine 2024年第2期30卷 99-106页

作者： su Tao FANG Zhi-e GUO Yu-ming WANG chun-yu WANG Jia-bo Ji Dong BAi Zhao-fang YANG Li XiAO Xiao-he Renal Division Department of MedicinePeking University First HospitalBeijing(100034)China Department of Pharmacy Chongqing Hospital of Traditional Chinese MedicineChongqing(400021)China Department of Hepatology Fifth Medical Center of Chinese PLA General HospitalBeijing(100039)China China Military institute of Chinese Materia Fifth Medical Center of Chinese PLA General HospitalBeijing(100039)China Phase i Clinical Trials Unit Department of Medicine for Infectious DiseasesFifth Medical Center of Chinese PLA General HospitalBeijing(100039)China Department of Pharmacy Affiliated Hospital of Shandong University of Traditional Chinese MedicineJinan(250000)China National Key Laboratory of Kidney Diseases Beijing(100039)China

Objective:To assess the risk of aristolochic acid(AA)-associated cancer in patients with AA nephropathy(AAN).Methods:A retrospective study was conducted on patients diagnosed with AAN at Peking University First Hospital from January 1997 to December ***-term surveillance and follow-up data were analyzed to investigate the influence of different factors on the prevalence of *** primary endpoint was the incidence of liver cancer,and the secondary endpoint was the incidence of urinary cancer during 1 year after taking AA-containing medication to ***:A total of 337 patients diagnosed with AAN were included in this *** the initiation of taking AA to the termination of follow-up,39 patients were diagnosed with *** cases of liver cancer were observed throughout the entire follow-up period,with urinary cancer being the predominant type(34/39,87.17%).Logistic regression analysis showed that age,follow-up period,and diabetes were potential risk factors,however,the dosage of the drug was not significantly associated with urinary ***:No cases of liver cancer were observed at the end of ***,a high prevalence of urinary cancer was observed in AAN *** a direct causality between AA and HCC is challenging.

关键词： aristolochic acid hepatocellular carcinoma urinary cancer drug safety retrospective study

Stercoral perforation of the cecum:A case report

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World Journal of Gastrointestinal surgery 2024年第4期16卷 1189-1194页

作者： Hung-chun Yu Ta-Wei Pu Jung-Cheng Kang Chao-Yang Chen Je-Ming Hu Ruei-Yu su Department of surgery Taichung Armed Forces General HospitalTaichung 411228Taiwan Department of surgery Tri-Service General HospitalNational Defense Medical CenterTaipei 11490Taiwan Division of Colon and Rectal surgery Department of SurgeryTri-Service General Hospital Songshan BranchNational Defense Medical CenterTaipei 105Taiwan Division of Colon and Rectal surgery Department of SurgeryTaiwan Adventist HospitalTaipei 105Taiwan Division of Colon and Rectal surgery Department of SurgeryTri-Service General HospitalNational Defense Medical CenterTaipei 114Taiwan Department of Pathology Tri-Service General HospitalNational Defense Medical CenterTaipei 105Taiwan Department of Pathology and Laboratory Medicine Taoyuan Armed Forces General HospitalTaoyuan 325Taiwan

BACKGROUND With less than 90 reported cases to date,stercoral perforation of the colon is a rare *** ulceration is thought to occur due to ischemic pressure necrosis of the bowel wall,which is caused by the presence of a stercoraceous *** underscore this urgent surgical situation concerning clinical presentation,surgical treatment,and results,we present the case of a 66-year-old man with a stercoral *** suMMARY A 66-year-old man with a history of hypertension,hyperlipidemia,and gout presented at the emergency department with lower abdominal pain and a low-grade fever lasting for a few *** computed tomography indicated a suspected bezoar(approximately 7.6 cm)in the dilated cecum,accompanied by pericolic fat stranding,mild proximal dilatation of the ileum,pneumoperitoneum,and minimal ***,feculent peritonitis with isolated cecal perforation were ***,a right hemicolectomy with peritoneal lavage was performed.A histopathological examination supported the intraoperative *** in stercoral perforations,a diagnosis should be diligently pursued,especially in older adults,and prompt surgical intervention should be implemented.

关键词： Acute abdomen Colectomy Peritoneal lavage Pneumoperitoneum Bezoars Case report

High quality repair of osteochondral defects in rats using the extracellular matrix of antler stem cells

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World Journal of Stem Cells 2024年第2期16卷 176-190页

作者： Yu-su Wang Wen-Hui Chu Jing-Jie Zhai Wen-Ying Wang Zhong-Mei He Quan-Min Zhao chun-Yi Li institute of Antler Science and Product Technology Changchun Sci-Tech UniversityChangchun 130000Jilin ProvinceChina College of Chinese Medicinal Materials Jilin Agricultural UniversityChangchun 130118Jilin ProvinceChina School of Life Science Taizhou UniversityTaizhou 318000Zhejiang ProvinceChina Department of Oral implantology Hospital of StomatologyJilin UniversityChangchun 130000Jilin ProvinceChina

BACKGROUND Cartilage defects are some of the most common causes of *** lesions caused by inflammation,trauma or degenerative disease normally result in osteochondral *** studies have shown that decellularized extracellular matrix(ECM)derived from autologous,allogenic,or xenogeneic mesenchymal stromal cells(MSCs)can effectively restore osteochondral *** To determine whether the decellularized ECM of antler reserve mesenchymal cells(RMCs),a xenogeneic material from antler stem cells,is superior to the currently available treatments for osteochondral *** We isolated the RMCs from a 60-d-old sika deer antler and cultured them in vitro to 70%confluence;50 mg/mL L-ascorbic acid was then added to the medium to stimulate ECM *** sheets of adipocyte-derived MSCs(aMSCs)and antlerogenic periosteal cells(another type of antler stem cells)were used as the *** weeks after ascorbic acid stimulation,the ECM sheets were harvested and applied to the osteochondral defects in rat knee *** The defects were successfully repaired by applying the *** highest quality of repair was achieved in the RMC-ECM group both in vitro(including cell attachment and proliferation),and in vivo(including the simultaneous regeneration of well-vascularized subchondral bone and avascular articular hyaline cartilage integrated with surrounding native tissues).Notably,the antler-stem-cell-derived ECM(xenogeneic)performed better than the aMSC-ECM(allogenic),while the ECM of the active antler stem cells was superior to that of the quiescent antler stem *** Decellularized xenogeneic ECM derived from the antler stem cell,particularly the active form(RMC-ECM),can achieve high quality repair/reconstruction of osteochondral defects,suggesting that selection of decellularized ECM for such repair should be focused more on bioactivity rather than kinship.

关键词： Osteochondral defect repair Mesenchymal stem cells Extracellular matrix Decellularization Antler stem cells Reserve mesenchymal cells Xenogeneic

Cardo poly (ether sulfone) toughened E51/DETDA epoxy resin and its carbon fiber composites

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新型炭材料（中英文） 2024年第4期39卷 681-691页

作者： WU Rong-peng ZHANG Xing-hua WEi Xing-hai JiNG De-qi su Wei-guo ZHANG Shou-chun Research Center of Advanced Thermoplastic Composites Engineering Institute of Coal ChemistryChinese Academy SciencesTaiyuan 030001China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China Key Laboratory of Carbon Materials Institute of Coal ChemistryChinese Academy SciencesTaiyuan 030001China National Key Laboratory of Science and Technology on Vessel integrated Power System Naval University of EngineeringWuhan 430033China

A toughener that can effectively improve the interlaminar toughness in carbon fiber composites is crucial for various *** investigated,the toughening effects of phenolphthalein-based cardo poly(ether sulfone)(PES-C)on E51/DETDA epoxy and its carbon fiber composites(CFCs).Scanning electron microscopy showed that the phase structures of PES-C/epoxy blends change from island(of dispersed phase)structures to bi-continuous structures(of the matrix)as the PES-C content increased,which is associated with reaction-induced phase *** adding 15 phr PES-C,the glass transition temperature(T_(g))of the blends increased by 51.5℃,and the flexural strength,impact strength and fracture toughness of the blends were improved by 41.1%,186.2%and 42.7%,*** improvements could be attributed to the phase separation structure of the PES-C/epoxy sys-tem.A PES-C film was used to improve the mode-ii fracture toughness(G_(iiC))of *** G_(iiC) value of the 7μm PES-C film toughened laminate was improved by 80.3%compared to that of the control *** increase in G_(iiC) was attributed to cohesive failure and plastic deformation in the interleaving region.

关键词： Epoxy resin CFRP PES-C Toughness