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Establishing a new testing protocol of the electrochemical stability window for electric double-layer capacitors

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Science China Chemistry 2025年第1期68卷 217-225页

作者： Ruilin Hou Xiaoxi Zhao Tingting Liang Qingyun dou Shan Xu Xingbin Yan School of Materials Science and Engineering Sun Yat-sen University Laboratory of Clean Energy Chemistry and Materials Lanzhou Institute of Chemical Physics Chinese Academy of Sciences College of Engineering and Applied Sciences Nanjing University Center of Industrial Analysis and Testing Guangdong Academy of Science

The electrochemical stability window(ESW) is crucial for determining the energy density of electric double-layer capacitors(EDLCs). However, current ESW testing protocols of EDLCs are strongly affected by artificial factors, thereby leading to unreliable result. To solve this problem, we first identify the key shortcomings of the traditional protocols by analyzing their test principles. Subsequently, taking an aqueous carbon-based EDLC as an example, we design a side reaction descriptor to represent the response difference in the charging capacitance to side reactions between the cyclic voltammetry and galvanostatic chargedischarge methods. With the aid of this descriptor, we propose a new ESW testing protocol, which is not only able to completely avoid the adverse influence of subjective factors but also fully consider the operating condition limitations. The protocol can be extended from the single electrode to the full device. This work proposes a more rigorous definition of ESW and provides a reliable protocol for evaluating the ESW of EDLCs.

关键词： electric double-layer capacitors electrochemical stability window testing protocol side reaction descriptor operating limitation

Deciphering the role of ultra-low-loaded rhodium in NiFe-MIL-53 for superior oxygen evolution reaction

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Journal of Energy Chemistry 2025年第1期100卷 77-86页

作者： Jinzhi Jia Jinhua Zhang Kailu Guo Lanyue Zhang Gening Du Hao You Junfeng Huang Mudong Tu Hua Li Yong Peng Wei dou Cailing Xu State Key Laboratory of Applied Organic Chemistry College of Chemistry and Chemical Engineering School of Materials and Energy Lanzhou University College of Chemistry and Chemical Engineering Luoyang Normal University

Designing highly active and stable electrocatalysts of oxygen evolution reaction （OER） is one of the crucial *** this study,a novel OER electrocatalyst,NiFe-MIL-53 modified with ultra-low rhodium（Rh@NiFe-MIL-53）,is successfully prepared via the hydrothermal ***-situ Raman spectroscopy and electrochemical impedance spectroscopy reveal that the doped Rh accelerates the phase transformation of NiFe-MIL-53 and the in-situ formed Rh@NiFeOOH is the actual active *** importantly,the enhanced reversibility of electrochemical reconstruction between NiFeOOH and NiFe（OH）2after doping Rh is beneficial for improving the electrochemical stability of the catalyst.X-ray photoelectron spectroscopy spectra show the strong electronic interaction between single-atom Rh and Ni/Fe in Rh@***,theoretical calculations confirm that the integration of single-atom Rh into the NiFeOOH successfully reduces the band gap,regulates the d-band center （εd）,accelerates the charge transfer,and optimizes the adsorption behavior of oxygen-containing intermediates,thereby lowering the energy barrier of rate-determining ***,the optimized Rh@NiFe-MIL-53 exhibits excellent OER activity （240 mV） with a small Tafel slope of 48.2 mV dec-1and long-term durability (over1270 h at 10 m A cm-2and 110 h at 200 mA cm-2).This work presents a new perspective on designing highly efficient OER electrocatalysts.

关键词： X ray photoelectron spectroscopy

InNi alloy-induced interface effect promoting the parallel electron transfer: improved photothermal catalytic CO2 hydrogenation

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Science China Chemistry 2025年

作者： Haoyu Zhang Yuhang Li Yu Nie Xinyu dou Haodong Ji Xin Tan Jinhua Ye Tao Yu School of Chemical Engineering and Technology Tianjin University Eco-environment and Resource Efficiency Research Laboratory School of Environment and Energy Peking University Shenzhen Graduate School School of Environmental Science and Engineering Tianjin University Advanced Catalytic Materials Research Center School of Materials Science and Engineering Tianjin University Research Center for Solar Driven Carbon Neutrality Hebei University

Photothermal catalytic CO2hydrogenation is an effective means of utilizing carbon ***,it is severely limited in terms of kinetics and ***,it is necessary to meticulously design catalysts to solve this ***,a sandwich structured NiO@InNi/In2O3is designed to intrinsically regulate the direction of photogenerated carriers transfer,resulting in a CO yield of 42.97 mmol g-1h-1(1290.3μmol h-1) with a selectivity near to 100%.InNi alloy favors the collection of photogenerated carriers by the parallel way and enhancement of the adsorption and activation of *** grown on the surface of InNi alloy not only improves the adsorption of H2and provides sufficient H+for the reaction,but also makes InNi alloy more stable during the reaction *** photothermal effect caused by In2O3accelerates the transfer of photogenerated carriers and increases the surface temperature of the catalyst,thereby synergistically promoting the reaction from a kinetic *** work ameliorates the kinetic and thermodynamic limitations of the photothermal catalytic CO2hydrogenation process through rationally designing the electron transfer direction of the sandwich structured catalysts to parallel way.

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Comparative analysis of empirical and deep learning models for ionospheric sporadic E layer prediction

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Earth and Planetary Physics 2025年第1期9卷 10-19页

作者： BingKun Yu PengHao Tian XiangHui Xue Christopher JScott HaiLun Ye JianFei Wu Wen Yi TingDi Chen XianKang dou Institute of Deep Space Sciences Deep Space Exploration LaboratoryHefei 230088China CAS Key Laboratory of Geospace Environment School of Earth and Space SciencesUniversity of Science and Technology of ChinaHefei 230026China Hefei National Laboratory University of Science and Technology of ChinaHefei 230088China Department of Meteorology University of ReadingReading RG66BBUK

Sporadic E(Es)layers in the ionosphere are characterized by intense plasma irregularities in the E region at altitudes of 90-130 *** they can significantly influence radio communications and navigation systems,accurate forecasting of Es layers is crucial for ensuring the precision and dependability of navigation satellite *** this study,we present Es predictions made by an empirical model and by a deep learning model,and analyze their differences comprehensively by comparing the model predictions to satellite RO measurements and ground-based ionosonde *** deep learning model exhibited significantly better performance,as indicated by its high coefficient of correlation(r=0.87)with RO observations and predictions,than did the empirical model(r=0.53).This study highlights the importance of integrating artificial intelligence technology into ionosphere modelling generally,and into predicting Es layer occurrences and characteristics,in particular.

关键词： ionospheric sporadic E layer radio occultation ionosondes numerical model deep learning model artificial intelligence

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Coseismic surface ruptures of MW7.8 and MW7.5 earthquakes occurred on February 6, 2023, and seismic hazard assessment of the East Anatolian Fault Zone, Southeastern Türkiye

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Science China Earth Sciences 2025年

作者： Peng LIANG Yueren XU Xiaocheng ZHOU Ying LI Qinjian TIAN Huiping ZHANG Zhikun REN Jingxing YU Chuanyou LI Zheng GONG Shiguang WANG Aixia dou Zifa MA Junjie LI Key Laboratory of Earthquake Prediction Institute of Earthquake ForecastingChina Earthquake Administration China Earthquake Disaster Prevention Center State Key Laboratory of Earthquake Dynamics Institute of GeologyChina Earthquake Administration Institute of Geophysics China Earthquake Administration

On February 6, 2023, southeastern Türkiye experienced a devastating earthquake doublet along the East Anatolian Fault（EAF）, with moment magnitude（MW） values of 7.8 and 7.5. These strong earthquakes resulted in at least 50,000 deaths and severe economic losses. Systematic research on coseismic surface ruptures induced by these events is vital for assessing the cascade rupture behaviors of plate boundary faults and future seismic hazards in the region. Interpretation of high-resolution post-earthquake satellite images and field investigations yielded the following results:（1） the two strong earthquakes had separate rupture zones. The first earthquake generated an approximately 280 km coseismic surface rupture along the southwestern segment of the main EAF, with 241 left-lateral displacements reaching up to 6.8±0.68 m, particularly 40 km northeast of the epicenter. The second earthquake produced a roughly 110 km surface rupture on an east-west branch of the EAF, with maximum displacements of 7.2±0.72 m.（2） The MW7.8 earthquake resulted in a cascading rupture across multiple segments of the southwestern section of the main EAF, with significantly variable displacements. The northeastern and southwestern parts of the main EAF and Malatya Fault remain at risk of strong earthquakes in the future.（3） The EAF rupture zone is densely populated, and due to the site amplification effect of loose sediments on foreland alluvial fans, foundation failures of buildings in the populated areas are common. Therefore, it is crucial to enhance the future seismic fortification capabilities in urban and rural areas along the EAF.

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模糊PID玉米免耕机排种施肥控制方法研究

农机化研究 2025年第1期47卷 178-184页

作者：张红娟窦新宇唐山学院智能与信息工程学院河北唐山063000

为了实现免耕机播种量和施肥量的精确控制,基于模糊PID控制,设计了控制系统。首先,建立排种量模型,以排种轴转速为控制量;其次,建立施肥量控制模型,分析排肥轴转速、排肥轴长度和免耕机前进速度对于排肥量误差的影响,选择排肥轴转速为... 详细信息

为了实现免耕机播种量和施肥量的精确控制,基于模糊PID控制,设计了控制系统。首先,建立排种量模型,以排种轴转速为控制量;其次,建立施肥量控制模型,分析排肥轴转速、排肥轴长度和免耕机前进速度对于排肥量误差的影响,选择排肥轴转速为控制量;再次,采用模糊PID控制的方法,对驱动电机进行调速,进而实现对排肥轴和排种轴转速的控制,完成排种量和排肥量的调整;最后,对系统进行测试。测试结果表明:电机转速从0调整到50 r/min的响应时间为0.8 s,施肥量变异系数分布区间为[2.6,4.1]。

关键词：模糊PID控制播种量模型施肥量模型玉米

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基于高校思政教学探究南水北调精神传播路径

南阳师范学院学报 2025年第1期24卷 83-90页

作者：豆欣南阳师范学院人工智能与软件工程学院河南南阳473061

南水北调精神是南水北调工程建设中集结着建设者智慧和力量的集中体现,是民族精神和时代精神的生动实践。以“大国统筹、人民至上、创新求精、奉献担当”为核心内涵的南水北调精神对于提升高校思政教学质量具有独特意义。将南水北调精... 详细信息

南水北调精神是南水北调工程建设中集结着建设者智慧和力量的集中体现,是民族精神和时代精神的生动实践。以“大国统筹、人民至上、创新求精、奉献担当”为核心内涵的南水北调精神对于提升高校思政教学质量具有独特意义。将南水北调精神融入高校思政教材、课堂教学和思政学术研讨的理论教学;开展多途径南水北调精神媒体宣传、融入网络思政教育、与思政党建教育相结合的宣传引领;打造南水北调精神实践教育平台、组织南水北调公益志愿服务、与校企协同育人相结合的实践教育,三管齐下推动南水北调精神在高校思政教学中的传播与弘扬。

关键词：南水北调精神高校思政教学传播路径

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课程超市视域下大学英语学分制模块课微认证教学评价模式改革研究

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职业技术 2025年第1期24卷 102-108页

作者：窦菊花广东科学技术职业学院广东珠海519090

本文探讨了在高等职业教育深化改革背景下,大学英语教学通过课程超市、学分制和微认证等创新评价模式,结合MOODLE平台优化教学质量,促进学生个性化学习及教师专业化发展的实践。文章首先指出传统教学评价的局限性,并介绍了相关政策要求... 详细信息

本文探讨了在高等职业教育深化改革背景下,大学英语教学通过课程超市、学分制和微认证等创新评价模式,结合MOODLE平台优化教学质量,促进学生个性化学习及教师专业化发展的实践。文章首先指出传统教学评价的局限性,并介绍了相关政策要求,随后详细阐述了这些创新模式的概念及其应用,特别强调了MOODLE平台在支持微认证评价中的作用。研究结果表明,基于MOODLE的微认证体系显著提升了学生的学习效果和动机,同时为教师提供了数据支持,促进了教学策略的调整。该模式构建了更科学、灵活的教学评价体系,对学生的未来职业发展具有积极影响。

关键词：课程超市学分制模块课程微认证教学评价

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A monolithic 3D IGZO-RRAM-SRAM-integrated architecture for robust and efficient compute-in-memory enabling equivalent-ideal device metrics

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Science China(Information Sciences) 2025年

作者： Shengzhe YAN Zhaori CONG Zi WANG Zhuoyu DAI Zeyu GUO Zhihang QIAN Xufan LI Xu ZHENG Chuanke CHEN Nianduan LU Chunmeng dou Guanhua YANG Xiaoxin XU Di GENG Jinshan YUE Lingfei WANG Ling LI Ming LIU Institute of Microelectronics of the Chinese Academy of Sciences University of Chinese Academy of Sciences

Abstract Compute-in-memory (CIM) based on various devices such as static random access memory (SRAM) and resistive random access memory (RRAM) and other emerging devices such as indium-gallium-zinc-oxide (IGZO) transistor, magnetoresistive RAM (MRAM), and ferroelectric RAM (FeRAM) has been explored for better performance and energy efficiency on neural networks applications. However, CIM based on a single-type device suffers a variety of non-ideal metrics to reach the simultaneous optimal accuracy, density, and energy efficiency. This work presents equivalent-ideal CIM (Eq-CIM), a monolithic 3D(M3D) IGZO-RRAM-SRAM integrated architecture for robust and efficient compute-in-memory enabling equivalent-ideal device metrics. To overcome the non-ideality (variation, endurance, temperature, etc.) of the single-type devices, system-technology co-optimization (STCO) is performed. This work highlights the non-ideality-aware functionality breakdown for robust high accuracy and simultaneous high density/efficiency, by utilizing 2T0C IGZO for temporal activation storage, RRAM for high-density weight storage, and SRAM for accurate CIM. Device-to-algorithm variation transfer is applied to analyze the system-level accuracy. We benchmark Eq-CIM architecture on CIFAR-10/ImageNet, with 5.06×storage density and 5.05×/2.45×area/energy efficiency compared with single-type-device-based CIM, and high robustness (<0.27%accuracy loss) from-40℃ to 120℃.

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