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Achieving structurally stable O3-type layered oxide cathodes through site-specific cation-anion co-substitution for sodium-ion batteries

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Journal of Energy Chemistry 2024年第6期93卷 411-418,I0011页

作者： Yihao shen Chen cheng Xiao Xia Lei Wang Xi Zhou Pan Zeng Jianrong Zeng Liang Zhang Institute of Functional Nano&Soft Materials(FUNSOM) Soochow UniversitySuzhou 215123JiangsuChina Institute for Advanced Study School of Mechanical EngineeringChengdu UniversityChengdu 610106SichuanChina Shanghai Synchrotron Radiation Facility Shanghai Advanced Research InstituteChinese Academy of SciencesShanghai 201204China Shanghai Institute of Applied Physics Chinese Academy of SciencesShanghai 201800China Jiangsu Key Laboratory of Advanced Negative Carbon Technologies Soochow UniversitySuzhou 215123JiangsuChina

O3-type layered oxides have garnered great attention as cathode materials for sodium-ion batteries because of their abundant reserves and high theoretical ***,challenges persist in the form of uncontrollable phase transitions and intricate Na^(+)diffusion pathways during cycling,resulting in compromised structural stability and reduced capacity over *** study introduces a special approach employing site-specific Ca/F co-substitution within the layered structure of O_(3)-NaNi_(0.5)Mn_(0.5)O_(2) to effectively address these ***,the strategically site-specific doping of Ca into Na sites and F into O sites not only expands the Na^(+)diffusion pathways but also orchestrates a mild phase transition by suppressing the Na^(+)/vacancy ordering and providing strong metal-oxygen bonding strength,*** as-synthesized Na_(0.95)Ca_(0.05)Ni_(0.5)Mn_(0.5)O_(1.95)F_(0.05)(NNMO-CaF)exhibits a mild O3→O3+O'3→P3 phase transition with minimized interlayer distance variation,leading to enhanced structural integrity and stability over extended *** a result,NNMO-CaF delivers a high specific capacity of 119.5 mA h g^(-1)at a current density of 120 mA g^(-1)with a capacity retention of 87.1%after 100 *** study presents a promising strategy to mitigate the challenges posed by multiple phase transitions and augment Na^(+)diffusion kinetics,thus paving the way for high-performance layered cathode materials in sodium-ion batteries.

关键词： Sodium-ion batteries O3-type layered oxides Site-specific co-doping Phase transition

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Binding SnO2 Nanoparticles with MoS2 Nanosheets Toward Highly Reversible and Cycle-Stable Lithium/Sodium Storage

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Energy & Environmental Materials 2024年第4期7卷 135-142页

作者： Deliang cheng Wenbiao Zhang Yi Tang Qingsheng Gao Renzong Hu Lichun Yang Min zhu Institute of Advanced Materials Jiangxi Normal University School of Materials Science and Engineering Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials South China University of Technology College of Chemistry and Materials Science Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications Jinan University Department of Chemistry Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Laboratory of Advanced Materials and Collaborative Innovation Center of Chemistry for Energy Materials Fudan University

SnO2,with its high theoretical capacity,abundant resources,and environmental friendliness,is widely regarded as a potential anode material for lithium-ion batteries （LIBs）.Nevertheless,the coarsening of the Sn nanop... 详细信息

关键词： 1 T-MoS2 heterostructure lithium-ion batteries Sn coarsening SnO2

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Effect of Ca Micro-Alloying on the Microstructure and Anti-Corrosion Property of Mg0.5Zn0.2Ge Alloy

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Acta Metallurgica Sinica(English Letters) 2024年第7期37卷 1147-1160页

作者： Bishan cheng Depeng Li Baikang Xing Ruiqing Hou Pingli Jiang Shijie zhu Shaokang Guan School of Materials Science and Engineering and Henan Key Laboratory of Advanced Magnesium Alloys Zhengzhou UniversityZhengzhou450001China Center of Advanced Analysis and Gene Sequencing Zhengzhou UniversityZhengzhou450001China Key Laboratory of Materials Processing and Mold Technology Ministry of EducationZhengzhou450002China

Magnesium and its alloys have attracting rising attention as one of biodegradable metallic ***,the rapid corrosion and severe localized corrosion still hinder their extensive applications in *** this study,micro-alloying of Ca(≤0.1 wt%)into Mg0.5Zn0.2Ge alloy developed in our previous work was explored to further enhance the corrosion resistance and alleviate the localized corrosion of the *** results reveal that the addition of Ca leads to the transformation of the cathodic Mg_(2)Ge phase in Mg0.5Zn0.2Ca alloy into anodic MgCaGe phase in Ca-containing alloys,thereby changing the galvanic couples in alloys during *** preferential dissolution of MgCaGe phase promotes the participation of Ca and Ge into the formation of corrosion products,resulting in the enrichment of Ca and Ge in the outmost of corrosion product layer,which stabilizes and passivates the corrosion product layer on Mg alloy ***,the enrichment of Zn at the corrosion interface seems to further hinder the corrosion of Mg *** of these factors confer a slower and more uniform corrosion on Mg0.5Zn0.2GexCa(x<0.1 wt%)alloy,which provides favorable candidates for the further processing to gain suitable biodegradable Mg alloys.

关键词： Magnesium alloy Micro-alloying Calcium Corrosion resistance

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Single nanozyme-based colorimetric biosensor for dopamine with enhanced selectivity via reactivity of oxidation intermediates

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Chinese Chemical Letters 2024年第10期35卷 425-429页

作者： Caixia zhu Qing Hong Kaiyuan Wang Yanfei shen Songqin Liu Yuanjian Zhang Jiangsu Engineering Laboratory of Smart Carbon-Rich Materials and Devices Jiangsu Province Hi-Tech Key Laboratory for Bio-Medical Research School of Chemistry and Chemical Engineering Medical School Southeast University

Reliable and selective sensing of dopamine（DA） is essential for early diagnosis of mental *** the various potential methods, nanozyme-based sensing systems have demonstrated promising sensitivity and reliability. However, owing to the lack of substrate specificity, it is challenging to selectively detect DA using nanozymes. Herein, based on the reactivity of the DA oxidation intermediates,we report a cascade colorimetric sensing system for the selective detection of DA using only a single nanozyme. It was disclosed that the oxidation product of DA catalyzed by Co-N-doped carbon sheets（Co-N-C, a common oxidase-like nanozyme）, dopamine quinone（DAQ）, showed significant biocatalytic electron-donating activity in the reduction of O2to generate O2·-. Further using O2·-to oxidize3,3,5,5-tetramethylbenzidine（TMB）, a colorimetric sensing platform for DA was constructed with a linear detection range of 50 nmol/L to 50 μmol/L and a low limit of detection of 4 nmol/L. Thanks to the reactivity of the oxidation product, without any biometric units（such as nucleic acids, enzymes,and antibodies/antigens）, the reaction selectivity of DA against other interferences（e.g., ascorbic acid,adrenaline, 5-hydroxytryptamine, and glutathione） was enhanced up to 71-fold. Beyond complicated cascade systems requiring at least two nanozymes, sophisticated artificial recognition via multiple interactions was simplified by exploiting the oxidative properties of product intermediates; thus, only a single common oxidase-like nanozyme was needed. This work offers a new strategy to enhance the selectivity of nanozymes for bioanalytical applications.

关键词： Artificial recognition Colorimetry Dopamine Nanozyme Selectivity

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Remarkable Wear Resistance in a Complex Concentrated Alloy with Nanohierarchical Architecture and Composition Undulation

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Research 2024年第1期2023卷 403-416页

作者： Yushan Geng Wenyuan Chen Hui Tan Jun cheng shengyu zhu Jun Yang Weimin Liu State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical PhysicsChinese Academy of SciencesLanzhou 730000PR China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049PR China Shandong Laboratory of Yantai Advanced Materials and Green Manufacturing Yantai 264000PR China

Sustained wear damages on the sliding surfaces of alloys are generally the culprit responsible for the failure of various mechanical *** by high-entropy effects,here we deliberately deploy nanohierarchical architecture with composition undulation in a Ni50(AlNbTiV)_(50) complex concentrated alloy,which yields ultralow wear rate within the order of 10^(−7) to 10^(−6) mm^(3)/Nm between room temperature and 800℃.Such remarkable wear resistance heretofore represents one of the highest wear resistance reported for the bulk alloys or composites,and originates from the multi-type adaptive friction interface protection governed by intrinsically nano-coupled grains and *** cooperative heterostructure releases gradient frictional stress in stages upon wear at room temperature through the coexistence of multiple deformation pathways while activating a dense nanocrystalline glaze layer upon wear at 800℃ to minimize adhesive and oxidative *** work uncovers a practical avenue for tailoring wear properties with multicomponent heterostructures over a wide temperature range.

关键词： wear alloys friction

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Energy Harvesting in the Wake of An Inverted C-Shaped Bluff Body

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China Ocean Engineering 2024年第1期38卷 68-80页

作者： WANG Jun-lei LI shen-fang Md.Mahbub ALAM zhu Hong-jun HU Guo-biao School of Mechanical and Power Engineering Zhengzhou UniversityZhengzhou 450000China Center for Turbulence Control Harbin Institute of Technology(Shenzhen)Shenzhen 518055China State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Southwest Petroleum UniversityChengdu 610500China Internet of Things Thrust The Hong Kong University of Science and Technology(Guangzhou)Guangzhou 511400China

This paper proposes a novel wake-induced vibration(WIV)-based energy harvesting system consisting of two bluff *** inverted C-shaped bluff body is stationary installed at the upstream position to generate an interference wake street,and a cylinder bluff body equipped with a transducer is elastically suspended at the downstream position to harness WIV *** hydrodynamics and energy harvesting(EH)performance of the proposed system are investigated via experimental *** reduced velocity(U*)ranging from 2 to 14(the corresponding Reynolds number ranging from 15100 to 106200)is considered in the present *** is found that the wake generated by the inverted C-shaped bluff body significantly affects the EH *** the opening angle(α)of the C-shaped bluff body increases the vibration amplitude of the downstream cylinder,thereby increasing the harvested *** the spacing(L)between two bluff bodies is two times the cylinder diameter(D),the wake-induced vibration(WIV)mode is observed,while the combined WIV and wake galloping(WG)mode occurs whenαis 150°,and L equals 3D or *** average drag coefficient becomes negative when L is 2D,3D,or *** carefully configuring a C-shaped bluff body,the wake generated by it can bring an augmenting effect on the vibration of the downstream EH *** example,the RMS power output of the proposed EH system reaches a maximum of 0.31 W at U*=8 and L=4D,which is 300%greater than that of its traditional ***,after a number of case stud-ies,it is identified that the proposed EH system can achieve the best performance whenαis 150°and L=2D.

关键词： wake-induced vibration vortex-induced vibration galloping energy harvesting bluff body

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Ripple Knowledge Graph Convolutional Networks for Recommendation Systems

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Machine Intelligence Research 2024年第3期21卷 481-494页

作者： Chen Li Yang Cao Ye zhu Debo cheng chengyuan Li Yasuhiko Morimoto Graduate School of Informatics Nagoya UniversityChikusaNagoya 464-8602Japan Centre for Cyber Resilience and Trust Deakin UniversityBurwood 3125Australia Science TechnologyEngineering and Mathematics(STEM)University of South AustraliaAdelaide 5000Australia Graduate School of Engineering Hiroshima UniversityHigashi-hiroshima 10587Japan

Using knowledge graphs to assist deep learning models in making recommendation decisions has recently been proven to effectively improve the model′s interpretability and *** paper introduces an end-to-end deep learning model,named representation-enhanced knowledge graph convolutional networks(RKGCN),which dynamically analyses each user′s preferences and makes a recommendation of suitable *** combines knowledge graphs on both the item side and user side to enrich their representations to maximize the utilization of the abundant information in knowledge *** is able to offer more personalized and relevant recommendations in three different *** experimental results show the superior effectiveness of our model over 5 baseline models on three real-world datasets including movies,books,and music.

关键词： Deep learning recommendation systems knowledge graph graph convolutional networks(GCNs) graph neural networks(GNNs)

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Unlocking the potential of ultra-thin two-dimensional antimony materials:Selective growth and carbon coating for efficient potassium-ion storage

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Journal of Energy Chemistry 2024年第5期92卷 440-449页

作者： Dongyu Zhang Zhaomin Wang Yabin shen Yeguo Zou Chunli Wang Limin Wang Yong cheng State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied ChemistryChinese Academy of Sciences(CAS)Changchun 130022JilinChina School of Applied Chemistry and Engineering University of Science and Technology of ChinaHefei 230026AnhuiChina

Antimony-based anodes have attracted wide attention in potassium-ion batteries due to their high theoretical specific capacities(∼660 mA h g^(-1))and suitable voltage ***,severe capacity fading caused by huge volume change and limited ion transportation hinders their practical ***,strategies for controlling the morphologies of Sb-based materials to improve the electrochemical performances have been *** these,the two-dimensional Sb(2D-Sb)materials present excellent properties due to shorted ion immigration paths and enhanced ion ***,the synthetic methods are usually tedious,and even the mechanism of these strategies remains elusive,especially how to obtain large-scale 2D-Sb ***,a novel strategy to synthesize 2D-Sb material using a straightforward solvothermal method without the requirement of a complex nanostructure design is *** method leverages the selective adsorption of aldehyde groups in furfural to induce crystal growth,while concurrently reducing and coating a nitrogen-doped carbon *** to the reported methods,it is simpler,more efficient,and conducive to the production of composite nanosheets with uniform thickness(3–4 nm).The 2D-Sb@NC nanosheet anode delivers an extremely high capacity of 504.5 mA h g^(-1) at current densities of 100 mA g^(-1) and remains stable for more than 200 *** characterizations and molecular dynamic simulations,how potassium storage kinetics between 2D Sb-based materials and bulk Sb-based materials are explored,and detailed explanations are *** findings offer novel insights into the development of durable 2D alloy-based anodes for next-generation potassium-ion batteries.

关键词： Antimony Two-dimensional materials Selective growth Nitrogen-doped carbon Potassium-ion batteries

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A Synchronization Acquisition Algorithm Based on the Frequency Hopping Pulses Combining

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China Communications 2024年第4期21卷 74-87页

作者： She Honghan cheng Yufan Zhang Wenzihan Zhang Yaohui Zhao Yuheng shen Haoran Mou Ying National Key Laboratory of Wireless Communications UESTCChengdu 611731China

As modern electromagnetic environments are more and more complex,the anti-interference performance of the synchronization acquisition is becoming vital in wireless *** the rapid development of the digital signal processing technologies,some synchronization acquisition algorithms for hybrid direct-sequence(DS)/frequency hopping(FH)spread spectrum communications have been ***,these algorithms do not focus on the analysis and the design of the synchronization acquisition under typical *** this paper,a synchronization acquisition algorithm based on the frequency hopping pulses combining(FHPC)is ***,the proposed algorithm is composed of two modules:an adaptive interference suppression(IS)module and an adaptive combining decision *** adaptive IS module mitigates the effect of the interfered samples in the time-domain or the frequencydomain,and the adaptive combining decision module can utilize each frequency hopping pulse to construct an anti-interference decision metric and generate an adaptive acquisition decision threshold to complete the *** and simulation demonstrate that the proposed algorithm significantly enhances the antiinterference and anti-noise performances of the synchronization acquisition for hybrid DS/FH communications.

关键词： adaptive anti-interference frequency hopping synchronization acquisition

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Sulfated Cyclocarya paliurus polysaccharides exert immunomodulatory potential on macrophages via Toll-like receptor 4 mediated MAPK/NF-κB signaling pathways

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Food Science and Human Wellness 2024年第1期13卷 115-123页

作者： Yue Yu Haibin zhu Mingyue shen Qiang Yu Yi Chen Shiru Mo Jianhua Xie State Key Laboratory of Food Science and Technology Nanchang UniversityNanchang 330047China International Institute of Food Innovation Nanchang UniversityNanchang 330200China

The biological activity of plant polysaccharides can be enhanced by sulfated *** this study,the immunomodulatory effect of sulfated Cyclocarya paliurus polysaccharides(SCP3)on macrophages RAW264.7 and its potential molecular mechanism were *** showed that SCP3 at 25-100μg/m L increased viability and improved phagocytosis of RAW264.7 ***,SCP3 could activate mitogen-activated protein kinase(MAPK)and nuclear factor kappa B(NF-κB)signaling pathways,which increased the phosphorylation of Erk1/2,JNK,p38 and NF-κB p65,promoting secretion of cytokines tumor necrosis factorα(TNF-α),interleukin 6(IL-6)and nitric oxide(NO)as well as the production of reactive oxygen species(ROS).In addition,Toll-like receptor 4(TLR4)receptor inhibitors were able to block the production of NO and TNF-αby SCP3-stimulated *** on Western blot analysis and validation using specific inhibitors against MAPK and NF-κB signaling pathways,the results demonstrated that SCP3 induced macrophages activation and enhanced TNF-αand NO production via TLR4-mediated MAPK and NF-κB *** summary,SCP3 has significant immunomodulatory *** underlying molecular mechanism was that SCP3 activates macrophages via TLR4 receptors to promote ROS production,which in turn activates the downstream MAPK/NF-κB signaling pathway and then increases the secretion levels of cytokines and NO.

关键词： Cyclocarya paliurus Sulfated polysaccharides Macrophages Immunomodulatory Mechanism

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