Binding SnO_(2)Nanoparticles with MoS_(2)Nanosheets Toward Highly Reversible and Cycle-Stable Lithium/Sodium Storage

作     者：Deliang Cheng Wenbiao Zhang Yi Tang Qingsheng Gao Renzong Hu Lichun Yang Min Zhu Deliang Cheng;Wenbiao Zhang;Yi Tang;Qingsheng Gao;Renzong Hu;Lichun Yang;Min Zhu

作者机构：Institute of Advanced MaterialsJiangxi Normal UniversityNanchang 330022China School of Materials Science and EngineeringGuangdong Provincial Key Laboratory of Advanced Energy Storage MaterialsSouth China University of TechnologyGuangzhou 510641China College of Chemistry and Materials ScienceGuangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and ApplicationsJinan UniversityGuangzhou 510632China Department of ChemistryShanghai Key Laboratory of Molecular Catalysis and Innovative MaterialsLaboratory of Advanced Materials and Collaborative Innovation Center of Chemistry for Energy MaterialsFudan UniversityShanghai 200433China 

出 版 物：《Energy & Environmental Materials》 (能源与环境材料（英文）)

年 卷 期：2024年第7卷第4期

页      面：135-142页

核心收录：

学科分类：0808[工学-电气工程] 07[理学] 070205[理学-凝聚态物理] 08[工学] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0702[理学-物理学] 

基　　金：the financial support from the National Key Research and Development Program of China(2018YFA0209402,2022YFB2502003) Guangdong Basic and Applied Basic Research Foundation(2023B1515040011) Jiangxi Provincial Natural Science Foundation(20212BAB214028) 

主　　题：1 T-MoS_(2) heterostructure lithium-ion batteries Sn coarsening SnO_(2) 

摘      要：SnO_(2),with its high theoretical capacity,abundant resources,and environmental friendliness,is widely regarded as a potential anode material for lithium-ion batteries(LIBs).Nevertheless,the coarsening of the Sn nanoparticles impedes the reconversion back to SnO_(2),resulting in low coulombic efficiency and rapid capacity *** this study,we fabricated a heterostructure by combining SnO_(2)nanoparticles with MoS_(2)nanosheets via plasma-assisted *** heterostructure consists of in-situ exfoliated MoS_(2)nanosheets predominantly in 1 T phase,which tightly encase the SnO_(2)nanoparticles through strong *** configuration effectively mitigates the volume change and particle aggregation upon ***,the strong affinity of Mo,which is the lithiation product of MoS_(2),toward Sn plays a pivotal role in inhibiting the coarsening of Sn nanograins,thus enhancing the reversibility of Sn to SnO_(2)upon ***,the SnO_(2)/MoS_(2)heterostructure exhibits superb performance as an anode material for LIBs,demonstrating high capacity,rapid rate capability,and extended ***,discharged/charged at a rate of 0.2 A g^(-1)for 300 cycles,it achieves a remarkable reversible capacity of 1173.4 mAh g^(-1).Even cycled at high rates of 1.0 and 5.0 A g^(-1)for 800 cycles,it still retains high reversible capacities of 1005.3 and 768.8 mAh g^(-1),***,the heterostructure exhibits outstanding electrochemical performance in both full LIBs and sodium-ion batteries.