检索结果-南通市图书馆

Structural Evolution of Ultra-High Molecular weight Polyethylene Low-Entangled Films with Reserved Shish Crystals During Hot Stretching

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Chinese Journal of Polymer Science 2024年第8期42卷 1227-1242页

作者： Jia-wei Gao Li Chen Ye-Shun Zhong chao-wei xing Yi-Guo Li Zong-Bao Wang School of Materials Science and Chemical Engineering Ningbo UniversityNingbo 315211China

Shish crystals are crucial to achieving high performance low-dimensional ultra-high molecular weight polyethylene(UHMWPE)***,high stretch and shear flow fields are necessary for the formation of shish *** this study,UHMWPE gel films with reserved shish crystals were prepared by gel molding,the structural evolution and properties of UHMWPE films stretched at temperatu res of 100,110,120and 130℃were investigated by in situ small-angle X-ray scattering(SAXS)/ultra-small-angle X-ray scattering(USAXS)/wide-angle X-ray diffraction(WAXD)measu rements as well as scanning electron microscopy(SEM)and differential scanning calorimetry(DSC)*** findings showed that the reserved shish crystals can facilitate the formation and structural evolution of shish-kebab crystals during the hot ***,the reserved shish crystals promote the structu ral evolution of UHMWPE films to a greater extent when stretched at 120 and 130℃,compared to 100 and 110℃,resulting in higher crystallinity,orientation,thermal properties,breaking strength and Young's *** pared to UHMWPE high-entangled films with reserved shish crystals prepared by compression molding,UHMWPE low-entangled films with reserved shish crystals prepared by gel molding are more effective in inducing the formation and evolution of shish-kebab crystals during the hot stretching,resulting in increased breaking strength and Young's modulus.

关键词： UHMWPE low-entangled films Reserved shish crystals Structural evolution Hot stretching

Highly active Pd-Fe/α-Al_(2)O_(3) catalyst with the bayberry tannin as chelating promoter for CO oxidative coupling to diethyl oxalate

在线全文

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2021年第2期32卷 796-800页

作者： wei-chao xing Ji-Min An Jing Lv Faisal Irshad Yu-Jun Zhao Sheng-Ping Wang Xin-Bin Ma Key Laboratory for Green Chemical Technology School of Chemical Engineering and TechnologyTianjin UniversityCollaborative Innovation Center of Chemical Science and EngineeringTianjin 300072China

A novel Pd-Fe/α-Al_(2)O_(3) catalyst was synthesized by incipient-wetness impregnation method with bayberry tannin as chelating promoter and commercial hollow column Raschig ring a-Al_(2)O_(3) as support for the synthesis of diethyl oxalate from CO and ethyl nitrite.A variety of characterization techniques including N2 physical adsorption,optical microscopy,scanning electron microscopy and energy dispersive system(SEM-EDS),inductively coupled plasma optical emission spectroscopy(ICP-OES),X-ray diffraction(XRD),X-ray photoelectron spectroscopy(XPS),transmission electron microscopy(TEM),were employed to explore the relationship between the physicochemical properties and activity of *** indicated that a large number of phenolic hydroxyl groups in bayberry tannin can efficiently anchor the active component Pd,reduce the particle size and make the active Pd as a multi-ring distribution on the commercial a-Al2O3 suppo rt,which we re beneficial to improve the catalytic activity for the production of diethyl oxalate from CO and ethyl nitrite.0.3 wts Pd-Fe/α-Al_(2)O_(3) showed excelle nt catalytic activity and selectivity in a continuous flow,fixed-bed reactor with the loading amount of 10 mL catalysts,Under the mild reaction conditions,the space-time yield of diethyl oxalate was 978 g L^(-1) h^(-1) and CO conversion was 44% with the selectivity to diethyl oxalate of 95.5%.

关键词： Bayberry tannin Diethyl oxalate Phenolic hydroxyl groups Ethyl nitrite Pd-Fe/α-Al_(2)O_(3)

Quantifying Responses of Winter Wheat Physiological Processes to Soil Water Stress for Use in Growth Simulation Modeling

在线全文

学校读者我要写书评

暂无评论

Pedosphere 2004年第4期14卷 509-518页

作者： HUJi-chao CAOwei-xing ZHANGJia-Bao JIANGDong FENGJie Hi-TechKeyLaboratoryofInformationAgricultureofJiangsuProvince NanjingAgriculturalUniversityNanjing210095（China） StateKeyLaboratoryofSoilandSustainableAgriculture InstituteofSoilScienceChineseAcademyofSciencesNanjing210008（China）

A deep understanding of crop-water eco-physiological relations is the basis for quantifying plant physiological responses to soil water stress. Pot experiments were conducted to investigate the winter wheat crop-water relations under both drought and waterlogging conditions in two sequential growing seasons from 2000 to 2002, and then the data were used to develop and validate models simulating the responses of winter wheat growth to drought and waterlogging stress. The experiment consisted of four treatments, waterlogging (keep 1 to 2 cm water layer depth above soil surface), control (70%-80% field capacity), light drought (40%-50% field capacity) and severe drought (30%-40% field capacity) with six replicates at five stages in the 2000-2001 growth season. Three soil water content treatments (waterlogging, control and drought) with two replicates were designed in the 2001-2002 growth season. Waterlogging and control treatments are the same as in the 2000-2001 growth season. For the drought treatment, no water was supplied and the soil moisture decreased from field capacity to wilting point. Leaf net photosynthetic rate, transpiration rate, predawn leaf water potential, soil water potential, soil water content and dry matter weight of individual organs were measured. Based on crop-water eco-physiological relations, drought and waterlogging stress factors for winter wheat growth simulation model were put forward. Drought stress factors integrated soil water availability, the sensitivity of different development stages and the difference between physiological processes (such as photosynthesis, transpiration and partitioning). The quantification of waterlogging stress factor considered different crop species, soil water status, waterlogging days and sensitivity at different growth stages. Data sets from the pot experiments revealed favorable performance reliability for the simulation sub-models with the drought and waterlogging stress factors.

关键词： crop simulation model drought water stress factor waterlogging winterwheat

Boosting Oxygen Evolution Reaction Performance on NiFe‑Based Catalysts Through d‑Orbital Hybridization

在线全文

学校读者我要写书评

暂无评论

Nano-Micro Letters 2025年第1期17卷 281-292页

作者： xing Wang wei Pi Sheng Hu Haifeng Bao Na Yao wei Luo State Key Laboratory of New Textile Materials and Advanced Processing Technology Key Laboratory of New Textile Materials and Applications of Hubei ProvinceSchool of Materials Science and EngineeringWuhan Textile UniversityWuhan 430200People’s Republic of China College of Chemistry and Molecular Sciences Wuhan UniversityWuhan 430072People’s Republic of China

Anion-exchange membrane water electrolyzers(AEMWEs)for green hydrogen production have received intensive attention due to their feasibility of using earth-abundant NiFe-based *** introducing a third metal into NiFe-based catalysts to construct asymmetrical M-NiFe units,the d-orbital and electronic structures can be adjusted,which is an important strategy to achieve sufficient oxygen evolution reaction(OER)performance in ***,the ternary NiFeM(M:La,Mo)catalysts featured with distinct M-NiFe units and varying d-orbitals are reported in this *** and theoretical calculation results reveal that the doping of La leads to optimized hybridization between d orbital in NiFeM and 2p in oxygen,resulting in enhanced adsorption strength of oxygen intermediates,and reduced rate-determining step energy barrier,which is responsible for the enhanced OER *** critically,the obtained NiFeLa catalyst only requires 1.58 V to reach 1 A cm^(−2) in an anion exchange membrane electrolyzer and demonstrates excellent long-term stability of up to 600 h.

关键词： NiFe-based catalysts d-orbital coupling Oxygen evolution reaction Anion exchange membrane electrolyzer

Vibration Compensation for Scanning Tunneling Microscope

在线全文

学校读者我要写书评

暂无评论

Semiconductor Photonics and Technology 2003年第4期9卷 230-233页

作者： LI Meng chao, FU xing, wei Xiao lei, HU Xiao tang (State Key Lab.of Precision Measurement Technology and Instrument, Tianjin University,Tianjin 300072, CHN) Tianjin University State Key Lab. of Precision Measurement Technology and Instrument Tianjin 300072

The influence of vibration is already one of main obstacles for improving the nano measuring *** techniques of anti-vibration,vibration isolation and vibration compensation become an important branch in nano measuring *** with the research of sensitivity to vibration of scanning tunneling microscope(STM),the theory,techniques and realization methods of nano vibration sensor based on tunnel effect are initially investigated,followed by developing the experimental *** experiments of the vibration detection and vibration compensation are carried *** experimental results show that vibration sensor based on tunnel effect is characterized by high sensitivity,good frequency characteristic and the same vibratory response characteristic consistent with STM.

关键词： Nano vibration sensor Scanning tunneling microscope(STM) Tunnel effect Vibration compensation

Controllable synthesis of biomimetic wood stem nanoporous high entropy oxides catalysts for oxygen evolution reaction

在线全文

学校读者我要写书评

暂无评论

Nano Research 2025年第1期18卷 107-117页

作者： wei Wang weiqi Wang Huihui Wang xing Lu Jinwen Zhang Yunzhuo Lu School of Materials Science and Engineering Dalian Jiaotong UniversityDalian 116028China School of Intelligence and Electronic Engineering Dalian Neusoft University of InformationDalian 116023China Guangdong Key Laboratory of Materials and Equipment in Harsh Marine Environment Guangzhou Maritime UniversityGuangzhou 510725China

Bubbles generated during the oxygen evolution reaction(OER)in water splitting readily adhere to the electrode surface,thereby impeding contact between the electrolyte and the active sites,thereby increasing the ***,it is imperative to elucidate the bubble release behavior and engineer electrodes that facilitate faster bubble *** this study,inspired by the wood stem of the Norway spruce,we synthesized a gradient nanoporous high-entropy oxide(GNP-HEO)electrode with a controllable pore *** GNP-HEO,featuring a well-controlled gradient in pore size,is achieved through a straightforward strategy combining selective laser melting with selective phase *** unique gradient nanoporous structure not only facilitates bubble release but also diminishes the bubble shielding effect in OER,thereby enhancing electrocatalytic *** affect interaction of Al,Co,Cr,Fe,and Ni,coupled with the gradient nanoporous structure,yields exceptional OER performance,evidenced by an overpotential of 250 mV at a current density of 50 mA/cm^(2) and a Tafel slope of 38.0 mV/dec in 1 M *** functional theory calculations confirm that the GNPHEO adheres to the adsorbate evolution mechanism reaction pathway and exhibits significant *** work highlights a promising approach for the design and synthesis of high-performance OER electrocatalysts.

关键词： oxygen evolution reaction high-entropy oxides selective phase dis-solution selective laser melting gradient nanoporous

A low redox potential and long life organic anode material for sodium-ion batteries

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2025年第1期100卷 557-564页

作者： Zhi Li Yang wei Kang Zhou Xin Huang xing Zhou Jie Xu Taoyi Kong Junwei Lucas Bao Xiaoli Dong Yonggang Wang Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Institute of New Energy Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) Fudan University Department of Chemistry Boston College School of Materials Science and Engineering Anhui University of Technology

Sodium-ion batteries （SIBs） with organic electrodes are an emerging research direction due to the sustainability of organic materials based on elements like C,H,O,and sodium ***,organic electrode materials for SIBs are mainly used as cathodes because of their relatively high redox potentials（>1 V）.Organic electrodes with low redox potential that can be used as anode are ***,a novel organic anode material （tetrasodium 1,4,5,8-naphthalenetetracarboxylate,Na4TDC） has been developed with low redox potential （<0.7 V） and excellent cyclic *** three-sodium storage mechanism was demonstrated with various in-situ/ex-situ spectroscopy and theoretical calculations,showing a high capacity of 208 mAh/g and an average decay rate of merely 0.022%per ***,the Na4TDC-hard carbon composite can further acquire improved capacity and cycling stability for 1200 cycles even with a high mass loading of up to 20 mg *** pairing with a thick Na3V2（PO4）3cathode (20.6 mg cm-2),the as-fabricated full cell exhibited high operating voltage （2.8 V）,excellent rate performance and cycling stability with a high capacity retention of 88.7% after 200 cycles,well highlighting the Na4TDC anode material for SIBs.

关键词： Organic anode material Low redox potential Composite anode Sodium-ion batteries

Stiffness-tunable biomaterials provide a good extracellular matrix environment for axon growth and regeneration

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Neural Regeneration Research 2025年第5期20卷 1364-1376页

作者： Ronglin Han Lanxin Luo Caiyan wei Yaru Qiao Jiming Xie Xianchao Pan Juan xing Department of Pathophysiology School of Basic Medical SciencesSouthwest Medical UniversityLuzhouSichuan ProvinceChina Department of Medicinal Chemistry School of PharmacySouthwest Medical UniversityLuzhouSichuan ProvinceChina

Neuronal growth, extension, branching, and formation of neural networks are markedly influenced by the extracellular matrix—a complex network composed of proteins and carbohydrates secreted by cells. In addition to providing physical support for cells, the extracellular matrix also conveys critical mechanical stiffness cues. During the development of the nervous system, extracellular matrix stiffness plays a central role in guiding neuronal growth, particularly in the context of axonal extension, which is crucial for the formation of neural networks. In neural tissue engineering, manipulation of biomaterial stiffness is a promising strategy to provide a permissive environment for the repair and regeneration of injured nervous tissue. Recent research has fine-tuned synthetic biomaterials to fabricate scaffolds that closely replicate the stiffness profiles observed in the nervous system. In this review, we highlight the molecular mechanisms by which extracellular matrix stiffness regulates axonal growth and regeneration. We highlight the progress made in the development of stiffness-tunable biomaterials to emulate in vivo extracellular matrix environments, with an emphasis on their application in neural repair and regeneration, along with a discussion of the current limitations and future prospects. The exploration and optimization of the stiffness-tunable biomaterials has the potential to markedly advance the development of neural tissue engineering.

关键词： alginate axon growth biomaterials extracellular matrix neural repair neurons neuroregeneration polyacrylamide polydimethylsiloxane stiffness

不同水氮条件下水稻冠层反射光谱与叶片水势关系的研究

在线全文

学校读者我要写书评

暂无评论

水土保持学报 2003年第3期17卷 178-180,183页

作者：田永超曹卫星姜东朱艳南京农业大学农业部作物生长调控重点开放实验室南京210095

研究了不同水氮处理对水稻叶片水势及冠层光谱的影响,确立了叶片水势与冠层反射光谱的相关关系。结果表明,水稻叶水势随土壤含水量的升高而升高;在相同干旱胁迫下,低氮处理的叶水势高于高氮处理的叶水势。研究发现,比值指数与归一化指... 详细信息

研究了不同水氮处理对水稻叶片水势及冠层光谱的影响,确立了叶片水势与冠层反射光谱的相关关系。结果表明,水稻叶水势随土壤含水量的升高而升高;在相同干旱胁迫下,低氮处理的叶水势高于高氮处理的叶水势。研究发现,比值指数与归一化指数的比值与水稻叶片水势、相对含水率呈良好的线性相关,从而获得了一种地面遥感监测水稻全生育期叶片水势的定量方法。

关键词：水稻冠层反射光谱叶片水势水氮处理相关关系土壤含水量叶片相对含水率遥感技术灌溉