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Room-temperature and atmospheric-pressure hydrogenation of lignin-derived phenol to KA oil by Pt/NiO@MOFs

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Nano Research 2024年第8期17卷 7053-7060页

作者： Fengbin Zheng Kun Wang Yifei Ren Bohua Wang Wenxing Chen caoyu Yang Shengxian Shao Yinglong Wang Zhiyong Tang Guodong Li College of Chemical Engineering Qingdao University of Science and TechnologyQingdao 266042China CAS Key Laboratory of Nanosystem and Hierarchical Fabrication CAS Center for Excellence in NanoscienceNational Center for Nanoscience and TechnologyBeijing 100190China School of Materials Science and Engineering Beijing Institute of TechnologyBeijing 100181China School of Nanoscience and Technology University of Chinese Academy of SciencesBeijing 100049China

Hydrogenation of lignin-derived phenol to KA oil(the mixture of cyclohexanone(K)and cyclohexanol(A))is attractive yet challenging in the sustainable upgrading of biomass derivatives under mild *** supported metal catalysts have been widely studied but the active components on supports often exhibit low recyclability due to their instability under experimental *** we show fabricating ultrasmall Pt/NiO in the pores of chromium terephthalate MIL-101 as catalysts for hydrogenation of ***,Pt/NiO@MIL-101 achieves catalytic phenol hydrogenation to KA oils of tunable K/A ratios and good reusability under room temperature and atmospheric hydrogen pressure,superior to contrast Pt@MIL-101 and Pt/NiO *** excellent performance mainly originates from the effective adsorption and activation of phenol by coordinatively unsaturated Cr sites and H2 activation on ultrasmall Pt/NiO as well as its effective spillover to the adsorbed phenol over Cr sites for hydrogenation ***,such catalyst also displays the excellent performances for hydrogenation of phenol’s derivatives under mild conditions.

关键词： ultrasmall Pt/NiO MIL-101 phenol hydrogenation KA oil

Bridging buried interface enable 24.67%-efficiency doctor-bladed perovskite solar cells in ambient condition

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Nano Research 2024年第9期17卷 8068-8076页

作者： Jianhui Chang Erming Feng Xiangxiang Feng Hengyue Li Yang Ding caoyu Long Siyuan Lu Haixia Zhu Wen Deng Jiayan Shi Yingguo Yang Si Xiao Yongbo Yuan Junliang Yang Hunan Key Laboratory for Super-microstructure and Ultrafast Process School of PhysicsCentral South UniversityChangsha 410083China Hunan Key Laboratory of Nanophotonics and Devices School of PhysicsCentral South UniversityChangsha 410083China Textile and Fashion Collage Hunan Institute of EngineeringXiangtan 411101China Shanghai Synchrotron Radiation Facility Shanghai Advanced Research InstituteChinese Academy of SciencesShanghai 201204China State Key Laboratory of Powder Metallurgy Central South UniversityChangsha 410083China

Scalable deposition of high-efficiency perovskite solar cells(PSCs)is critical to accelerating their commercial ***,a significant number of defects are distributed at the buried interface of perovskite film fabricated by scalable deposition,exhibiting much negative influence on the efficiency and stability of ***,2-(N-morpholino)ethanesulfonic acid potassium salt(MESK)is incorporated as the bridging layer between the tin oxide(SnO_(2))electron transport layer(ETL)and the perovskite film deposited via scalable two-step doctor *** experiment and simulation results demonstrate that MESK can passivate the trap states of Sn suspension bonds,thereby enhancing the charge extraction and transport of the SnO_(2)***,the strong interaction with uncoordinated Pb ions can modulate the crystal growth and crystallographic orientation of perovskite film and passivate buried *** employing MESK interface bridging,PSCs fabricated via scalable doctor blading in ambient condition achieve a power conversion efficiency(PCE)of 24.67%,which is one of the highest PCEs for doctor-bladed PSCs,and PSC modules with an active area of 11.35 cm^(2)achieve a PCE of 19.45%.Furthermore,PSCs exhibit excellent long-term stability,and the unpackaged target device with a storage of 1680 h in ambient condition(25℃and humidity of 30%relative humidity(RH))can maintain more than 90%of the initial *** research provides a strategy for constructing a high-performance interface bridge between SnO_(2)ETL and perovskite film,and achieving efficient and stable large-area PSCs and modules fabricated via scalable doctor-blading process in ambient condition.

关键词： perovskite solar cells doctor blading buried interface defect passivation orientation regulation

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绿色氧化剂催化苯胺氧化偶联反应的研究进展

高等学校化学学报 2024年第8期45卷 21-34页

作者：班志勇杨曹雨冯清殷国俊李国栋烟台大学化学化工学院烟台264005 中国科学院纳米系统与多级次制造重点实验室中国科学院纳米科学卓越创新中心国家纳米科学中心北京100190 中国科学院大学纳米科学与工程学院北京100049

偶氮苯和氧化偶氮苯类化合物在颜料、光学材料、荧光探针和光电器件等领域具有广泛的应用前景.目前,已发展了不同的催化剂和氧化剂用于苯胺氧化偶联制备偶氮苯及氧化偶氮苯类化合物,其中开发绿色环保的氧化体系一直是该研究领域的热点... 详细信息

偶氮苯和氧化偶氮苯类化合物在颜料、光学材料、荧光探针和光电器件等领域具有广泛的应用前景.目前,已发展了不同的催化剂和氧化剂用于苯胺氧化偶联制备偶氮苯及氧化偶氮苯类化合物,其中开发绿色环保的氧化体系一直是该研究领域的热点和难点问题.本文综合评述了分别以双氧水和氧气作为氧化剂时,催化苯胺选择性氧化制备偶氮苯及氧化偶氮苯类化合物的研究进展,同时探讨了苯胺氧化的机理,主要包括亚硝基苯中间体机理与自由基偶联机理.最后,总结了催化剂合成和催化机制方面存在的潜在问题和挑战,并对未来的研究方向进行了展望,从而为相关领域的发展提供借鉴.

关键词：苯胺选择性氧化偶联过氧化氢氧气偶氮类化合物

APPLICATION OF A NEURAL NETWORK PREDICTOR/CONTROLLER TO DYNAMIC POSITIONING OF FLOATING STRUCTURES

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Journal of Hydrodynamics 2003年第1期15卷 31-44页

作者： LeeTzung-hang caoyu-song DepartmentofMechanicalEngineering TamkangUniversityTamsuiTaiwanChina SchoolofNavalArchitectureandMarineEngineering UniversityofNewOrleansNewOrleansLA70115

An on-line training functional-link neural network predictor/controller fordynamic positioning of water surface structures is described in this paper. The on-line trainingneural network predictor acquires the knowledge about the system using a small number of samples ofthe latest system status measured on board of the structure. The trained function-link neuralnetwork is used with an optimal controller to control the output of the system. The accuracy androbustness of the on-line training predictor are demonstrated through the numerical simulations oftwo ship maneuvers. The on-line training neural network predictor/controller is applied to thedynamic positioning (station-keeping) of a ship in a uniform current with and without externalenvironmental disturbances. The results of the numerical simulations are very satisfactory.

关键词： on-line training neural network predictor/ controller dynamicpositioning

ESTIMATION OF ATMOSPHERIC INPUT OF MERCURY TO SOUTH LAKE AND JINGYUE POOL

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Chinese Geographical Science 2002年第1期12卷 86-89页

作者： FANGFeng－man caoyu－hong 等 ChangchunInstituteofGeography theChineseAcademyofSciencesChangchun130021P.R.China DepartmentofGeogaphy AnhuiNormalUniversityWuhu241000P.R.China

Taking South Lake and Jingyue Pool in Changchun as examples, we determined particulate Hg in ambient air and Hg concentration in precipitation. Results indicated that particulate Hg in air and Hg concentration in precipitation in both sites in nonheating period were lower than that in heating period, which is influenced by coal combustion. The annual particulate Hg concentrations of South Lake and Jingyue Pool were 0.254ng/m3 and 0.109ng/m3. The yearly average Hg concentrations in precipitation were 0.268μg/L(South Lake) and 0.108μg/L(Jingyue Pool). The higher particulate Hg concentration in air and Hg concentration in precipitation in South Lake than that of Jingyue Pool indicated that mercury deposition was influenced by anthropogenic sources(especially from coas combustion). Hg concentration in precipitation is related with particulate Hg in the atmosphere. Dry deposition fluxes were estimated by using dry deposition model on the base of particulate Hg concentrations in the atmosphere, they were 35.5μg/(m2.a) for South lake and 15.3μg/(m2.a) for Jingyue Pool. Combined with precipitation amount, wet deposition fluxes were estimated in these two sites, 152.2μg/(m2.a) for South Lake and 61.2μg/(m2.a) for Jingyue Pool. Atmospheric Hg deposition fluxes were 160.2g/a for South Lake and 328.62g/a for Jingyue Pool.

关键词： south lake jingyue pool atmospheric mercury precipitation depositionfluxes

A Novel Digital Soft-Start Circuit for DC-DC Switching Regulator

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A Novel Digital Soft-Start Circuit for DC-DC Switching Regul...

An Ontology-Based Service Matching Strategy in Grid Environments

2005 6th International Conference on ASIC

作者： Lai Xinquan Guo Jianping Yu Weixue caoyu Institute of Electronic CAD Xidian University

ISBN: (纸本)0780392108;9780780392106

＜正＞A new CMOS -compatible digital soft-start circuit for DC-DC switching regulator is presented in this paper,for which the technical is adopted to eliminate the inrush current and avoid the overshoot of the output ***’s fully integrated on chip,so that the external soft-start capacitor is not in need,which leads to the reduction of the required board space and component *** simulation shows that,while the system has an output voltage of 1.5V at a load of 6A,the envelop of inductor current increases placidly at approximately 1.43A/ms and output voltage increases about 16mV every cycle.

关键词： digital soft start DC-DC inrush current overshoot integrated on chip

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Wuhan University Journal of Natural Sciences 2004年第5期9卷 781-786页

作者： YINNan SHENDe-rong YUGe KOUYue NIETie-zheng caoyu SchoolofInformationScienceandEngineering.NortheasternUniversity.Shenyang110004.Liaoning.China

An efficient ontology-based service scarching scheme is put forward in this paper by introducing semantic information into grid systems. The ideas of ontology and OWL (Web ontology language) are applied to establish a uniform abstract concept model and standardization for grid services. We propose a general framework of ontology-based service discovery sub-system, which includes ontology storage module, context-based domain selection module and specific service matching module. Implementation policies are also presented in this paper. Key words ontology - grid - service matching - scmantic - service composition CLC number TP 393 Foundation item: Supported by High Technology Research and Development Program of China (2003AA414210) and National Natural Science Foundation of China (60173051)Biography: YIN Nan (1979-), male, Master student, research di rection: Web service, grid, distributed system.

关键词： ontology grid service matching scmantic service composition

DERIVATIONS ON DIFFERENTIAL OPERATOR ALGEBRA AND WEYL ALGEBRA

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Chinese Annals of Mathematics,Series B 1996年第2期17卷 199-212页

作者： CHEN caoyu Department of Mathematics, Shanghai Normal University, Shanghai 200234, China. 上海师范大学数学系上海

Let L be an n-dimensional nilpotent Lie algebra with a basis {x1,…,xn}, and every xiacts as a locally nilpotent derivation on algebra A. This paper shows that there exists a setof derivations {y1,…,yn} on U(L) such that (A#U(L))#k[yi,…,yn] is isomorphic to theWeyl algebra An(A). The author also uses the derivations to obtain a necessary and sufficientcondition for a finite dimensional Lie algebra to be nilpotent.

关键词： Crossed porduct Smash product Derivation Nilpotent Lie algebra Weyl algebra

离子液体界面修饰的高效稳定FAPbI_(3)钙钛矿太阳能电池

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物理化学学报 2024年第6期40卷 34-37页

作者： Yameen Ahmed 封想想高远基丁洋龙操玉 Mustafa Haider 李恒月李专黄誓成 Makhsud I.Saidaminov 阳军亮中南大学物理与电子学院超微结构与超快过程湖南省重点实验室长沙410083 中南大学粉末冶金国家重点实验室长沙410083 广西晶联光电材料有限公司广西柳州545036 中南大学材料科学与工程学院长沙410083 Department of Electrical&Computer Engineering University of Victoria3800 Finnerty RoadVictoriaBritish Columbia V8P 5C2Canada Department of Chemistry University of Victoria3800 Finnerty RoadVictoriaBritish Columbia V8P 5C2Canada

碘铅甲眯(FAPbI_(3))钙钛矿太阳能电池因其优异的光伏性能而受到广泛关注,但器件的长期稳定性仍然是FAPbI_(3)太阳能电池的关键问题。FAPbI_(3)黑色钙钛矿相在室温下会相变为黄色非钙钛矿相,且水分会加速这一相变。界面工程是提高钙钛... 详细信息

碘铅甲眯(FAPbI_(3))钙钛矿太阳能电池因其优异的光伏性能而受到广泛关注,但器件的长期稳定性仍然是FAPbI_(3)太阳能电池的关键问题。FAPbI_(3)黑色钙钛矿相在室温下会相变为黄色非钙钛矿相,且水分会加速这一相变。界面工程是提高钙钛矿太阳能电池稳定性的常用方法之一。作为绿色溶剂,离子液体被认为是有毒界面修饰剂的潜在替代品,这也提高了它们的商业可行性,并加速了它们在可再生能源市场的应用。本研究利用具有低挥发性、低毒性、高导电性和高热稳定性的离子液体1-乙基-3-甲基咪唑四氟硼酸盐(EMIM[BF_(4)])来修饰钙钛矿太阳能电池的电子传输层和钙钛矿层之间的界面。离子液体的引入不仅减少了界面缺陷,而且提高了钙钛矿薄膜的质量。密度泛函理论计算表明,离子液体与钙钛矿表面之间存在较强的界面相互作用,有利于降低钙钛矿表面缺陷态密度,稳定钙钛矿晶格。除钙钛矿薄膜缺陷外,溶液处理的SnO_(2)也存在表面缺陷。在SnO_(2)表面的缺陷产生缺陷态,也会导致能带对准问题和稳定性问题。密度泛函理论计算表明,有离子液体的表面间隙态比没有离子液体的表面间隙态小,这种减弱的表面间隙态表明表面区域载流子复合减少,有利于提高器件性能。因此,我们实现了功率转换效率大于22%的离子液体修饰的FAPbI_(3)钙钛矿太阳能电池(对照21%)。在相对湿度~20%的干箱中存放1800h以上后,冠军器件保留了初始状态的~90%,而控制器件降解为非钙钛矿黄色六方相(δ-FAPbI_(3))。

关键词： FAPbI_(3) 相稳定性 SnO_(2) 钙钛矿太阳能电池离子液体界面工程

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