检索结果-南通市图书馆

Space truss construction modeling based on on-orbit assembly motion feature

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Aeronautics 2024年第3期37卷 365-379页

作者： Changjie ZHAO Weizhong GUO meng chen Jiaxing HU Youcheng HAN Rongfu lin State Key Lab of Mechanical System and Vibration Shanghai Jiao Tong UniversityShanghai 200240China Institute of Aerospace System Engineering Shanghai Shanghai 201109China

More space truss construction has been planned to develop and utilize space *** trusses are designed in the way of large-scale,complex,modular,and on-orbit *** meet the upcoming challenge of large-scale space infrastructure construction,it is necessary to study space truss automation design and robotic *** paper proposes an ordinal finite screw adjacency matrix model(OFSAMM),focusing on the relationship between assembly motions,to express and compute a space truss *** this model,a space truss is abstracted as a set of ordered assembly motions,each of which is recorded as a finite screw as the basic element of the truss and its *** operation of truss transformation is also derived under this ***,the truss configuration,the assembly sequence,the truss sub-assembly,the truss components,and the on-orbit assembly task can be expressed and calculated in a unified model,which is calculated and stores the truss topology and assembly with the minimum storage *** the end of this paper,we introduce how to synthesize and optimize space truss design through two *** study will help to improve design ***,it provides a theoretical basis for the automatic construction of space truss structures,especially in the next stage.

关键词： Adjacency matrix Finite screw On-orbit construction modeling Space applications Space trusses Topology design

Efficient Spin-Flip between Charge-Transfer States for High-Performance Electroluminescence, without an Intermediate Locally Excited State

在线全文

学校读者我要写书评

暂无评论

Research 2024年第1期2023卷 339-349页

作者： Donghai Zhang Shanshan Jiang Xiaodong Tao Fulin lin lingyi meng Xu-lin chen Can-Zhong Lu State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhouFujian 350002China Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China FuzhouFujian 350108China Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials Xiamen Institute of Rare Earth MaterialsHaixi InstitutesChinese Academy of SciencesXiamenFujian 361021China University of Chinese Academy of Sciences Beijing 100049China

Thermally activated delayed fluorescence(TADF)materials with both high photoluminescence quantum yield(PLQY)and fast reverse intersystem crossing(RISC)are strongly desired to realize efficient and stable organic light-emitting diodes(OLEDs).Control of excited-state dynamics via molecular design plays a central role in optimizing the PLQY and RISC rate of TADF materials but remains ***,3 TADF emitters possessing similar molecular structures,similar high PLQYs(89.5%to 96.3%),and approximate energy levels of the lowest excited singlet states(S_(1)),but significantly different spin-flipping RISC rates(0.03×10^(6) s^(−1) vs.2.26×10^(6) s^(−1))and exciton lifetime(297.1 to 332.8μs vs.6.0μs)were systematically synthesized to deeply investigate the feasibility of spin-flip between charge-transfer excited states(^(3)CT–^(1)CT)transition.

关键词： transition lifetime desired

Azocalixarenes: a scaffold of universal excipients with high efficiency

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Science China Chemistry 2024年第5期67卷 1697-1706页

作者： Yu-Xin Yue Yi-lin lin meng-meng chen Han-Wen Tian Rong Ma Ze-Han Wang Fang-Yuan chen Yu-chen Pan Dong-Sheng Guo College of Chemistry State Key Laboratory of Elemento-Organic ChemistryKey Laboratory of Functional Polymer Materials(Ministry of Education)Frontiers Science Center for New Organic MatterCollaborative Innovation Center of Chemical Science and Engineering(Tianjin)Nankai UniversityTianjin 300071China

Excipients are important components of pharmaceutical preparations that affect their quality, safety, and efficacy. Macrocyclic receptors are a family of supramolecular excipients with several advantages, including molecular-level protection, small sizes,fast kinetics of host-guest recognition, and modular construction. With the continuous advances in the medical field, personalized and precision medicine requires the development of excipients with low dosages, integrated modifying effects, universality,and controlled release. To meet these requirements, we have developed a new family of macrocyclic excipients based on calixarenes by integrating their covalent(broad chemical design space) and noncovalent(wide range of substrates) ***, azocalixarenes(Azo CAs) were designed, showing high binding affinities to a broad spectrum of active pharmaceutical ingredients(APIs), selectivity to interferents, and responsiveness to hypoxic microenvironments. Due to their highly efficient and controllable recognition, Azo CAs serve as low-dose excipients for 30 APIs. Molecular encapsulation by Azo CAs results in the integrated modification of the physicochemical properties of APIs, including solubility, stability, bioavailability,and biocompatibility. Moreover, Azo CAs can be reduced by azoreductases overexpressed in hypoxic microenvironments,leading to the controlled release of APIs. Collectively, Azo CA excipients have broad application prospects for a series of diseases such as enteritis, arthritis, stroke, cancer, bacterial infection and kidney injury, with diverse therapeutic modalities,including chemotherapy, photodynamic therapy, photothermal therapy, immunotherapy, boron neutron capture therapy, radiotherapy, fluorescence imaging, and their combinations.

关键词： supramolecular chemistry host-guest systems excipient calixarene molecular recognition

Fatigue Crack Initiation and Propagation Dominated by Crystallographic Factors in TiB/near α-Ti Composite

在线全文

学校读者我要写书评

暂无评论

Acta Metallurgica Sinica(English Letters) 2024年第5期37卷 763-776页

作者： Fanchao meng Rui Zhang Shuai Wang Fengbo Sun Run chen Lujun Huang lin Geng School of Materials Science and Engineering Harbin Institute of TechnologyHarbin 150001China Waikato Centre for Advanced Materials and Manufacturing School of EngineeringUniversity of WaikatoHamilton 3240New Zealand State Key Laboratory of Advanced Welding and Joining Harbin Institute of TechnologyHarbin 150001China

Discontinuously reinforced titanium matrix composites(DRTMCs)with a network structure have been extensively researched due to their superior combination of strength and ***,their fatigue performance has remained *** order to elucidate the fatigue behavior of DRTMCs,a tension-tension fatigue test was performed on a TiB/nearα-Ti composite with network *** results showed that the variability of fatigue lifetime increased as the stress level *** analysis indicated that fatigue crack initiation was associated with facet formation,while the subsequent propagation was hindered by the network structure comprising TiB whiskers and *** characterization further revealed that facets formed due to a combination of shear and normal *** reduction in fatigue lifetime was attributed to an increase in the effective slip length,which was influenced by the orientation of grains near the crack-initiation sites toward basal slip in the life-limiting *** in situ observation suggested that the crack initiation was facilitated by both basal and prismatic slip ofα-Ti as well as fracture of *** propagation was found to be associated with basal and prismatic slip systems with high Schmid factors,regardless of whether the crack was intergranular or intragranular.

关键词： Titanium matrix composite TiBw Fatigue lifetime variability Crack initiation Crack propagation

Kinetic-boosted CO_(2) electroreduction to formate via synergistic electric-thermal field on hierarchical bismuth with amorphous layer

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2024年第3期90卷 233-243,I0007页

作者： Bing Yang Junyi Zeng Zhenlin Zhang lin meng Donglin Shi Liang chen Youju Huang College of Material Chemistry and Chemical EngineeringKey Laboratory of Organosilicon Chemistry and Material TechnologyMinistry of EducationHangzhou Normal UniversityHangzhou 311121ZhejiangChina State Key Laboratory of Metastable Materials Science and Technology College of Materials Science and EngineeringYanshan UniversityQinhuangdao 066004HebeiChina

Electrocatalytic converting CO_(2) into chemical products has emerged as a promising approach to achieving carbon ***,we report a bismuth-based catalyst with high curvature terminal and amorphous layer which fabricated via two-step electrodeposition achieves stable formate output in a wide voltage window of 600 *** Faraday efficiency(FE) of formate reached up to 99.4% at-0.8 V *** and it remained constant for more than 92 h at-15 mA cm^(-2).More intriguingly,FE formate of95.4% can be realized at a current density of industrial grade(-667.7 mA cm^(-2)) in flow *** special structure promoted CO_(2) adsorption and reduced its activation energy and enhanced the electric-thermal field and K^(+) enrichment which accelerated the reaction *** situ spectroscopy and theoretical calculation further confirmed that the introduction of amorphous structure is beneficial to adsorpting CO_(2)and stabling*OCHO *** work provides special insights to fabricate efficient electrocatalysts by means of structural and crystal engineering and makes efforts to realize the industrialization of bismuth-based catalysts.

关键词： CO_(2) electroreduction Hierarchical bismuth Amorphous layer Electric-thermal field Kinetic-boosting

A novel long persistent luminescent material CaGeO_(3):Tb^(3+)with photo-stimulation properties

在线全文

学校读者我要写书评

暂无评论

Journal of Rare Earths 2024年第7期42卷 1233-1239,I0002页

作者： Wei meng Xiaoyan Fu Tongyan lin Zewen Liu Naihui chen Jiaxu Zhang Runyao Liu Rujun Yang Long chen Hongwu Zhang School of Chemistry and Material Sciences Ludong UniversityYantai264025China College of Materials Science and Engineering Xiamen University of TechnologyXiamen361024China College of Materials Xiamen UniversityXiamen361005China

A novel green long afterglow material CaGeO_(3):Tb^(3+)was synthesized by high temperature solid phase *** to the experimental results,CaGeO_(3):Tb^(3+)is a green long persistent luminescent(LPL)material with excellent ***_(3):Tb^(3+)shows LPL emission peak at 442,490.9,548.7,588.5 and 623.8 nm,corresponding to ^(5)D_(3) to^(7)F_(4)and^(5)D_(4)to^(7)F_(J)(J=6,5,4,3)transitions of Tb^(3+).Its CIE coordinates are(0.27,0.50),indicating that the afterglow emission is close to the light of green *** addition,after the excitation source is turned off,the afterglow time is longer than 90 *** an interval of 7 h,the photo-stimulation luminescence(PSL)can be observed by using 980 nm laser cyclic *** thermoluminescence(ThL)results show that there are three types of traps in the material and their depths are 0.666,0.774 and 0.892 eV respectively,which are caused by the doping of Tb^(3+).All the results show that CaGeO_(3):Tb^(3+)is an excellent long afterglow luminescent material.

关键词： Long persistent luminescence Photo-stimulation Trap CaGeO_(3):Tb^(3+) Rare earths

Positive effects of biochar application and Rhizophagus irregularis inoculation on mycorrhizal colonization,rice seedlings and phosphorus cycling in paddy soils

在线全文

学校读者我要写书评

暂无评论

Pedosphere 2024年第2期34卷 361-373页

作者： Yixuan chen Zhonghua WEN Jun meng Zunqi LIU Jialong WEI Xiyu LIU Ziyi GE Wanning DAI Li lin Wenfu chen National Biochar Institute Shenyang Agricultural UniversityShenyang 110866China Key Laboratory of Biochar and Soil Improvement Ministry of Agriculture and Rural AffairsShenyang 110866China

Phosphorus(P)is an essential element for plant growth but is often limiting in ecosystems;therefore,improving the P fertilizer use efficiency is *** and arbuscular mycorrhizal fungi(AMF)may enhance P cycling in paddy soils that contain high content of total P but low content of available P(AP).In this study,the effects of biochar addition and Rhizophagus irregularis inoculation on the organic and inorganic P contents and phosphatase activities in paddy soils,rice seedling growth,and AMF colonization were *** with no biochar addition,biochar addition enhanced the percentage of spore germination at day 7,hyphal length,most probable number,and mycorrhizal colonization rate of *** by 32%,662%,70%,and 28%on average,*** and *** altered soil P cycling and *** and ***,either individually or in combination,increased soil AP content by 2%–48%.Rice seedlings treated with biochar and *** produced greater biomass,improved root morphology,and increased nutrient uptake compared with those of the control without biochar and *** results suggest that combined application of biochar and *** is beneficial to rice cultivation in paddy soils with high content of total P but low content of AP.

关键词： arbuscular mycorrhizal fungi available P phosphorus fraction rice husk biochar seedling growth spore germination

Overview of SOI materials technology in China

在线全文

学校读者我要写书评

暂无评论

Nuclear Science and Techniques 2005年第6期16卷 330-334页

作者： chen meng WANG Xi lin cheng-Lu Shanghai Simgui Technology Co. Ltd 200 Puhui Road Jiading Shanghai 201821 Shanghai Institute of Microsystem and Information Technology the Chinese Academy of Sciences 865 Changning Road Shanghai 200050

In recent years, novel structure SOI materials have been fabricated successfully. Also, SiGeOI (SGOI)material, an ideal substrate for realizing strained-silicon structures, has been investigated by modified SIMOX *** 2002, the 100 mm, 125 mm and 150 mm SIMOX wafers have been successfully produced by ShanghaiSimgui Technology Co. Ltd, a commercial spin-off of Shanghai Institute of Microsystem and Information Technology(SIMIT), Chinese Academy of Sciences (CAS), and shipped to the semiconductor industry worldwide. This paperpresents an outlook for R & D on SOI technologies, and the recent status and future prospect of SIMOX wafers inChina.

关键词： SOI技术硅结构离子注入技术半导体

A Dynamic Covalent Bonding-based Nanoplatform for Intracellular Co-Delivery of Protein Drugs and Chemotherapeutics with Enhanced Anti-Cancer Effect

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Polymer Science 2024年第5期42卷 559-569,I0005页

作者： Sai-Nan Liu Jia-Hui meng Li-Yun Cui Hua chen lin-Qi Shi Ru-Jiang Ma Key Laboratory of Functional Polymer Materials of Ministry of Education Institute of Polymer ChemistryTianjin Key Laboratory of Functional Polymer MaterialsState Key Laboratory of Medicinal Chemical BiologyFrontiers Science Center for New Organic MatterCollege of ChemistryNankai UniversityTianjin300071China Haihe Laboratory of Sustainable Chemical Transformations Tianjin300192China

Efficient intracellular delivery of protein drugs is critical for protein *** combination of protein drugs with chemotherapeutics represents a promising strategy in enhancing anti-cancer ***,co-delivery systems for efficient delivery of these two kinds of drugs are still lacking because of their different ***,we show a well-designed delivery system based on dynamic covalent bond for efficient intracellular co-delivery of ribonuclease A(RNase A)and doxorubicin(DOX).Two polymers,PEG-b-P(Asp-co-AspDA)and PAE-b-P(Asp-co-AspPBA),and two 2-acetylphenylboronic acid(2-APBA)-functionalized drugs,2-APBA-RNase A and 2-APBA-DOX,self-assemble into mixed-shell nanoparticles(RNase A/DOX@MNPs)via dynamic phenylboronic acid(PBA)-catechol bond between PBA and dopamine(DA)*** PBA-catechol bond endows the nanoparticles with high stability and excellent stimulus-responsive drug release *** the slight acidic environment at tumor tissue,RNase A/DOX@MNPs are positively charged,promoting their *** cellular uptake into endosome,further protonation of PAE chains leads to the rupture of endosomes because of the proton sponge effect and the cleavage of PBA-catechol bond promotes the release of two *** cytoplasm,the high level of GSH removed the modification of 2-APBA on *** restored RNase A and DOX show a synergistic and enhanced antic-cancer *** system may be a promising platform for intracellular co-delivery of protein drugs and chemotherapeutics.

关键词： Drug co-delivery Combination therapy Dynamic covalent bond