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Research on shell-side heat and mass transfer with multi-component in LNg spiral-wound heat exchanger under sloshing conditions

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Petroleum Science 2024年第2期21卷 1333-1345页

作者： Xue-Ping Du guang-Lei Yu ya-cheng Xu Zhi-Jie chen Nai-Liang Li Huan-guang Wang School of Low-carbon Energy and Power Engineering China University of Mining and TechnologyXuzhou221116JiangsuChina Key Laboratory of Thermo-Fluid Science and Engineering MOEXi'an Jiaotong UniversityXi'an710049ShaanxiChina Xi'an Aerospace Propulsion Test Technology Institute Xi'an710100ShaanxiChina

The spiral-wound heat exchanger(SWHE) is the primary low-temperature heat exchanger for large-scale LNg plants due to its high-pressure resistance, compact structure, and high heat exchange efficiency. This paper studied the shell-side heat and mass transfer characteristics of vapor-liquid two-phase mixed refrigerants in an SWHE by combining a multi-component model in FLUENT software with a customized multicomponent mass transfer model. Besides, the mathematical model under the sloshing condition was obtained through mathematical derivation, and the corresponding UDF code was loaded into FLUENT as the momentum source term. The results under the sloshing conditions were compared with the relevant parameters under the steady-state condition. The shell-side heat and mass transfer characteristics of the SWHE were investigated by adjusting the component ratio and other working conditions. It was found that the sloshing conditions enhance the heat transfer performance and sometimes have insignificant effects. The sloshing condition is beneficial to reduce the flow resistance. The comprehensive performance of multi-component refrigerants has been improved and the improvement is more significant under sloshing conditions, considering both the heat transfer and pressure *** results will provide theoretical support for the research and design of multi-component heat and mass transfer enhancement of LNg SWHE under ocean sloshing conditions.

关键词： Spiral-wound heat exchanger Sloshing conditions Two-phase flow Multi-component Heat and mass transfer

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An ultra-porous g-c_(3)N_(4) micro-tube coupled with MXene(Ti_(3)c_(2)TX)nanosheets for efficient degradation of organics under natural sunlight

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Journal of Environmental Sciences 2024年第3期137卷 258-270页

作者： Zongyang ya Qiyou Wang Jingjin cai Peng Wang Xinyu Jiang Zhiyin cai Shanglin Xiang Tingwei Wang Dongyu cai college of Materials Science&Engineering Nanjing Tech University30 South PuZhu RoadNanjing 211816China Key Laboratory of Flexible Electronics(KLOFE)&Institute of Advanced Materials(IAM) Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM)Nanjing Tech University30 South PuZhu RoadNanjing 211816China

It remains as a challenge for realizing efficient photo-responsive catalysts towards largescale degradation of organic pollutants under natural *** work reports a new pore engineering strategy for creating ultra-porous g-c_(3)N_(4) micro-tubes with an unprecedentedly high specific surface area of 152.96 m^(2)/*** is mainly associated with releasing internal vapor pressure in the autoclave where the hydrothermal treatment of the urea/melamine mixture is *** by microscopic observation,porosity measurement and spectroscopic characterization,it is found that releasing the pressure at halfway of hydrothermal process is vital for forming exfoliated rod-like precursors and the de-aggregation of these rods presents substantial benefits on the production of mesopores on g-c_(3)N_(4) microtubes during the calcination of *** offers a large number of reactive sites required by photocatalytic *** these micro-tubes with Ti_(3)c_(2)T_(X) nanosheets via electrostatic interaction yields a 1D/2D heterojunction with a close interfacial *** addition of metallically conductive Ti_(3)c_(2)T_(X) nanosheets accelerates the separation between electrons and holes,and also enhances the light *** these merits of structural design lead to forming a group of highly efficient catalysts demonstrating an excellent photocatalytic degradation rate of k=0.0560 min^(-1)for RhB dyes under 100 mW/cm~2 visible light radiation that micks sunlight *** laboratory valuation is further supported by an outdoor test that shows a fast degradation rate of 0.0744 min^(-1)under natural sunlight.

关键词： carbon nitride MXene Heterojunction Photocatalysis

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Shexiang Tongxin Dropping Pill Promotes Angiogenesis through VEgF/eNOS Signaling Pathway on Diabetic coronary Microcirculation Dysfunction

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chinese Journal of Integrative Medicine 2024年第10期30卷 886-895页

作者： cUI Xin-yu LIU Tian-hua BAI ya-li ZHANg Meng-di LI guo-dong ZHANg Yu-ting YUAN Yue-ying ZHANg ya-wen YU Li-shuang HAN Li-na WU yan School of Traditional chinese Medicine Beijing University of Chinese Medicine Key Laboratory of Traditional chinese Medicine Syndrome and Formula Ministry of Education Beijing University of Chinese Medicine Beijing Research Institute of chinese Medicine Beijing University of Chinese Medicine

Objective: To study the effect of Shexiang Tongxin Dropping Pill(STDP) on angiogenesis in diabetic cardiomyopathy mice with coronary microcirculation dysfunction(cMD). Methods: According to a random number table, 6 of 36 SPF male c57BL/6 mice were randomly selected as the control group, and the remaining 30 mice were injected with streptozotocin intraperitoneally to replicate the type 1 diabetes model. Mice successfully copied the diabetes model were randomly divided into the model group, STDP low-dose group [15 mg/(kg·d)], medium-dose group [30 mg/(kg·d)], high-dose group [60 mg/(kg·d)], and nicorandil group [15 mg/(kg·d)], 6 in each group. The drug was given by continuous gavage for 12 weeks. The cardiac function of mice in each group was detected at the end of the experiment, and coronary flow reserve(cFR) was detected by chest Doppler technique. Pathological changes of myocardium were observed by hematoxylin-eosin staining, collagen fiber deposition was detected by masson staining, the number of myocardial capillaries was detected by platelet endothelial cell adhesion molecule-1 staining, and the degree of myocardial hypertrophy was detected by wheat germ agglutinin staining. The expression of the vascular endothlial growth factor(VEgF)/endothelial nitric oxide synthase(eNOS) signaling pathway-related proteins in myocardial tissue was detected by Western blot. Results: compared with the model group, medium-and high-dose STDP significantly increased the left ventricular ejection fraction and left ventricular fraction shortening(Pcardiac muscle structure, reduced myocardial fibrosis, reduced myocardial cell area, increased capillary density, and increased cFR level(all Pgh-dose STDP could significantly increase the expression of VEgF and promote the phosphorylation of vascular endothelial growth factor receptor 2, phosphoinositide 3-kinase, protein kinase B, and eNOS(Pco

关键词： Shexiang Tongxin Dropping Pill angiogenesis coronary microcirculation dysfunction diabetic cardiomyopathy type 1 diabetes

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Plutonium utilization in a small modular molten-salt reactor based on a batch fuel reprocessing scheme

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Nuclear Science and Techniques 2024年第4期35卷 15-28页

作者： Xue-chao Zhao Rui yan gui-Feng Zhu ya-Fen Liu Jian guo Xiang-Zhou cai yang Zou Shanghai Institute of Applied Physics Chinese Academy of SciencesShanghai 201800China cAS Innovative Academies in TMSR Energy System Chinese Academy of SciencesShanghai 201800China University of chinese Academy of Sciences Beijing 100049China

A molten salt reactor(MSR)has outstanding features considering the application of thorium fuel,inherent safety,sustainability,and resistance to ***,fissile material^(233)U is significantly rare at the current stage,thus it is difficult for MSR to achieve a pure thorium-uranium fuel ***,using plutonium or enriched uranium as the initial fuel for MSR is more *** this study,we aim to verify the feasibility of a small modular MSR that utilizes plutonium as the starting fuel(SM-MSR-Pu),and highlight its advantages and ***,the structural design and fuel management scheme of the SM-MSR-Pu were ***,the neutronic characteristics,such as the graphite-irradiation lifetime,burn-up performance,and coefficient of temperature reactivity were calculated to analyze the physical characteristics of the *** results indicate that plutonium is a feasible and advantageous starting fuel for a SM-MSR;however,there are certain shortcomings that need to be *** a 250 MWth SM-MSR-Pu,approximately 288.64 kg^(233)U of plutonium with a purity of greater than 90% is produced while 978.00 kg is burned every ten *** temperature reactivity coefficient decreases from -4.0 to -6.5 pcm K^(-1) over the 50-year operating time,which ensures a long-term safe ***,the amount of plutonium and accumulation of minor actinides(MAs)would increase as the burn-up time increases,and the annual production and purity of^(233)U will *** achieve an optimal burn-up performance,setting the entire operation time to 30 years is ***,more than 3600 kg of plutonium eventually accumulate in the *** research is required to effectively utilize this accumulated plutonium.

关键词： Molten salt fuel Plutonium utilization ^(233)U TRUs mole fraction Temperature feedback coefficient

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Assessment of hydraulic performance changes of Dongting Lake after the Three gorges Reservoir impoundment by a novel semi-empirical approach

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Journal of geographical Sciences 2024年第8期34卷 1537-1557页

作者： SUN Zhaohua LI Zhiqing cHEN Li FAN Jiewei LIU ya State Key Laboratory of Water Resources Engineering and Management Wuhan UniversityWuhan 430072China Yellow River Water&Hydropower Development group co. Ltd.Jiyuan 459017HenanChina changjiang River Scientific Research Institute Wuhan 430010China

Floodplain lakes are important water storage areas in lowland regions that often undergo geomorphologic evolution,and timely topographic data are generally *** this study,to assess the impacts of lakebed deformation on hydraulic performance in Dongting Lake,a set of semi-empirical methods was proposed to establish performance graphs(Pgs)using only hydrological *** methods were used to evaluate the changes in water level,storage capacity,and flood detention ability in Dongting Lake caused by topographic adjustment after the Three gorges Reservoir *** methods showed that Pgs can effectively simulate the water level and outflow processes of Dongting Lake with Nash-Sutcliffe efficiency coefficients(NSEs)above 0.9.A comparison of the estimated water level and discharge using Pgs from different periods suggested that bed erosion in Dongting Lake caused water level decreases of 0.18 m and 0.32 m during the flood and dry seasons,*** the magnitude of erosion at high elevations in the lake is small,the impacts of bed adjustment on the storage capacity and flood detention ability are not currently *** study showed that the hydraulic performance of a floodplain lake can be evaluated independently of topographic data under the condition of no reverse flows or negative watersurface slopes.

关键词： Dongting Lake hydraulic performance graph bed adjustment semi-empirical approach backwater effect

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In-situ interfacial passivation and self-adaptability synergistically stabilizing all-solid-state lithium metal batteries

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Journal of Energy chemistry 2024年第1期88卷 282-292,I0007页

作者： Huanhui chen Xing cao Moujie Huang Xiangzhong Ren Yubin Zhao Liang Yu ya Liu Liubiao Zhong Yejun Qiu Shenzhen Engineering Lab of Flexible Transparent conductive Films School of Materials Science and EngineeringHarbin Institute of TechnologyShenzhen 518055GuangdongChina guangdong Provincial Key Laboratory of Semiconductor Optoelectronic Materials and Intelligent Photonic Systems School of Materials Science and EngineeringHarbin Institute of TechnologyShenzhen 518055GuangdongChina college of chemistry and Environmental Engineering Shenzhen UniversityShenzhen 518060GuangdongChina School of Resource and Environmental Sciences Wuhan UniversityWuhan 430072HubeiChina

The function of solid electrolytes and the composition of solid electrolyte interphase(SEI)are highly significant for inhibiting the growth of Li ***,we report an in-situ interfacial passivation combined with self-adaptability strategy to reinforce Li_(0.33)La_(0.557)TiO_(3)(LLTO)-based solid-state ***,a functional SEI enriched with LiF/Li_(3)PO_(4) is formed by in-situ electrochemical conversion,which is greatly beneficial to improving interface compatibility and enhancing ion *** the polarized dielectric BaTiO_(3)-polyamic acid(BTO-PAA,BP)film greatly improves the Li-ion transport kinetics and homogenizes the Li *** expected,the resulting electrolyte offers considerable ionic conductivity at room temperature(4.3 x 10~(-4)S cm^(-1))and appreciable electrochemical decomposition voltage(5.23 V)after electrochemical *** Li-LiFePO_(4) batteries,it shows a high specific capacity of 153 mA h g^(-1)at 0.2c after 100 cycles and a long-term durability of 115 mA h g^(-1)at 1.0 c after 800 ***,a stable Li plating/stripping can be achieved for more than 900 h at 0.5 mA cm^(-2).The stabilization mechanisms are elucidated by ex-situ XRD,ex-situ XPS,and ex-situ FTIR techniques,and the corresponding results reveal that the interfacial passivation combined with polarization effect is an effective strategy for improving the electrochemical *** present study provides a deeper insight into the dynamic adjustment of electrode-electrolyte interfacial for solid-state lithium batteries.

关键词： Solid-state lithium batteries composite solid electrolyte In-situ polymerization Interfacial passivation layer Self-adaptability

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copper-based electro-catalytic nitrate reduction to ammonia from water:Mechanism,preparation,and research directions

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Environmental Science and Ecotechnology 2024年第4期20卷 42-62页

作者： Jinshan Wei Yi Li Hexing Lin Xihui Lu chucheng Zhou ya-yun Li Shenzhen Key Laboratory of Special Functional Materials&Shenzhen Engineering Laboratory for Advance Technology of ceramics College of Materials Science and EngineeringShenzhen UniversityShenzhen518060PR China

global water bodies are increasingly imperiled by nitrate pollution,primarily originating from industrial waste,agricultural runoffs,and urban *** escalating environmental crisis challenges traditional water treatment paradigms and necessitates innovative ***-catalysis,especially utilizing copper-based catalysts,known for their efficiency,cost-effectiveness,and eco-friendliness,offer a promising avenue for the electro-catalytic reduction of nitrate to *** this review,we systematically consolidate current research on diverse copper-based catalysts,including pure cu,cu alloys,oxides,single-atom entities,and ***,we assess their catalytic performance,operational mechanisms,and future research directions to find effective,long-term solutions to water purification and ammonia ***-catalysis technology shows the potential in mitigating nitrate pollution and has strategic importance in sustainable environmental *** to the application,challenges regarding complexity of the real water,the scale-up of the commerical catalysts,and the efficient collection of produced NH3 are still *** reseraches of catalyst specially on long term stability and in situ mechanisms are proposed.

关键词： Water treatment Nitrate removal Electrocatalysis cu catalysts Ammonia synthesis

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Association between childhood obesity and gut microbiota:16S rRNA gene sequencing-based cohort study

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World Journal of gastroenterology 2024年第16期30卷 2249-2257页

作者： Xu-Ming Li Qing Lv ya-Jun chen Lu-Biao yan Xin Xiong Laboratory Department Nanjing Medical University Affiliated Obstetrics and Gynecology Hospital(Nanjing Maternal and Child Health Hospital)Nanjing 210004Jiangsu ProvinceChina Department of Pediatrics Shenzhen University General HospitalShenzhen 518055Guangdong ProvinceChina Department of Inspection Division Women’s Hospital of Nanjing Medical University(Nanjing Maternity and Child Health Care Hospital)Nanjing 210004Jiangsu ProvinceChina Department of Pediatrics Women’s Hospital of Nanjing Medical University(Nanjing Maternity and Child Health Care Hospital)Nanjing 210004Jiangsu ProvinceChina Department of Neonatology Chenzhou First People’s HospitalChenzhou 423000Hunan ProvinceChina

BAc.gROUND This study aimed to identify characteristic.gut genera in obese and normal-weight children(8-12 years old)using 16S rDNA *** research aimed to provide insights for mechanistic studies and prevention strategies for childhood *** normal-weight and thirty age-and sex-matched obese children were *** and body measurements were collected,and fecal samples underwent 16S rDNA *** differences in body mass index(BMI)and body-fat percentage were observed between the *** of gut microbiota diversity revealed lowerα-diversity in obese *** in gut microbiota composition were found between the two *** and Firmicutes were more abundant in the obese group,while Bacteroides and Sanguibacteroides were more prevalent in the control *** To identify the characteristic.gut genera in obese and normal-weight children(8-12-year-old)using 16S rDNA sequencing,and provide a basis for subsequent mechanistic studies and prevention strategies for childhood *** Thirty each normal-weight,1:1 matched for age and sex,and obese children,with an obese status from 2020 to 2022,were included in the control and obese groups,*** information was collected through questionnaires and body measurements were obtained from both obese and normal-weight *** samples were collected from both groups and subjected to 16S rDNA sequencing using an Illumina MiSeq sequencing platform for gut microbiota diversity *** Significant differences in BMI and body-fat percentage were observed between the two *** Ace and chao1 indices were significantly lower in the obese group than those in the control group,whereas differences were not significant in the Shannon and Simpson ***-Wallis tests indicated significant differences in unweighted and weighted UniFrac distances between the gut microbiota of normal-weight and obese children(Pggest

关键词： childhood obesity gut microbiota 16S rDNA sequencing Diversity analysis genus identification Body mass index

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Enhanced crystallization of Poly(butylene adipate-co-terephthalate)by a Self-assembly Nucleating Agent

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chinese Journal of Polymer Science 2024年第5期42卷 663-674,I0010页

作者： cheng Zhou Kun chen Zi-Heng Zhang Meng-Fan Jing chun-Tai Liu chang-Yu Shen ya-Ming Wang State Key Laboratory of Structural Analysis Optimization and CAE Software for Industrial EquipmentNational Engineering Research Center for Advanced Polymer Processing TechnologyZhengzhou UniversityZhengzhou450002China

Poly(butylene adipate-co-terephthalate)(PBAT)is a promising biodegradable flexible polymer but suffers from slow crystallization rate,making it less attractive for some applications like the injection-molded products in comparison with low-density polyethylene(LDPE).This work aimed to accelerate the crystallization of PBAT by adding a self-assembly nucleating agent octamethylenedicarboxylic dibenzoylhydrazide(OMBH).PBAT/OMBH composites with various OMBH contents(0 wt%,0.5 wt%,0.7 wt%,1 wt%,2 wt%,3 wt%and 5 wt%)were prepared through *** effect of OMBH on the crystallization behavior,morphologies and mechanical properties of PBAT was *** highest nucleation efficiency value of 59.6%was achieved for PBAT with 0.7 wt%OMBH,much higher than that of 22.7%for PBAT with 0.7 wt%*** force microscopy results showed that OMBH formed fine fibers and induced the formation of transcrystalline layers of *** transform infrared spectroscopy(FTIR)combined with two-dimensional correlation spectra suggested that the intermolecular dipole-dipole N—H…O=c interactions but not hydrogen bond between OMBH and PBAT promoted the crystallization of PBAT in the initial period of *** presence of OMBH did not change the crystal form of PBAT but had positive contribution in enhancing its crystallinity and mechanical *** work is essential for preparing PBAT with high crystallization rate,enhancing its potential applications in injection-molded products.

关键词： Poly(butylene adipate-co-terephthalate) Biodegradable Self-assembly nucleating agent crystallization

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clinical analysis of 12 cases of ovarian neuroendocrine carcinoma

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World Journal of clinical cases 2024年第6期12卷 1111-1119页

作者： Xiao-Yu Xing Wei Zhang Li-ya Liu Li-Ping Han Department of gynecology The First Affiliated Hospital of Zhengzhou UniversityZhengzhou 450000Henan ProvinceChina

BAc.gROUND Neuroendocrine neoplasms of the female genital tract are *** To enhance our clinical understanding of neuroendocrine carcinoma(NEc)of the *** A retrospective review was conducted on 12 patients diagnosed with NEc of the ovary,analyzing clinicopathological characteristics,treatment modalities,and survival *** The median age at diagnosis was 34.5 years(range:20 to 62 years).Among the 12 cases,9 were small cell carcinoma of the ovary and 3 were large cell *** cases were stage I tumors,one case was stage IV,and six cases were stage *** patients underwent surgery as part of their *** patients received adjuvant *** the 12 patients,one patient received radiotherapy,and one patient with a BRcA2 mutation was administered PARP inhibitor maintenance after *** median progression-free survival was 13 months,and the median overall survival was 19.5 *** cases remained disease-free,while eight cases experienced tumor recurrence,including three cases that resulted in death due to disease *** NEc of the ovary is a rare condition that is more common in women of childbearing age and is associated with aggressive behavior and poor clinical *** resection remains the mainstay of treatment,with some patients benefiting from adjuvant chemoradiation therapy.

关键词： Neuroendocrine carcinoma Ovary Pathology Treatment

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