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Journal of Thermal Science 2024年第4期33卷 1554-1563页

作者： JI Zengcai SONG Guoliang TANG Zihua sun Liwei State Key Laboratory of coal conversion Institute of Engineering ThermophysicsChinese Academy of SciencesBeijing100190China University of chinese Academy of Sciences Beijing100049China Dalian National Laboratory for clean Energy Dalian116023China

Solid particle heat storage technology offers a potential solution to the challenges posed by the significant growth of renewable energy sources,particularly in terms of grid security and ***,it has the capability to optimize the energy utilization efficiency of the power *** order to investigate the transport regulation characteristics of solid particles in the thermal storage and release system of a circulating fluidized bed(cFB),a test rig with a capacity of 0.1 MW(th)was *** rig was utilized to systematically study the transport regulation characteristics of solid particles under the double U-type valve feed structure and U-type valve discharge *** experimental findings indicate that the system's design enables efficient and rapid storage and release of solid particles in the *** air distribution mode,specifically the double U-type valve feed structure and the U-type valve discharge structure,significantly influence the feed and discharge characteristics of the ash storage *** was observed that the impact of loose air on these characteristics is more substantial than that of the return air,irrespective of the feed structure or the return *** adjusting the feed and discharge rate,it is recommended to adopt a scheme that involves coarse adjustment through loose air and fine adjustment through return air.

关键词： solid particle thermal storage air distribution mode transport regulation

comprehensive Exergoeconomic Analysis and Optimization of a Novel Zero-carbon-Emission Multi-Generation System based on carbon Dioxide c.c.e

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Journal of Thermal Science 2024年第3期33卷 1065-1081页

作者： sun Yan LI Hongwei WANG Di DU changhe School of Energy and Power Engineering Northeast Electric Power UniversityJilin132012China School of Automation Engineering Northeast Electric Power UniversityJilin132012China Xi’an Institute of Electromechanical Information Technology Xi’an710065China

This paper aims to conduct a comprehensive exergoeconomic analysis of a novel zero-carbon-emission multi-generation system and propose a fast optimization method combined with machine *** detailed exergoeconomic analysis of a novel combined power,freshwater and cooling multi-generation system is performed in this *** exergoeconomic analysis model is established by exergy flow theory.A comprehensive exergy,exergoeconomic and environmental analysis is carried *** critical decision variables are researched to bring out effects on the multi-generation system exergoeconomic performance.A novel fast optimization method combining genetic algorithm and Bagging neural network is *** advanced nature comparison is made between the proposed system and four similar *** display that increasing the turbine inlet temperature can improve exergy efficiency and decrease the total product unit *** multi-generation system exergy destruction directly determines exergy efficiency and total exergy destruction cost *** total product unit cost in the cost optimal design case is reduced by 7.7%and 25%,respectively,compared with exergy efficiency optimal design case and basic design *** with four similar cases,the proposed multi-generation system has great advantages in thermodynamic performance and exergoeconomic *** paper can provide research methods and ideas for performance analysis and fast optimization of multi-generation system.

关键词： waste heat recovery exergoeconomic analysis supercritical carbon dioxide optimization machine learning

Synthesis of multifunctional additives for solid propellants:Structure,properties and mechanism

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Defence Technology（防务技术） 2024年第3期33卷 308-316页

作者： Pingan Zhang Lina sun Jianmin Yuan Jianru Deng college of chemistry and chemical Engineering Hunan UniversityChangsha 410082PR China college of Material Science and Engineering Hunan UniversityChangsha 410082PR China Hu Bei Sanjiang Aerospace Jianghe chemical Technology co. LtdYichang 444200PR China

To simplify the composite propellant formulation and address the current issue of the single-functionality present in existing additives,the multi-cyano,amine-based polybutadiene(AEHTPB-cN)was prepared based on AEHTPB by adopting appropriate synthesis *** replacing 10% of HTPB binder in the propellant formulation,it can effectively enhance the interfacial bond strength between the propellant binder matrix and solid fillers(AP(ammonium perchlorate)and RDX(c.c.otrimethylene-trinitramine)),the mechanical properties of the HTPB/AP/RDX/Al propellant were superior to blank control propellant with an improvement of 35.4% in tensile strength,62.0% enhancement in elongation at break,and reduce the propellant burn rate by 10.7% with any energy *** function mechanism of AEHTPB-cN was systematically elucidated through experiments and computer simulation *** results show that the tertiary amine group in AEHTPB-cN can react with AP to form ammonium ionic bonds,and the hydroxyl and cyano groups can form hydrogen bonding interactions with AP,which enables AEHTPB-cN to be firmly adsorbed on the AP surface through chemical and physical *** RDX,the interfacial bonding effect of AEHTPB-cN is attributed to their ability to form c-H···N≡c weak hydrogen bonding interaction between the cyano group and RDX methylene group.

关键词： Hydroxyl-terminated polybutadiene(HTPB) HTPB propellant chemical modification Bonding agent Mechanism

Effect of structural characteristics on the transport characteristics of solid particles in the thermal storage and release system of circulating fluidized bed

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Particuology 2024年第6期89卷 22-31页

作者： Zengcai Ji Guoliang Song Zihua Tang Liwei sun Institute of Engineering Thermophysics Chinese Academy of SciencesBeijing100190China University of chinese Academy of Sciences Beijing100049China Dalian National Laboratory for clean Energy Dalian116023China

coal-fired power generation stands as the most economically viable modulating power source in present-day *** holds the potential to offer prospective solutions to the challenges posed by the rapid expansion of intermittent,unpredictable,and unstable renewable energy *** particle thermal storage technology emerges as an effective means to enhance the flexibility of coal-fired circulating fluidized bed power *** attain an optimized structure for the solid particle thermal storage and release system in circulating fluidized bed units,experimental research was conducted on a 0.1 MWth circulating fluidized bed test *** study delved into the impact of ash storage bin geometries and the shapes of their feed-discharge valves on the control properties of solid particle *** experimental outcomes reveal that employing inverted m-shaped valve and dual U-shaped valves for feed control,alongside U-shaped valves and N-shaped valves for discharge control,both enable efficient and rapid storage and release of solid particles within the circulating fluidized *** similar air distribution conditions,the inverted m-shaped valve exhibits lower conveying energy consumption than the dual U-shaped valves,while the N-shaped valve excels in control characteristics over the U-shaped ***,the inverted m-shaped valve and the N-shaped valve demonstrate optimal overflow port heights,and the ash storage bin exhibits an optimum height-to-diameter ratio.

关键词： Solid particle Thermal storage System structure Transport regulation

Achieving Negatively charged Pt Single Atoms on Amorphous Ni(OH)_(2)Nanosheets with Promoted Hydrogen Absorption in Hydrogen Evolution

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Nano-Micro Letters 2024年第10期16卷 213-224页

作者： Yue Liu Gui Liu Xiangyu chen chuang Xue Mingke sun Yifei Liu Jianxin Kang Xiujuan sun Lin Guo School of chemistry Beijing Advanced Innovation Center for Biomedical EngineeringKey Laboratory of Bio-inspired Smart Interfacial Science and TechnologyBeihang UniversityBeijing 100191People's Republic of China School of chemistry Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of EducationXiangtan UniversityXiangtan 411105HunanPeople'Republic of China

Single-atom(SA)catalysts with nearly 100%atom utilization have been widely employed in electrolysis for decades,due to the outperforming catalytic activity and ***,most of the reported SA catalysts are fixed through the strong bonding between the dispersed single metallic atoms with nonmetallic atoms of the substrates,which greatly limits the controllable regulation of electrocatalytic activity of SA *** this work,Pt-Ni bonded Pt SA catalyst with adjustable electronic states was successfully constructed through a controllable electrochemical reduction on the coordination unsaturated amorphous Ni(OH)_(2)nanosheet *** on the X-ray absorption fine structure analysis and first-principles calculations,Pt SA was bonded with Ni sites of amorphous Ni(OH)_(2),rather than conventional O sites,resulting in negatively charged Pt^(δ-).In situ Raman spectroscopy revealed that the changed configuration and electronic states greatly enhanced absorbability for activated hydrogen atoms,which were the essential intermediate for alkaline hydrogen evolution *** hydrogen spillover process was revealed from amorphous Ni(OH)_(2)that effectively cleave the H-O-H bond of H_(2)O and produce H atom to the Pt SA sites,leading to a low overpotential of 48 mV in alkaline electrolyte at-1000 mA cm^(-2)mg^(-1)_(Pt),evidently better than commercial Pt/c *** work provided new strategy for the control-lable modulation of the local structure of SA catalysts and the systematic regulation of the electronic states.

关键词： Hydrogen evolution reaction Amorphous Pt single atoms Hydrogen spillover

Interfacial charge redistribution to promote the catalytic activity of Vs-coP-coS_(2)/c n-n heterojunction for oxygen evolution

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chinese chemical Letters 2024年第2期35卷 611-616页

作者： Jiawen sun Hui Xue Jing sun Niankun Guo Tianshan Song Yi-Ru Hao Qin Wang college of chemistry and chemical Engineering Inner Mongolia UniversityHohhot 010021China

Modulating surface charge redistribution based on interface and defect engineering has been considered as a resultful means to boost electrocatalytic ***,the mechanism of synergistic regulation of heterojunction and vacancy defects remains ***,a Vs-coP-coS_(2)/c n-n heterojunction with sulfur vacancies is successfully constructed,which manifests superior electrocatalytic activity for oxygen evolution,as demonstrated by a low overpotential of 170 mV to reach 10 mA/cm^(2).The experimental results and density functional theory calculations testify that the outstanding OER performance of Vs-coP-coS_(2)/c heterojunction is owed to the synergistic effect of sulfur vacancies and built-in electric field at n-n heterogeneous interface,which accelerates the electron transfer,induces the charge redistribution,and regulates the adsorption energy of active intermediates during the *** study affords a promising means to regulate the electrocatalytic performance by the construction of heterogeneous interfaces and defects,and in-depth explores the synergistic mechanisms of n-n heterojunction and vacancies.

关键词： charge redistribution n-n Heterojunction Built-in electric field Sulfur vacancy Oxygen evolution reaction

Rhodium-catalyzed N-Arylation Addition of Arylboronic Acids to Ketimines

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chinese Journal of chemistry 2024年第18期42卷 2243-2248页

作者： Xue-Wei Qian Xing-Wen sun Department of chemistry Fudan University220 Handan RoadShanghai 200433China

Herein,we report rhodium catalyzed N-arylation via addition of arylboronic acids to electron-deficientα-iminoesters which can be prepared in high efficiency by using easily accessible B-carbonyl *** reaction is highly regiospecific to achieve the N-aryl addition efficiently with up to 99%yield under mild *** corresponding product can be further efficiently converted into indoles andaseries of other important building blocks.

关键词： Rhodium catalyzed N-Arylation addition Amines Umpolung Indole c.c.coupling

Heteroatom doping regulates the catalytic performance of singleatom catalyst supported on graphene for ORR

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Nano Research 2024年第3期17卷 1086-1093页

作者： Ji-Kai sun Yu-Wei Pan Meng-Qian Xu Lei sun Shaolong Zhang Wei-Qiao Deng Dong Zhai Institute of Molecular Sciences and Engineering Institute of Frontier and Interdisciplinary ScienceShandong UniversityQingdao 266237China college of chemistry and Environmental Engineering Shenzhen UniversityShenzhen 518060China

Replacing fossil fuels with fuel cells is a feasible way to reduce global energy shortages and environmental ***,the oxygen reduction reaction(ORR)at the cathode has sluggish kinetics,which limits the development of fuel *** is significant to develop catalysts with high catalytic activity of *** single-atom catalysts(SAcs)of Pt supported on heteroatom-doped graphene are potential candidates for *** we studied the SAcs of Pt with different heteroatoms doping and screened out Pt-c_(4) and Pt-c_(3)O_(1) structures with only 0.13 V overpotential for ***,it is found that B atoms doping could weaken the adsorption capacity of Pt,while N or O atoms doping could enhance *** regularity was verified on Fe *** the electronic interaction analysis between Pt and adsorbate,we explained the mechanism of this regularity and further proposed a new descriptor named corrected d-band center(ε_(d-corr))to describe *** descriptor is an appropriate reflection of the number of free electrons of the SAcs,which could evaluate its adsorption *** work provides a purposeful regulatory strategy for the design of ORR catalysts.

关键词： single-atom catalyst(SAc) oxygen reduction reaction(ORR) heteroatom doping corrected d-band center descriptor

All-inorganic ultrathin high-sensitivity transparent temperature sensor based on a Mn-co-Ni-O nanofilm

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Microsystems & Nanoengineering 2024年第3期10卷 195-205页

作者： Yuanyuan cui Mengwei sun changbo Liu Yuan Deng Research Institute for Frontier Science Beihang UniversityBeijing 100191China School of Materials Science and Engineering Beihang UniversityBeijing 100191China Key Laboratory of Intelligent Sensing Materials and chip Integration Technology of Zhejiang Province Hangzhou Innovation Institute of Beihang UniversityHangzhou 310051China

The demand for optically transparent temperature sensors in intelligent devices is ***,the performance of these sensors,particularly in terms of their sensitivity and resolution,must be further *** study introduces a novel transparent and highly sensitive temperature sensor characterized by its ultrathin,freestanding design based on a Mn-co-Ni-O *** Mn-co-Ni-O-based sensor exhibits remarkable sensitivity,with a temperature coefficient of resistance of−4%℃^(−1),and can detect minuscule temperature fluctuations as small as 0.03℃.Additionally,the freestanding sensor can be transferred onto any substrate for versatile application while maintaining robust structural stability and excellent resistance to interference,indicating its suitability for operation in challenging *** practical utility in monitoring the surface temperature of optical devices is demonstrated through vertical integration of the sensor and a micro light-emitting diode on a polyimide ***,an experiment in which the sensor is implanted in rats confirms its favorable biocompatibility,highlighting the promising applications of the sensor in the biomedical domain.

关键词： transparent sensor versatile

cascade electrolysis and thermocatalysis: a reliable system for upgrading c1 to c4 hydrocarbons

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Rare Metals 2024年第1期43卷 410-412页

作者： chao-Yue sun Wen Li Hai-Qing Wang Institute for Advanced Interdisciplinary Research(iAIR) College of Chemistry and Chemical EngineeringUniversity of JinanJinan 250022China

The carbon c.c.e is important for maintaining a stable climate and carbon balance on Earth. Renewable-electricitydriven upc.c.ing of carbon dioxide (cO_(2)) into value-added multi-carbon molecules is a potentially sus... 详细信息

关键词： c.c.ing hydrocarbons enable