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Status and prospects for symmetric organic redox flow batteries

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Journal of Energy chemistry 2025年第1期100卷 125-143页

作者： Md Al Raihan c.Adam Dyker Department of chemistry University of New Brunswick

As environmental concerns from fossil fuel consumption intensify, large-scale energy storage becomes imperative for the integration of renewable sources like wind, hydro, and solar with the electrical *** flow batteries, particularly those employing organic molecules, are positioned as a key technology for this purpose. This review explores the growing field of symmetric organic redox flow batteries(ORFBs) within this context. Unlike traditional asymmetric designs based on unique active materials for each electrode, symmetric ORFBs involve a single bipolar species for both electrodes. This review highlights the benefits of a symmetric design, and categorizes five distinct classes of organic bipolar molecules used in both aqueous and non-aqueous solvents. By providing a comprehensive overview of their cell cycling and performance characteristics, the strengths and weaknesses of the diverse categories of bipolar molecules are highlighted for both solvent systems, as are opportunities for future development. This should guide new research directions and advance the development of practical symmetric ORFBs.

关键词： Redox flow battery Symmetric battery Organic battery Aqueous electrolyte Non-aqueous electrolyte

Acquired sensorineural hearing loss,oxidative stress,and microRNAs

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Neural Regeneration Research 2025年第9期20卷 2513-2519页

作者： Desmond A.Nunez Ru c.Guo Division of Otolaryngology–Head&Neck Surgery Department of SurgeryFaculty of MedicineThe University of British ColumbiaVancouverBCCanada Division of Otolaryngology–Head&Neck Surgery Gordon&Leslie Diamond Health Care CentreVancouver General HospitalVancouverBCCanada Faculty of Medicine–The University of British columbia VancouverBCCanada

Hearing loss is the third leading cause of human ***-related hearing loss,one type of acquired sensorineural hearing loss,is largely responsible for this escalating global health ***-induced,ototoxic,and idiopathic sudden sensorineural are other less common types of acquired hearing *** etiology of these conditions is complex and multi-fa ctorial involving an interplay of genetic and environmental *** stress has recently been proposed as a likely linking cause in most types of acquired sensorineural hearing *** non-coding RNA sequences known as microRNAs(miRNAs)have increasingly been shown to play a role in cellular hypoxia and oxidative stress responses including promoting an apoptotic *** hair cell death is a central histopathological finding in sensorineural hearing *** these cells do not regenerate in humans,it underlies the irreversibility of human age-related hearing *** EMBASE,Ovid MEDLINE,Web of Science core collection,and *** databases over the period August 1,2018 to July 31,2023 were searched with"hearing loss,""hypoxamiRs,""hypoxia,""microRNAs,""ischemia,"and"oxidative stress"text words for English language primary study publications or registered clinical *** red clinical trials known to the senior author we re also assessed.A total of 222studies were thus *** excluding duplicates,editorials,retra ctions,secondary research studies,and non-English language articles,39 primary studies and clinical trials underwent full-text *** resulted in 11 animal,in vitro,and/or human subject journal articles and 8 registered clinical trial database entries which form the basis of this narrative *** miR-34a and miR-29b levels increase with age in *** miRNAs were demonstrated in human neuroblastoma and murine cochlear cell lines to target Sirtuin 1/peroxisome proliferato r-activated receptor gamma coactivator-1-alpha(SIRT1/P Gc-1α),SIRT

关键词： hearing loss hypoxia microRNAs oxidative stress sensorineural

Multiple sclerosis is at a checkpoint: advancing the program

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Neural Regeneration Research 2025年第3期20卷 811-812页

作者： Brandon c.Smith Jessica L.Williams Department of Neurosciences Lerner Research InstituteCleveland ClinicClevelandOHUSA Department of Biological Geologicaland Environmental SciencesCleveland State UniversityClevelandOHUSA

Multiple sclerosis(MS) is a chronic inflammatory and demyelinating disease of the central nervous system(cNS). Patients with MS experience sensory and motor function loss due to myelin and/or axon damage perpetuated b... 详细信息

关键词： Hauser sclerosis damage

Analysis of Differences in Productivity,Profitability and Soil Fertility Between Organic and conventional cropping Systems in the Tropics and Sub-tropics

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Journal of Integrative Agriculture 2014年第10期13卷 2299-2310页

作者： te Pas c M Rees R M School of GeoSciences University of Edinburgh carbon Management centre Scotland's Rural College

Organic farming aims to stimulate soil fertility by avoiding the use of synthetic fertiliser inputs, relying instead on locally available natural resources. It is regarded by many as a sustainable alternative to conventional fanning because it ensures higher biodiversity, restricts environmental pollution, prevents land degradation and is easy to apply for smallholder and subsistence farmers. Although widely practiced and studied in temperate regions, little is known about the potential overall benefits of organic farming in the tropics and subtropics. This paper addresses this gap by undertaking an analysis of the differences between organic and conventional agriculture in the tropics and sub-tropics based on an extensive literature review including 88 papers with 458 data pairs. The comparison is based on three main indicators： yield, gross margin and soil organic carbon （SOc）. The differences between the organic and conventional systems for each of these main indicators is represented by the ratio of the value of the indicator in the organic system divided by the corresponding value in the conventional system. This was initially calculated for each data pair individually, and grouped by a variety of explanatory factors, such as precipitation, human development level, soil texture, crop type, organic input type, time after conversion and certification. The results demonstrate that under organic management, yields were on average 26% higher, gross margins 51% higher and soil organic carbon 53% higher than under conventional management. The highest yield increases in organic cropping systems were achieved in the least developed countries, in arid regions and on coarse soils. For gross margins, certification was the main reason for differences between organic and conventional systems. certified farmers, mostly located in developed countries, receive significantly higher prices. Furthermore, organic farming in the driest regions results in higher profits than in other

关键词： organic farming conventional fanning tropics subtropics carbon sequestration yield soil quality soil organic carbon

Biomass derived Fe-N/c catalyst for efficiently catalyzing oxygen reduction reaction in both alkaline and neutral pH conditions

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chinese chemical Letters 2023年第1期34卷 465-468页

作者： Lin-Qian Yu Hao Wang Shu-la chen te-Er Wen Bao-cheng Huang Ren-cun Jin laboratory of Water Pollution Remediation School of Life and Environmental SciencesHangzhou Normal UniversityHangzhou 311121China

Fe-N/c is a promising oxygen reduction reaction(ORR)catalyst to substitute the current widely used precious metal ***-effectively fabricating the Fe-N/c material with high catalytic activity and getting in-depth insight into the responsible catalytic site are of great *** this work,we proposed to use biomass,tea leaves waste,as the precursor to prepare ORR *** adding 5%Fecl3(wt%)into tea precursor,the pyrolysis product(i.e.,5%Fe-N/c)exhibited an excellent four-electron ORR activity,whose onset potential was only 10 m V lower than that of commercial Pt/*** limiting current density of 5%Fe-N/c(5.75 m A/cm^(2))was even higher than Pt/c(5.44 m A/cm^(2)).compared with other biomass or metal organic frameworks derived catalysts,5%Fe-N/c showed similar ORR ***,both the methanol tolerance and material stability performances of as-prepared 5%Fe-N/c catalyst were superior to that of Pt/c.X-ray adsorption fine structure characterization revealed that the FeN4O2might be the possible catalytic *** appropriate amount of iron chloride addition not only facilitated catalytic site formation,but also enhanced material conductivity and reaction *** results of this work may be useful for the Fe based transition metal ORR catalyst design and application.

关键词： Fe-N/c Oxygen reduction reaction Biomass Fe coordination Polyphenol

challenges and opportunities for battery health estimation:Bridging laboratory research and real-world applications

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Journal of Energy chemistry 2024年第2期89卷 434-436,I0011页

作者： te Han Jinpeng Tian c.Y.chung Yi-Ming Wei center for Energy and Environmental Policy Research Beijing Institute of TechnologyBeijing 100081China School of Management and Economics Beijing Institute of TechnologyBeijing 100081China Department of Electrical and Electronic Engineering and Research centre for Grid Modernization The Hong Kong Polytechnic UniversityKowloon 999077Hong KongChina

Addressing climate change demands a significant shift away from fossil fuels,with sectors like electricity and transportation relying heavily on renewable *** to this transition are energy storage systems,notably lithium-ion *** time,these batteries degrade,affecting their efficiency and posing safety *** and predicting battery aging is essential,especially estimating its state of health(SOH).Various SOH estimation methods exist,from traditional model-based approaches to machine learning approaches.

关键词： Energy storage systems State of health Multi-source data Scientific AI Data-sharing mechanism

Ultra‑Transparent and Multifunctional IZVO Mesh Electrodes for Next‑Generation Flexible Optoelectronics

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Nano-Micro Letters 2025年第1期17卷 293-309页

作者： Kiran A.Nirmal Tukaram D.Dongale Atul c.Khot chenjie Yao Nahyun Kim Tae Geun Kim School of Electrical Engineering Korea UniversityAnam‑ro 145Seongbuk‑guSeoulRepublic of Korea computational Electronics and Nanoscience Research laboratory School of Nanoscience and BiotechnologyShivaji UniversityKolhapur 416004India

Mechanically durable transparent electrodes are essential for achieving long-term stability in flexible optoelectronic ***,they are crucial for applications in the fields of energy,display,healthcare,and soft *** meshes represent a promising alternative to traditional,brittle,metal oxide conductors due to their high electrical conductivity,optical transparency,and enhanced mechanical *** this paper,we present a simple method for fabricating an ultra-transparent conducting metal oxide mesh electrode using selfcracking-assisted *** this method,we produced an electrode with ultra-transparency(97.39%),high conductance(Rs=21.24Ωsq^(−1)),elevated work function(5.16 eV),and good mechanical *** also evaluated the effectiveness of the fabricated electrodes by integrating them into organic photovoltaics,organic light-emitting diodes,and flexible transparent memristor devices for neuromorphic computing,resulting in exceptional device *** addition,the unique porous structure of the vanadium-doped indium zinc oxide mesh electrodes provided excellent flexibility,rendering them a promising option for application in flexible optoelectronics.

关键词： Self-cracking template Vanadium-doped indium zinc oxide mesh Organic solar cells Organic light-emitting diodes Flexible transparent memory

Machine learning empowers efficient design of ternary organic solar cells with PM6 donor

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Journal of Energy chemistry 2025年第1期100卷 337-347页

作者： Kiran A.Nirmal Tukaram D.Dongale Santosh S.Sutar Atul c.Khot Tae Geun Kim School of Electrical Engineering Korea University computational Electronics and Nanoscience Research laboratory School of Nanoscience and Biotechnology Shivaji University Yashwantrao chavan School of Rural Development Shivaji University

Organic solar cells(OScs) hold great potential as a photovoltaic technology for practical ***, the traditional experimental trial-and-error method for designing and engineering OScs can be complex, expensive, and time-consuming. Machine learning(ML) techniques enable the proficient extraction of information from datasets, allowing the development of realistic models that are capable of predicting the efficacy of materials with commendable accuracy. The PM6 donor has great potential for high-performance OScs. However, it is crucial for the rational design of a ternary blend to accurately forecast the power conversion efficiency(PcE) of ternary OScs(TOScs) based on a PM6 ***, we collected the device parameters of PM6-based TOScs and evaluated the feature importance of their molecule descriptors to develop predictive models. In this study, we used five different ML algorithms for analysis and prediction. For the analysis, the classification and regression tree provided different rules, heuristics, and patterns from the heterogeneous dataset. The random forest algorithm outperforms other prediction ML algorithms in predicting the output performance of PM6-based TOScs. Finally, we validated the ML outcomes by fabricating PM6-based TOScs. Our study presents a rapid strategy for assessing a high PcE while elucidating the substantial influence of diverse descriptors.

关键词： Random forests

Rolling route for refining grains of super light Mg-Li alloys containing Sc and Be

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Transactions of Nonferrous Metals Society of china 2010年第8期20卷 1374-1379页

作者： cHIANG chih-te LEE Shyong Department of Mechanical Engineering National Central University

Pioneering work on Sc or/and Be added Mg-Li alloys with refined grains was initiated. Various rolling-based thermo-mechanical treatments on these Mg-Li alloys were carried out. Four Mg-Li alloys were prepared by vacuum melting process. A unique route for producing fine grains was applied which concluded solution treatment at 350 ℃, cold rolling with 60% thickness reduction and 250 ℃ annealing, successively.

关键词： Mg-Li alloy beryllium scandium solid solution strengthening