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Refractory high-entropy alloys:A focused review of preparation methods and properties

Journal of Materials Science & Technology 2023年第11期142卷 196-215页

作者： Wei xiong amy x.y.guo Shuai Zhan Chain-Tsuan Liu Shan Cecilia Cao Materials Genome Institute Shanghai UniversityShanghai 200444China Hong Kong Institute of Advanced Study City University of Hong KongKowloonHong KongChina

In recent years,high-entropy alloys(HEAs)have become prominent metallic materials due to their unique design strategies and excellent mechanical *** HEAs-inherent high-entropy,lattice-distortion,sluggish-diffusion,and cocktail effects make HEAs maintain high strength,oxidation resistance,corrosion resistance,wear resistance,and other excellent comprehensive properties,showing stronger competitiveness relative to traditional *** high-entropy alloys(RHEAs)are considered as a new kind of high-temperature materials with great application prospects due to their excellent mechanical properties and have the potential to replace nickel-based superalloy as the next generation of high-temperature *** reviewed the research status and preparation methods of RHEAs in recent years,including the metallurgical smelting,powder metallurgy,magnetron sputtering,and additive manufacturing *** microstructure and phase-transformation process of RHEAs were *** mechan-ical properties and main strengthening and toughening mechanisms of RHEAs,such as solid-solution strengthening,precipitation strengthening,and the transformation-induced plasticity(TRIP),were discussed,and the deformation mechanism of RHEAs was *** properties of RHEAs,including high strength,oxidation resistance,corrosion and wear resistance were *** will meet the huge market demand in the engineering materials field,but there are still many challenges,such as the tradeoff between high strength and high ductility,structural design,and performance optimization of RHEAs with brittle BCC *** believe that this combination of knowledge may shape the future of RHEAs and break through the mutually exclusive conundrum of high strength and high toughness for RHEAs.

关键词： Refractory high-entropy alloy Preparation technology Phase transformation Mechanical properties Strengthening and toughening mechanisms Deformation mechanisms

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Biomedical applications of the powder-based 3D printed titanium alloys:A review

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Journal of Materials Science & Technology 2022年第30期125卷 252-264页

作者： amy x.y.guo Liangjie Cheng Shuai Zhan Shouyang Zhang Wei xiong Zihan Wang Gang Wang Shan Cecilia Cao Materials Genome Institute Shanghai UniversityShanghai 200444China

3D printing technology is a new type of precision forming technology and the core technology of the third industrial *** powder-based 3D printing technology of titanium and its alloys have received great attention in biomedical applications since its advantages of custom manufacturing,costsaving,time-saving,and resource-saving *** particular,the personalized customization of 3D printing can meet specific needs and achieve precise control of micro-organization and structural *** purpose of this review is to present the most advanced multi-material 3D printing methods for titanium-based *** first reviewed the bone tissue engineering,the application of titanium alloy as bone substitutes and the development of manufacturing technology,which emphasized the advantages of 3D printing technology over traditional manufacturing *** is more,the optimization design of the hierarchical structure was analyzed to achieve the best mechanical properties,and the biocompatibility and osseointegration ability of the porous titanium alloy after implantation in living bodies was ***,we emphasized the development of digital tools such as artificial intelligence,which provides new ideas for the rational selection of processing *** 3D printing titanium-based alloys will meet the huge market demand in the biomedical field,but there are still many challenges,such as the trade-off between high strength and low modulus,optimization of process parameters and structural *** believe that the combination of mechanical models,machine learning,and metallurgical knowledge may shape the future of metal printing.

关键词： The powder-based 3D printing technology Ti-based alloys Biomedical applications Artificial intelligence

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THE　CONSTANT　PHASE　ELEMENT　(CPE)　ON　MnO_2　ELECTRODE

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Chinese Chemical Letters 1996年第5期7卷 457-458页

作者： guo, y xia, x xINJIANG UNIV DEPT CHEMURUMQI 830046PEOPLES R CHINA

Abstract: Ac impedance responses of electrolytic manganese dioxide (EMD) electrode are measured with EIS. It was found that the impedance responses are consistent with the constant phase element (CPE)form and calculat... 详细信息

关键词： MnO2 CPE CONSTANT ELECTRODE ELEMENT ON

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New methods to find solutions and analyze stability of equilibrium of nonholonomic mechanical systems

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Acta Mechanica Sinica 2018年第6期34卷 1136-1144页

作者： J.Chen y.x.guo F.x.Mei School of Aerospace Engineering Beijing Institute of TechnologyBeijing 100081China School of Physics Liaoning UniversityShenyang 110000China

A large proportion of constrained mechanical systems result in nonlinear ordinary differential equations,for which it is quite difficult to find analytical *** initial motions method proposed by Whittaker is effective to deal with such problems for various constrained mechanical systems,including the nonholonomic systems discussed in the first part of this paper,where in addition to differential equations of motion,nonholonomic constraints *** final equations of motion for these systems are obtained in the form of corresponding power ***,an alternative,direct method to determine the initial values of higher-order derivatives(q)0,(q)0,…is proposed,being different from that of *** second part of this work analyzes the stability of equilibrium of less complex,nonholonomic mechanical systems represented by gradient *** discuss the stability of equilibrium of such systems based on the properties of the gradient *** advantage of this novel method is its avoidance of the difficulty of directly establishing Lyapunov functions aimed at such unsteady nonlinear ***,these theoretical considerations are illustrated through four examples.

关键词： Nonholonomic system Initial motions Gradient system Lyapunov function Stability

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Constructing Donor–Acceptor‑Linked COFs Electrolytes to Regulate Electron Density and Accelerate the Li^(+)Migration in Quasi‑Solid‑State Battery

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Nano-Micro Letters 2025年第1期17卷 456-471页

作者： Genfu Zhao Hang Ma Conghui Zhang yongxin yang Shuyuan yu Haiye Zhu yongjiang Sun Hong guo School of Materials and Energy International Joint Research Center for Advanced Energy Materials of Yunnan ProvinceYunnan UniversityKunming 650091People’s Republic of China yunnan yuntianhua Co. LtdR&D CenterKunming 650228People’s Republic of China Southwest United Graduate School Kunming 650091People’s Republic of China

Regulation the electronic density of solid-state electrolyte by donor–acceptor(D–A)system can achieve highly-selective Li^(+)transportation and conduction in solid-state Li metal *** study reports a high-performance solid-state electrolyte thorough D–A-linked covalent organic frameworks(COFs)based on intramolecular charge transfer *** other reported COFbased solid-state electrolyte,the developed concept with D–A-linked COFs not only achieves electronic modulation to promote highly-selective Li^(+)migration and inhibit Li dendrite,but also offers a crucial opportunity to understand the role of electronic density in solid-state Li metal *** introduced strong electronegativity F-based ligand in COF electrolyte results in highlyselective Li^(+)(transference number 0.83),high ionic conductivity(6.7×10^(-4)S cm^(−1)),excellent cyclic ability(1000 h)in Li metal symmetric cell and high-capacity retention in Li/LiFePO_(4)cell(90.8%for 300 cycles at 5C)than substituted C-and N-based *** is ascribed to outstanding D–A interaction between donor porphyrin and acceptor F atoms,which effectively expedites electron transferring from porphyrin to F-based ligand and enhances Li^(+)***,we anticipate that this work creates insight into the strategy for accelerating Li^(+)conduction in high-performance solid-state Li metal batteries through D–A system.

关键词： Electronic modulation engineering Donor-acceptor-linked covalent organic frameworks Quasi-solid-state Li metal battery

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One kind motion of controllable constrained Birkhoffian system:the absence of constraints

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Acta Mechanica Sinica 2020年第3期36卷 735-741页

作者： J.Chen F.x.Mei S.x.Liu y.x.guo School of Aerospace Engineering Beijing Institute of TechnologyBeijing 100081China School of Physics Liaoning UniversityShenyang 110000China

This paper is devoted to discuss the motion of controllable constrained Birkhoffian system along with its absence of *** first step is to establish the autonomous and non-autonomous differential equations of motion of the system,based on Pfaff-Birkhoff ***,the existence of constraint multipliers are exhaustively ***,the definition of one kind motion of the system,called free motion,is given,which is described and analyzed by the absence of constraints that are determined by constraint *** 2 illustrates that one system can realize its free motion by selecting proper control *** particular,theorem 2 provides that one system can naturally realize free motion when we consider the integral of the unconstrained Birkhoffian system as the constraints of constrained Birkhoffian ***,the results obtained are illustrated by several examples.

关键词： Constrained Birkhoffian system Kinematic control Absence of constraint Free motion

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Enhanced pitting corrosion resistance of a Zr-based metallic glass by ultraviolet light irradiation

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Journal of Iron and Steel Research International 2023年第8期30卷 1642-1649页

作者： Z.Chen D.P.Wang S.Wang y.x.Geng y.x.guo y.C.Wu Z.G.Liu y.y.Zhang y.x.Wang School of Materials Science and Engineering Jiangsu University of Science and Technology.Zhenjiang 212003JiangsuChina School of Mechanical Engineering Jiangsu University of Science and TechnologyZhenjiang 212003JiangsuChina

The influence of ultraviolet light irradiation on the pitting corrosion performance of a Zr_(2)Ni metallic glass was examined using electrochemical methods and immersion test in 0.05 mol/L NaCl *** the results of potentiostatic polarization,the pitting potential of the ultraviolet light-irradiated sample shifted positively with a value of~300 mV,revealing the enhanced pitting corrosion resistance of the *** corrosion morphology after the immersion test also demonstrated lower degree of corrosion damage and improved pitting resistance of the sample with ultraviolet light irradiation.x-ray photoelectron spectroscopy analysis revealed more zirconium enrichment in the passive film and no chloride ions adsorption for the samples with ultraviolet irradiation,accounting for the suppression of the pit generation and *** findings indicate that ultraviolet light irradiation improves the pitting corrosion resistance of the Zr-based metallic glasses,which are promising structural materials to be used in corrosion environments with high ultraviolet irradiation.

关键词： Metallic glass Pitting-Corrosion Ultraviolet light irradiation Passive film

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Reduced mesencephalic astrocyte-derived neurotrophic factor expression by mutant androgen receptor contributes to neurodegeneration in a model of spinal and bulbar muscular atrophy pathology

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Neural Regeneration Research 2025年第9期20卷 2655-2666页

作者： yiyang Qin Wenzhen Zhu Tingting guo yiran Zhang Tingting xing Peng yin Shihua Li xiao-Jiang Li Su yang Guangdong Key Laboratory of Non-human Primate Research Key Laboratory of CNS Regeneration(Ministry of Education)Guangdong–HongKong–Macao Institute of CNS RegenerationJinan UniversityGuangzhouGuangdong ProvinceChina

Spinal and bulbar muscular atrophy is a neurodegenerative disease caused by extended CAG trinucleotide repeats in the androgen receptor gene,which encodes a ligand-dependent transcription facto *** mutant androgen receptor protein,characterized by polyglutamine expansion,is prone to misfolding and forms aggregates in both the nucleus and cytoplasm in the brain in spinal and bulbar muscular atrophy *** aggregates alter protein-protein interactions and compromise transcriptional *** this study,we reported that in both cultured N2a cells and mouse brain,mutant androgen receptor with polyglutamine expansion causes reduced expression of mesencephalic astrocyte-de rived neurotrophic *** n of mesencephalic astrocyte-derived neurotrophic factor amelio rated the neurotoxicity of mutant androgen receptor through the inhibition of mutant androgen receptor *** down endogenous mesencephalic astrocyte-derived neurotrophic factor in the mouse brain exacerbated neuronal damage and mutant androgen receptor *** findings suggest that inhibition of mesencephalic astrocyte-derived neurotrophic factor expression by mutant androgen receptor is a potential mechanism underlying neurodegeneration in spinal and bulbar muscular atrophy.

关键词： androgen receptor mesencephalic astrocyte-derived neurotrophic factor mouse model neurodegeneration neuronal loss neurotrophic factor polyglutamine disease protein misfolding spinal and bulbar muscular atrophy transcription factor

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Relationship of Corrosion Behavior Between Single-Phase Equiatomic CoCrNi,CoCrNiFe,CoCrNiFeMn Alloys and Their Constituents in NaCl Solution

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Acta Metallurgica Sinica(English Letters) 2021年第11期34卷 1574-1584页

作者： D.P.Wang J.W.Shen Z.Chen F.G.Chen P.y.guo y.x.Geng y.x.Wang School of Materials Science and Engineering Jiangsu University of Science and TechnologyZhenjiang 212003China

The composition is a significant issue for corrosion resistance of metallic *** reveal the correlation of corrosion behavior between multiprinciple alloys and their constituents,a series of single-phase equiatomic alloys of CoCrNi,CoCrNiFe and CoCrNiFeMn was *** electrochemical and scanning electron microscope results demonstrated that corrosion resistance of the equiatomic alloys in 0.1 M NaCl solution is located in the range but not the average value of their constituents.x-ray photoelectron spectroscopy analysis indicated that the protective performance of passive film is mainly determined by the constituent with the highest corrosion resistance and the breakdown of passive film is mainly dominated by the elements with the highest corrosion *** findings can guide the materials design of multiprinciple alloys with expected corrosion performance.

关键词： High-entropy alloy Corrosion Constituent x-ray photoelectron spectroscopy(xPS) Passive films

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STUDy ON PROPERTIES OF PULSE ELECTRODEPOSITED RE-Ni-W-P-SiC COMPOSITE COATINGS

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Acta Metallurgica Sinica(English Letters) 2007年第2期20卷 111-116页

作者： Z.C. guo x.y. Zhu R.D. xu Faculty of Materials and Metallurgical Engineering Kunming University of Science and Technology Kunming 650093 China

The effects of pulse frequency f and duty cycle r on the deposition rate, composition, morphology, and hardness of pulse electrodeposited RE （rare earth）-Ni-W-P-SiC composite coatings have been studied. The results indicate that pulse current can improve the deposition rate of RE-Ni-W-P-SiC composite coatings; W, P, and SiC contents in the coating decrease with the increase of pulse frequency and reach the lowest value at f = 33Hz, whereas the RE content in the composite coatings increases with the increase of pulse frequency. SiC content decreases with the increase of duty cycle, W content reaches the lowest value, and P content reaches the highest value at r = 0.4; pulse current and RE can lead to smaller size of the crystalline grains; however, the effects of different pulse frequency and duty cycle on the morphologies of RE-Ni-W-P-SiC composite coatings are not obvious. The hardness of RE-Ni-W-P-SiC composite coatings is the highest when the duty cycle is at 0.6 and 0.8 and pulse frequency is at 50Hz. At the same pulse frequency, the hardness of RE-Ni-W-P-SiC composite coatings at r= 0.8 is higher than that at r= 0.6.

关键词： frequency duty cycle electrodeposition RE-Ni-W-P-SiC composite coating

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