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Refractory high-entropy alloys:A focused review of preparation methods and properties

Journal of Materials Science & Technology 2023年第11期142卷 196-215页

作者： Wei xiong amy x.y.guo Shuai Zhan Chain-Tsuan Liu Shan Cecilia Cao Materials Genome Institute Shanghai UniversityShanghai 200444China Hong Kong Institute of Advanced Study City University of Hong KongKowloonHong KongChina

In recent years,high-entropy alloys(HEAs)have become prominent metallic materials due to their unique design strategies and excellent mechanical *** HEAs-inherent high-entropy,lattice-distortion,sluggish-diffusion,and cocktail effects make HEAs maintain high strength,oxidation resistance,corrosion resistance,wear resistance,and other excellent comprehensive properties,showing stronger competitiveness relative to traditional *** high-entropy alloys(RHEAs)are considered as a new kind of high-temperature materials with great application prospects due to their excellent mechanical properties and have the potential to replace nickel-based superalloy as the next generation of high-temperature *** reviewed the research status and preparation methods of RHEAs in recent years,including the metallurgical smelting,powder metallurgy,magnetron sputtering,and additive manufacturing *** microstructure and phase-transformation process of RHEAs were *** mechan-ical properties and main strengthening and toughening mechanisms of RHEAs,such as solid-solution strengthening,precipitation strengthening,and the transformation-induced plasticity(TRIP),were discussed,and the deformation mechanism of RHEAs was *** properties of RHEAs,including high strength,oxidation resistance,corrosion and wear resistance were *** will meet the huge market demand in the engineering materials field,but there are still many challenges,such as the tradeoff between high strength and high ductility,structural design,and performance optimization of RHEAs with brittle BCC *** believe that this combination of knowledge may shape the future of RHEAs and break through the mutually exclusive conundrum of high strength and high toughness for RHEAs.

关键词： Refractory high-entropy alloy Preparation technology Phase transformation Mechanical properties Strengthening and toughening mechanisms Deformation mechanisms

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Biomedical applications of the powder-based 3D printed titanium alloys:A review

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Journal of Materials Science & Technology 2022年第30期125卷 252-264页

作者： amy x.y.guo Liangjie Cheng Shuai Zhan Shouyang Zhang Wei xiong Zihan Wang Gang Wang Shan Cecilia Cao Materials Genome Institute Shanghai UniversityShanghai 200444China

3D printing technology is a new type of precision forming technology and the core technology of the third industrial *** powder-based 3D printing technology of titanium and its alloys have received great attention in biomedical applications since its advantages of custom manufacturing,costsaving,time-saving,and resource-saving *** particular,the personalized customization of 3D printing can meet specific needs and achieve precise control of micro-organization and structural *** purpose of this review is to present the most advanced multi-material 3D printing methods for titanium-based *** first reviewed the bone tissue engineering,the application of titanium alloy as bone substitutes and the development of manufacturing technology,which emphasized the advantages of 3D printing technology over traditional manufacturing *** is more,the optimization design of the hierarchical structure was analyzed to achieve the best mechanical properties,and the biocompatibility and osseointegration ability of the porous titanium alloy after implantation in living bodies was ***,we emphasized the development of digital tools such as artificial intelligence,which provides new ideas for the rational selection of processing *** 3D printing titanium-based alloys will meet the huge market demand in the biomedical field,but there are still many challenges,such as the trade-off between high strength and low modulus,optimization of process parameters and structural *** believe that the combination of mechanical models,machine learning,and metallurgical knowledge may shape the future of metal printing.

关键词： The powder-based 3D printing technology Ti-based alloys Biomedical applications Artificial intelligence

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THE　CONSTANT　PHASE　ELEMENT　(CPE)　ON　MnO_2　ELECTRODE

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Chinese Chemical Letters 1996年第5期7卷 457-458页

作者： guo, y xia, x xINJIANG UNIV DEPT CHEMURUMQI 830046PEOPLES R CHINA

Abstract: Ac impedance responses of electrolytic manganese dioxide (EMD) electrode are measured with EIS. It was found that the impedance responses are consistent with the constant phase element (CPE)form and calculat... 详细信息

关键词： MnO2 CPE CONSTANT ELECTRODE ELEMENT ON

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New methods to find solutions and analyze stability of equilibrium of nonholonomic mechanical systems

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Acta Mechanica Sinica 2018年第6期34卷 1136-1144页

作者： J.Chen y.x.guo F.x.Mei School of Aerospace Engineering Beijing Institute of TechnologyBeijing 100081China School of Physics Liaoning UniversityShenyang 110000China

A large proportion of constrained mechanical systems result in nonlinear ordinary differential equations,for which it is quite difficult to find analytical *** initial motions method proposed by Whittaker is effective to deal with such problems for various constrained mechanical systems,including the nonholonomic systems discussed in the first part of this paper,where in addition to differential equations of motion,nonholonomic constraints *** final equations of motion for these systems are obtained in the form of corresponding power ***,an alternative,direct method to determine the initial values of higher-order derivatives(q)0,(q)0,…is proposed,being different from that of *** second part of this work analyzes the stability of equilibrium of less complex,nonholonomic mechanical systems represented by gradient *** discuss the stability of equilibrium of such systems based on the properties of the gradient *** advantage of this novel method is its avoidance of the difficulty of directly establishing Lyapunov functions aimed at such unsteady nonlinear ***,these theoretical considerations are illustrated through four examples.

关键词： Nonholonomic system Initial motions Gradient system Lyapunov function Stability

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One kind motion of controllable constrained Birkhoffian system:the absence of constraints

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Acta Mechanica Sinica 2020年第3期36卷 735-741页

作者： J.Chen F.x.Mei S.x.Liu y.x.guo School of Aerospace Engineering Beijing Institute of TechnologyBeijing 100081China School of Physics Liaoning UniversityShenyang 110000China

This paper is devoted to discuss the motion of controllable constrained Birkhoffian system along with its absence of *** first step is to establish the autonomous and non-autonomous differential equations of motion of the system,based on Pfaff-Birkhoff ***,the existence of constraint multipliers are exhaustively ***,the definition of one kind motion of the system,called free motion,is given,which is described and analyzed by the absence of constraints that are determined by constraint *** 2 illustrates that one system can realize its free motion by selecting proper control *** particular,theorem 2 provides that one system can naturally realize free motion when we consider the integral of the unconstrained Birkhoffian system as the constraints of constrained Birkhoffian ***,the results obtained are illustrated by several examples.

关键词： Constrained Birkhoffian system Kinematic control Absence of constraint Free motion

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Enhanced pitting corrosion resistance of a Zr-based metallic glass by ultraviolet light irradiation

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Journal of Iron and Steel Research International 2023年第8期30卷 1642-1649页

作者： Z.Chen D.P.Wang S.Wang y.x.Geng y.x.guo y.C.Wu Z.G.Liu y.y.Zhang y.x.Wang School of Materials Science and Engineering Jiangsu University of Science and Technology.Zhenjiang 212003JiangsuChina School of Mechanical Engineering Jiangsu University of Science and TechnologyZhenjiang 212003JiangsuChina

The influence of ultraviolet light irradiation on the pitting corrosion performance of a Zr_(2)Ni metallic glass was examined using electrochemical methods and immersion test in 0.05 mol/L NaCl *** the results of potentiostatic polarization,the pitting potential of the ultraviolet light-irradiated sample shifted positively with a value of~300 mV,revealing the enhanced pitting corrosion resistance of the *** corrosion morphology after the immersion test also demonstrated lower degree of corrosion damage and improved pitting resistance of the sample with ultraviolet light irradiation.x-ray photoelectron spectroscopy analysis revealed more zirconium enrichment in the passive film and no chloride ions adsorption for the samples with ultraviolet irradiation,accounting for the suppression of the pit generation and *** findings indicate that ultraviolet light irradiation improves the pitting corrosion resistance of the Zr-based metallic glasses,which are promising structural materials to be used in corrosion environments with high ultraviolet irradiation.

关键词： Metallic glass Pitting-Corrosion Ultraviolet light irradiation Passive film

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Relationship of Corrosion Behavior Between Single-Phase Equiatomic CoCrNi,CoCrNiFe,CoCrNiFeMn Alloys and Their Constituents in NaCl Solution

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Acta Metallurgica Sinica(English Letters) 2021年第11期34卷 1574-1584页

作者： D.P.Wang J.W.Shen Z.Chen F.G.Chen P.y.guo y.x.Geng y.x.Wang School of Materials Science and Engineering Jiangsu University of Science and TechnologyZhenjiang 212003China

The composition is a significant issue for corrosion resistance of metallic *** reveal the correlation of corrosion behavior between multiprinciple alloys and their constituents,a series of single-phase equiatomic alloys of CoCrNi,CoCrNiFe and CoCrNiFeMn was *** electrochemical and scanning electron microscope results demonstrated that corrosion resistance of the equiatomic alloys in 0.1 M NaCl solution is located in the range but not the average value of their constituents.x-ray photoelectron spectroscopy analysis indicated that the protective performance of passive film is mainly determined by the constituent with the highest corrosion resistance and the breakdown of passive film is mainly dominated by the elements with the highest corrosion *** findings can guide the materials design of multiprinciple alloys with expected corrosion performance.

关键词： High-entropy alloy Corrosion Constituent x-ray photoelectron spectroscopy(xPS) Passive films

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STUDy ON PROPERTIES OF PULSE ELECTRODEPOSITED RE-Ni-W-P-SiC COMPOSITE COATINGS

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Acta Metallurgica Sinica(English Letters) 2007年第2期20卷 111-116页

作者： Z.C. guo x.y. Zhu R.D. xu Faculty of Materials and Metallurgical Engineering Kunming University of Science and Technology Kunming 650093 China

The effects of pulse frequency f and duty cycle r on the deposition rate, composition, morphology, and hardness of pulse electrodeposited RE （rare earth）-Ni-W-P-SiC composite coatings have been studied. The results indicate that pulse current can improve the deposition rate of RE-Ni-W-P-SiC composite coatings; W, P, and SiC contents in the coating decrease with the increase of pulse frequency and reach the lowest value at f = 33Hz, whereas the RE content in the composite coatings increases with the increase of pulse frequency. SiC content decreases with the increase of duty cycle, W content reaches the lowest value, and P content reaches the highest value at r = 0.4; pulse current and RE can lead to smaller size of the crystalline grains; however, the effects of different pulse frequency and duty cycle on the morphologies of RE-Ni-W-P-SiC composite coatings are not obvious. The hardness of RE-Ni-W-P-SiC composite coatings is the highest when the duty cycle is at 0.6 and 0.8 and pulse frequency is at 50Hz. At the same pulse frequency, the hardness of RE-Ni-W-P-SiC composite coatings at r= 0.8 is higher than that at r= 0.6.

关键词： frequency duty cycle electrodeposition RE-Ni-W-P-SiC composite coating

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Experimental methods for determination of mechanical behaviors of materials at high temperatures via the split Hopkinson bars

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Acta Mechanica Sinica 2020年第6期36卷 1275-1293,I0003页

作者： Q.B.Dou K.R.Wu T.Suo C.Zhang x.guo y.Z.guo W.G.guo y.L.Li School of Aeronautics Northwestern Polytechnical UniversityXi’an710072China Joint International Research Laboratory of Impact Dynamics and its Engineering Application Xi’an710072China Shaanxi Key Laboratory of Impact Dynamics and its Engineering Application Xi’an710072China State Key Laboratory for Strength and Vibration of Mechanical Structures School of AerospaceXi’an Jiaotong UniversityXi’an710049China

Full understanding of the thermomechanical behaviors of materials at high strain rates and high temperatures are of great importance from not only scientific meaning but also practical value in engineering structure design and safety *** efforts have been made for abilities of operation the split Hopkinson bars,the most popular technique for experimental determination of mechanical behaviors of materials over the strain rates from 10^2 to 10^4 s^−1 over the past 70 years,at high temperatures since 1960s.A review of experiment work is presented in this paper to give an overview of the development of experimental techniques at high temperatures based on Hopkinson bar *** principles of the split Hopkinson bar requires the loading bars avoiding temperature gradient or keeping relatively low temperature when performing high temperature *** such as performing temperature gradient corrections,rapid heating or using special designed automatically assembled systems were proposed by researchers to enable the operation of the split Hopkinson bars at temperature as high as ***,to the application of high speed photographic technique for capturing the dynamic deformation process of the specimen in high temperature Hopkinson bar testing,some key issues of eliminating the strong thermal radiation induced lights oversaturation and de-blurring of images due to insufficient exposure at high temperature and high strain rate condition,as well as fabrication of high contrast speckle pattern for high temperature digital image correlation measurement were also *** technique can now enable the split Hopkinson bar testing to be performed at high temperature up to 1873 K under the loading conditions of compression or tension with the in situ observation and full field measurement of deformation as *** paper concludes with summaries of the most important achievements and highlighting of the prospects,trends and remaining challenge

关键词： Mechanical behaviors Split Hopkinson bar High strain rate High temperature

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Synthetic biodegradable functional polymers for tissue engineering:a brief review

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Science China Chemistry 2014年第4期57卷 490-500页

作者： guo BaoLin MA Peter x Center for Biomedical Engineering and Regenerative Medicine Frontier Institute of Science and Technology Xi'an Jiaotong University Department of Biomedical Engineering University of Michigan Department of Biologic and Materials Sciences University of Michigan Macromolecular Science and Engineering Center University of Michigan Department of Materials Science and Engineering University of Michigan

Scaffolds play a crucial role in tissue engineering. Biodegradable polymers with great processing flexibility are the predominant scaffolding materials. Synthetic biodegradable polymers with well-defined structure and without immunological concerns associated with naturally derived polymers are widely used in tissue engineering. The synthetic biodegradable polymers that are widely used in tissue engineering, including polyesters, polyanhydrides, polyphosphazenes, polyurethane, and poly(glycerol sebacate) are summarized in this article. New developments in conducting polymers, photoresponsive polymers, amino-acid-based polymers, enzymatically degradable polymers, and peptide-activated polymers are also discussed. In addition to chemical functionalization, the scaffold designs that mimic the nano and micro features of the extracellular matrix(ECM) are presented as well, and composite and nanocomposite scaffolds are also reviewed.

关键词： synthetic biodegradable polymers functional polymers scaffolds tissue engineering

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