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Progress in Natural Science:Materials International 2016年第6期26卷 517-522页

作者： Vahid Saadattalab alireza Shakeri Hamid Gholami School of Chemistry University College of Science University of Tehran

Polyaniline was synthesized chemically in an acidic medium in the presence of Ammonium Peroxydisulphate(APS) as an oxidizing agent. PANI(Polyaniline) nanocomposites were prepared in the presence of various amount of carbon nanotube and zinc oxide(from 1 to 5 wt%) by solution casting method. The free-standing film of polyaniline and its nanocomposites were obtained by vaporization of solvent content. The composition,morphology and structure of the polymer and the nanocomposites were characterized by Fourier transform infrared spectroscopy FT-IR spectra, scanning electron microscopy(SEM) image and XRD pattern. In addition,thermal stability was studied by TGA analysis, electrical conductivity was measured by four-point probe technique and mechanical properties were studied by tensile strength test. The characteristic FTIR peaks of PANI were found to shift to lower wave number in nanocomposites due to the formation of H-bonding. XRD results revealed that the crystallinity of PANI was more noticeable after addition of nano-ZnO, while the intensity of the peaks increased by the addition of ZnO nanoparticles. Furthermore, TGA results showed that the decomposition of the nanocomposite was less than that of pure polyaniline which confirms the successful fabrication of products. Young's modulus and strength at break point were increased in the case of the nanocomposite, in addition, the electrical conductivity of the PANI/ZnO nanocomposite film was found to be smaller than that of the PANI film while CNTs increase the conductivity of polyaniline.

关键词： Conductive polymer Polyaniline Nanocomposite Zinc oxide CNT

Fabrication of g-C_(3)N_(4) nanosheet/Bi_(5)O_(7)Br/NH_(2)-MIL-88B(Fe)nanocomposites:Double S-scheme photocatalysts with impressive performance for the removal of antibiotics under visible light

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International Journal of Minerals,Metallurgy and Materials 2023年第7期30卷 1363-1374页

作者： Nasrin Sedaghati Aziz Habibi-Yangjeh alireza Khataee Department of Chemistry Faculty of ScienceUniversity of Mohaghegh ArdabiliArdabil 56199-11367Iran Research Laboratory of Advanced Water and Wastewater Treatment Processes Department of Applied ChemistryFaculty of ChemistryUniversity of TabrizTabriz 51666-16471Iran Department of Environmental Engineering Faculty of EngineeringGebze Technical UniversityGebze 41400Turkey

Novel graphitic carbon nitride(g-C_(3)N_(4))nanosheet/Bi_(5)O_(7)Br/NH_(2)-MIL-88B(Fe)photocatalysts(denoted as GCN-NSh/Bi_(5)O_(7)Br/FeMOF,in which MOF is metal–organic framework)with double S-scheme heterojunctions were synthesized by a facile solvothermal *** resultant materials were examined by X-ray photoelectron spectrometer(XPS),X-ray diffraction(XRD),scanning electron microscopy(SEM),energy dispersive X-ray spectroscopy(EDX),transmission electron microscopy(TEM),high-resolution transmission electron microscopy(HRTEM),photoluminescence spectroscopy(PL),Fourier transform infrared spectroscopy(FT-IR),UV-Vis diffuse reflection spectroscopy(UV-vis DRS),photocurrent density,electrochemical impedance spectroscopy(EIS),and Brunauer–Emmett–Teller(BET)*** the integration of Fe-MOF with GCN-NSh/Bi_(5)O_(7)Br,the removal constant of tetracycline over the optimal GCN-NSh/Bi_(5)O_(7)Br/Fe-MOF(15wt%)nanocomposite was promoted 33 times compared with that of the pristine *** GCN-NSh/Bi_(5)O_(7)Br/Fe-MOF(15wt%)nanocomposite showed superior photoactivity to azithromycin,metronidazole,and cephalexin removal that was 36.4,20.2,and 14.6 times higher than that of pure GCN,*** quenching tests showed that·O_(2)-and h+mainly contributed to the elimination *** addition,the nanocomposite maintained excellent activity after 4 successive *** on the developed n–n heterojunctions among n-GCN-NSh,n-Bi_(5)O_(7)Br,and n-Fe-MOF semiconductors,the double S-scheme charge transfer mechanism was proposed for the destruction of the selected antibiotics.

关键词： g-C_(3)N_(4)nanosheet/Bi_(5)O_(7)Br/NH_(2)-MIL-88B(Fe) metal-organic framework double S-scheme heterojunctions antibiotics pho-tocatalytic performance

Synthesis of 4-（4-Methylsulfonylphenyl）-3-phenyl-2（3H）-thiazole Thione Derivatives as New Potential COX-2 Inhibitors

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Chinese Journal of Chemistry 2006年第6期24卷 791-794页

作者： EMAMI, Saeed FOROUMADI, alireza Department of Medicinal Chemistry Faculty of Pharmacy Mazandaran University of Medical Sciences Sari Iran Pharmaceutical Sciences Research Center Tehran University of Medical Sciences Tehran Iran

Synthesis of novel 4-（4-methylsulfonylphenyl）-3-phenyl-2（3H）-thiazole thione derivatives with functionalized diarylheterocycle pharmacophore as potential COX-2 inhibitors was described. The title compounds were synthesized by cyclocondensation of corresponding dithiocarbamate and 2-bromo-1-（4-methylsulfonylphenyl）ethanone, followed by dehydration with H2SO4. All of the target compounds were characterized by ^1H NMR, IR and mass spectral data.

关键词： synthesis diaryl heterocycle 2(3H)-thiazole thione COX-2 inhibitor

Sensitivity Analysis of Pollutants and Pattern Factor in a Gas Turbine Model Combustor due to Changes in Stabilizing Jets Characteristics

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Journal of Thermal Science 2022年第5期31卷 1622-1641页

作者： BAZDIDI-TEHRANI Farzad TEYMOORI alireza GHIYASI Mehdi School of Mechanical Engineering Iran University of Science and TechnologyTehran16846-13114Iran

In the present paper,a sensitivity analysis of pollutants and pattern factor in a model combustor due to changes in the geometrical characteristics of stabilizing jets has been carried *** exhaust pollutants including NO_(x),CO and soot have been chosen due to their harmful effect on the *** pattern factor has been also considered owing to its impact on turbine *** geometrical characteristics comprise diameter,angle and position of stabilizing ***-Lagrangian approach has been employed to model liquid fuel injection and distribution,breakup and evaporation of *** the analysis of reactive-spray flow characteristics,RANS approach,realizable k-εturbulence model,discrete ordinates radiative heat transfer model and steady flamelet combustion model together with the chemical reaction mechanism of diesel fuel(C_(10)H_(22))have been ***_(x) modeling has been performed via *** analysis is such that by making variations in the problem inputs(diameter,angle and position of jets)in an organized manner,the effects on the outputs(NO_(x),CO,soot and pattern factor)are *** number and order of simulations are predicted by design of experiments and full factorial *** have been analyzed using analysis of *** has been observed that if interactions among the characteristics of jets are considered,it is possible to analyze the exhaust pollutants more *** fact,by using the interactions,it is likely to find a point where all output parameters are *** show that by considering interactions of stabilizing jet characteristics,the maximum values of NO_(x),CO,soot and pattern factor change from 13.927 ppm,11.198%mole fraction,2.877 ppm and 0.043 to 26.233 ppm,14.693%mole fraction,142.357 ppm and 0.060,***,the minimum values change from 5.819 ppm,7.568%mole fraction,0.013 ppm and 0.029 to 6.098 ppm,5.987%mole fraction,0.002 ppm and 0.027,respectively.

关键词： model jet-stabilized combustor liquid fuel injection sensitivity analysis design of experiments pollutants pattern factor

Tannin characterization and sourcing in historical leathers through FTIR spectroscopy and PCA analysis

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Collagen and Leather 2023年第3期5卷 73-81页

作者： alireza Koochakzaei Mohammadamin Sabaghian Faculty of Cultural Materials Conservation Tabriz Islamic Art UniversityTabrizIslamic Republic of Iran

This study aimed to identify and classify the type of plants used for tanning historical leathers using cost-effective Fourier transform infrared(FTIR)*** investigation was carried out on five plants(oak bark,sumac,valonia,tara,and gallnut)and four historical leather samples from book bindings dating back to the Qajar *** extraction from both plants and leathers was performed using acetone-water solvent,and the samples were then subjected to FTIR ***-processing of the spectra included baseline correction,smoothing,and *** component analysis(PCA)was used to identify the source of tannins based on FTIR *** was found to provide a good separation of condensed tannins from hydrolysable ***,PCA analysis allowed for the separation and identification of the type of plant used for tannin *** examination of historical leather samples revealed that the primary classification based on the type of tannin is possible,but accurate identification faces challenges due to structural changes and degradation over time.

关键词： Vegetable tanning Tannin characterization Historical leather FTIR PCA Hydrolysable tannins

Parametric study on the mixed solvent synthesis of ZIF-8 nano- and micro-particles for CO adsorption: A response surface study

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Frontiers of Chemical Science and Engineering 2020年第4期14卷 579-594页

作者： alireza Hadi Javad Karimi-Sabet Abolfazl Dastbaz Department of Chemical Engineering Faculty of EngineeringUniversity of TehranTehranIran Material and Nuclear Fuel Research School(MNFRS) Nuclear Science and Technology Research InstituteTehranIran

The room temperature synthesis of ZIF-8 micro-and nano-particles was investigated using a mixed methanol-water solvent ***-8 particles of good quality and high crystallinity were *** surface methodology was used to determine the effect of the synthesis conditions on the ZIF-8 yield,particle size distribution,and mean particle *** ligand/metal salt molar ratio followed by the amount of sodium formate(the deprotonating agent)and then the amount of water(i.e,the composition of the mixed solvent)respectively had the largest effects on both the ZIF-8 yield and particle *** showed that mixing of solvents with different strengths in producing ZIF-8 crystals is a practical method to size-controlled synthesis of ZIF-8 *** method is more favorable for industrial-scale ZIF-8 synthesis than using excess amounts of ligands or chemical additives(like sodium formate).In addition,ZIF-8 samples with different mean particle sizes(100,500,and 1000 nm)were used for CO adsorption and the mid-sized ZIF-8 particles had the highest adsorption capacity.

关键词： metal organic frameworks zeolitic imidazo-late frameworks ZIF-8 response surface methodology Box Behnken design CO adsorption

Qubit movement-assisted entanglement swapping

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Chinese Physics B 2020年第5期29卷 92-100页

作者： Sare Golkar Mohammad Kazem Tavassoly alireza Nourmandipour Atomic and Molecular Group Faculty of PhysicsYazd UniversityYazd 89195-741Iran Photonic Research Group Engineering Research CenterYazd UniversityYazd 89195-741Iran Department of Physics Faculty of ScienceSirjan University of TechnologySirjanIran

We propose a scheme to generate entanglement between two distant qubits(two-level atom)which are separately trapped in their own(in general)non-Markovian dissipative cavities by utilizing entangling swapping,considering the case in which the qubits can move along their cavity axes rather than a static state of *** first examine the role of movement of the qubit by studying the entropy evolution for each *** average entropy over the initial states of the qubit is *** by performing a Bell state measurement on the fields leaving the cavities,we swap the entanglement between qubit-field in each cavity into qubit-qubit and field-field *** entangling power is used to measure the average amount of swapped entanglement over all possible pure initial *** results are presented in two weak and strong coupling regimes,illustrating the positive role of movement of the qubits on the swapped *** is revealed that by considering certain conditions for the initial state of qubits,it is possible to achieve a maximally long-leaving stationary entanglement(Bell state)which is entirely independent of the environmental variables as well as the velocity of *** happens when the two qubits have the same velocities.

关键词： dissipative systems quantum entanglement entanglement swapping

Secure ticket-based authentication method for IoT applications

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Digital Communications and Networks 2023年第3期9卷 710-716页

作者： Mojtaba Alizadeh Mohammad Hesam Tadayon alireza Jolfaei Computer Engineering Department Lorestan UniversityKhorramabadIran Iran Telecommunication Research Center(ITRC) TehranIran Department of Computing Macquarie UniversitySydneyAustralia

The recent surge in the number of machines,appliances,and services connected to the Internet demands secure processing and transmission of sensory *** plays a crucial role in a typical security model used in the Internet of Things(IoT),and it protects data communications from various attacks,such as impersonation and denial of service,by verifying and allowing legitimate users to access the IoT ***,recent authentication literature has not addressed the need for developing a scalable and efficient authentication method in this *** paper proposes a secure and anonymous ticket-based authentication method for the *** proposed method protects the network from various security and privacy threats such as data alternation and denial of service while also offering mutual authentication and sensor *** security and performance evaluations confirm the improvement.

关键词： IoT Internet of things Authentication Privacy Security

The power of microsatellite markers and AFLPs in revealing the genetic diversity of Hashemi aromatic rice from Iran

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Journal of Integrative Agriculture 2016年第6期15卷 1186-1197页

作者： alireza Tarang Anahita Bakhshizadeh Gashti Gilan Branch Agricultural Biotechnology Research Institute of Iran/Agricultural Research Education and Extension Organization (AREO)

Hashemi, a popular aromatic rice among Iranians, is famous for its fragrance and taste. Such features are major reasons for its higher price compared to non-aromatic varieties available in Iran. Therefore, the knowledge of genetic diversity of this profitable crop is a fundamental ineterst for plant breeders in future breeding programs. In the present research, genetic diversity among 35 genotypes of Hashemi aromatic rice （Oryza sativa L.） from Guilan and Mazandaran provinces of Iran was estimated using simple sequence repeat （SSR） and amplified fragment length polymorphism （AFLP） markers. Out of 21 SSR and 12 EcoRI-Msel AFLP marker combinations, only 16 SSRs and 10AFLPs exhibited polymorphic patterns while others were monomorphic. The 10 AFLP primer combinations produced a total of 142 of bands and 20 were polymorphic （14.08%）. Moreover, 40 out of 47 bands amplified with 16 SSR markers showed polymorphism （85.1%）. The average num- ber of alleles identified by SSR primers was 2.56 alleles per locus with a range of 2 to 4. The average value of polymorphic information content （PIC） was 0.393 and 0.468 for AFLP and SSR markers, respectively. However, the genetic similarity values ranged from 0.26 to 1 for SSRs and 0.21 to 1 forAFLPs. Later, a unweighted pair group method with arithmetic mean （UPGMA） dendrogram was generated and genotypes were clustered into four groups with SSRs at similarity coefficient of 0.55 while AFLPs clustered them into six groups at similarity coefficient of 0.41. Cluster analysis revealed a narrow genetic diversity and low correlation between geographical differentiation and genetic distance within cultivars.

关键词： Hashemi aromatic rice genetic diversity SSR AFLP

Electron-acoustic supernonlinear waves and their multistability in the framework of the nonlinear Schrödinger equation

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Communications in Theoretical Physics 2020年第7期72卷 71-80页

作者： alireza Abdikian Jharna Tamang Asit Saha Department of Physics Malayer UniversityMalayer 65719-95863Iran Department of Mathematics Sikkim Manipal Institute of TechnologySikkim Manipal UniversityMajitarRangpoEast-Sikkim 737136India

Finite-amplitude supernonlinear electron-acoustic waves(EAWs)are investigated under the nonlinear Schrödinger(NLS)equation in a plasma system that is composed of cold electronfluid,immobile ions and q-nonextensive hot *** the wave transfiguration,the NLS equation is deduced in a dynamical *** presence of finite-amplitude nonlinear and supernonlinear EAWs is shown by phase plane *** effects of the nonextensive parameter(q)and the speed of waves(v)on different traveling wave solutions of EAWs are ***,by introducing a small external periodic force in the dynamical system,multistability behaviors of EAWs under the NLS equation are shown for the first time in classical plasmas.

关键词： electron-acoustic wave dynamical system phase plane analysis nonextensive plasma