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Ce-promoted Mn/Na_2 WO_4/SiO_2 catalyst for oxidative coupling of methane at atmospheric pressure

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Journal of Natural Gas Chemistry 2010年第1期19卷 47-53页

作者： Seyed Mehdi kamali Shahri ali Nakhaei Pour Research Institute of Petroleum Industry (RIPI) National Iranian Oil Company P. O. Box 18745-4163 Tehran Iran

A series of Ce-promoted Mn-Na2WO4/SiO2 catalysts were prepared by incipient wetness impregnation method, and their catalytic performance for oxidative coupling of methane （OCM） was investigated at atmospheric pressure in a micro-quartz-tube reactor. The catalysts were characterized by X-ray diffraction （XRD）, temperature program reduction （TPR） and BET surface area. Ce promoter increased surface area and Na2WO4 species dispersion, which enriched the amount of the surface species. In addition, Ce promoter increased the Na/W species reduction, but the reduction peak shifted to higher temperature. Stability test of 5wt%Ce catalyst indicated suitable performance and stability. The selectivity and yield of C^2＋ hydrocarbons after 50 h operation reached 65.5% and 19.6%, respectively, at 840 ℃ over 5wt%Ce-2wt%Mn5wt%Na2WO4/SiO2 catalyst.

关键词： oxidative coupling of methane CeO2 promoter Mn/Na2WO4/SiO2

An investigation into the properties of ternary and binary cement pastes containing glass powder

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Frontiers of Structural and Civil Engineering 2019年第3期13卷 741-750页

作者： Marcelo Frota BAZHUNI Mahsa kamali ali GHAHREMANINEZHAD Department of Civil Architectural and Environmental EngineeringUniversity of MiamiCoral GablesFL 33146USA

The properties of binary and ternary cement pastes containing glass powder (GP) were *** at early age was evaluated using semi-adiabatic calorimetry and at late ages using non-evaporable water content and thermogravimetric *** transport characteristic was assessed by measuring electrical *** binary paste with slag showed the highest hydration activity compared to the binary pastes with GP and fly ash (FA).The results indicated that the pozzolanic behavior of the binary paste with GP was less than that of the binary pastes with slag or FA at late *** increase in the electrical resistivity and compressive strength of the binary paste with GP compared to other modified pastes at late ages was *** was shown that GP tends to increase the drying shrinkage of the *** pastes containing GP did not exhibit synergistic enhancements compared to the respective binary pastes.

关键词： cement paste glass powder pozzolanic reaction supplementary cementitious material

Association of H pylori cagA and vacA genotypes and IL-8 gene polymorphisms with clinical outcome of infection in Iranian patients with gastrointestinal diseases

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World Journal of Gastroenterology 2006年第32期12卷 5205-5210页

作者： Eskandar kamali-Sarvestani Abdulah Bazargani Malihe Masoudian Kamran Lankarani ali-reza Taghavi Mehdi Saberifiroozi Department of Immunology and Autoimmune Diseases Research Center Shiraz Medical School Shiraz University of Medical SciencesShirazIran Department of Bacteriology and virology Shiraz Medical School Shiraz University of Medical SciencesShirazIran Department of cellular and molecular sciences Khatam University TehranIran Gastrointestinal and Hepatology Research center Shiraz Medical School Shiraz University of Medical SciencesShirazIran Department of Internal medicine Shiraz Medical School Shiraz University of Medical SciencesShirazIran

AIM： To find out if a functional promoter polymorphism in the IL-8 gene along with cagA status and polymorphisms in vacA gene influence the type of diseases in Iranian patients infected by Hpylori. METHODS： IL-8 -251 A/T polymorphism was genotyped by oligonucleotide allele specific PCR （ASO-PCR） in a sample of 233 patients with Hpylori infection undergoing upper gastrointestinal endoscopy. The presence of cagA gene and polymorphisms in vacA gene was also determined by PCR. Association of these genetic polymorphisms with the development of gastritis, peptic ulcers as well as gastric cancer was tested. RESULTS： When the patients with different clinical manifestations were compared according to the presence of cagA gene or various vacA genotypes, only the vacA genotypes were significantly different among gastritis, peptic ulcer and gastric cancer patients （χ^2= 17.8; P=0.001）. Furthermore, there was a significant difference in the frequency of IL-8 -251 A/T genotypes between patients with gastric cancer and benign diseases （χ^2=10.47;P=0.005） CONCLUSION： The IL-8 -251 A/T polymorphism and the polymorphisms in H pylor/ vacA gene are involved in limiting the infection outcome to gastritis and peptic ulcer or in favoring cancer onset in Iranian patients.

关键词： Interleukin 8 Hpylori Gastric cancer Peptic ulcer Polymorphism

Synthesis of vinasse-dolomite nanocomposite biochar via a novel developed functionalization method to recover phosphate as a potential fertilizer substitute

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Frontiers of Environmental Science & Engineering 2020年第4期14卷 173-188页

作者： Nima kamali Abdollah Rashidi Mehrabadi Maryam Mirabi Mohammad ali Zahed Civil Water and Environmental Engineering FacultyShahid Beheshti University A.C.TehranIran Cell and Molecular Biology Department Faculty of Biological SciencesKharazmi UniversityTehranIran

The effectiveness of phosphate(P)removal from aqueous solutions was investigated by novel low-cost biochars synthesized from vinasse and functionalized with calcined *** vinasse-derived biochar,synthesized via pyrolysis at different temperatures,showed easy preparation and a large surface *** novel vinasse biochar nanocomposites were prepared by adding dolomite to the vinasse biochars with different weight percentages(10,20 and 30%).The characteristics of the prepared materials were identified for further understanding of the inherent adsorption mechanism between P ions and vinasse ***-dolomite nanocomposite was very effective in the adsorption of P species from aqueous *** effect of the operational factors on Vinasse-dolomite nanocomposite was explored by applying response surface methodology(RSM).According to RSM results,the optimum condition was achieved to be contact time 90(min),250(mg/L)of P concentration and pH *** isotherm and kinetic studies were applied on experimental data to understand the adsorption *** Vinasse-dolomite nanocomposite revealed preferential P species adsorption in the presence of co-existing *** P species could be recovered by 1.0 MHC 1 where the efficiency was not affected up to the fifth *** P-loaded Vinasse-dolomite nanocomposite was successfully tested on a plant;it significantly improved its growth and proved its potency as a P-based fertilizer substitute.

关键词： Biochar Vinasse Dolomite Phosphate Fertilizer

Fischer-Tropsch synthesis by reduced graphene oxide nanosheets supported cobalt catalysts: role of support and metal nanoparticle size on catalyst activity and products selectivity

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Frontiers of Chemical Science and Engineering 2021年第2期15卷 299-309页

作者： Hasan Oliaei Torshizi ali Nakhaei Pour ali Mohammadi Yahya Zamani Seyed Mehdi kamali Shahri Department of Chemistry Faculty of ScienceFerdowsi University of MashhadMashhad ***Iran Gas Research Division Research Institute of Petroleum IndustryTehran ***Iran Department of Chemical Engineering Pennsylvania State UniversityState CollegePA 16801USA

In this paper,a series of cobalt catalysts supported on reduced graphene oxide(rGO)nanosheets with the loading of 5,15 and 30 wt-%were provided by the impregnation *** activity of the prepared catalysts is evaluated in the Fischer-Tropsch synthesis(FTS).The prepared catalysts were carefully characterized by nitrogen adsorption-desorption,hydrogen chemisorption,X-ray diffraction,Fourier transform infrared spectroscopy,Raman spectroscopy,temperature programmed reduction,transmission electron microscopy,and field emission scanning electron microscopy techniques to confirm that cobalt particles were greatly dispersed on the rGO *** results showed that with increasing the cobalt loading on the rGO support,the carbon defects are increased and as a consequence,the reduction of cobalt is *** FTS activity results showed that the cobalt-time yield and turnover frequency passed from a maximum for catalyst with the Co0 average particle size of 15 nm due to the synergetic effect of cobalt reducibility and particle *** products selectivity results indicated that the methane selectivity decreases,whereas the C5+selectivity raises with the increasing of the cobalt particle size,which can be explained by chain propagation in the primary chain growth reactions.

关键词： cobalt catalyst cobalt particle size Fischer-Tropsch synthesis reduced graphene oxide supported catalyst

Temperature-dependent development of diamondback moth, Plutella xylostella （Lepidoptera： Plutellidae） on two brassicaceous host plants

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Insect Science 2007年第4期14卷 309-316页

作者： ali GOLIZADEH KARIM kamali YAGHOUB FATHIPOUR HABIB ABBASIPOUR DepartmentofEntomology FacultyofAgricultureTarbiatModaresUniversityTehran Department of Plant Protection Faculty of Agricultural SciencesShahed UniversityTehranIran

The effect of temperature on the development of the Plutella xylostella （Linnaeus）（Lepidoptera： PluteUidae）, was evaluated at eight constant temperatures （10, 15, 20, 25, 28, 30, 32.5 and 35~C）, with relative humidity of 65% and a photoperiod of 14：10 （L： D） hours on two host plants, cauliflower, Brassica oleracea var. botrytis and cabbage, Brassica oleracea var. capitata. The low temperature threshold was estimated to be 7.06℃ and 7.84℃ and the thermal constant was 263.74 and 261.58 degree-days for P. xylostella on cauliflower and cabbage, respectively, using the linear model. Data were fitted to various nonlinear temperature-dependent models, and the low and high temperature thresholds, as well as the optimum temperature for development, has been estimated. Criteria of choice from the literature were used to evaluate models and to select the most suitable equation for P. xylostella development on each host plant. Conclusively, linear and Briere-2 models are recommended for the description of temperature-dependent development of P. xylostella on two host plants.

关键词： Brassica oleracea degree-days development rate Plutella xylostella tem-perature-dependent thermal requirement

Promoter effect on the CO_2-H_2O formation during Fischer-Tropsch synthesis on iron-based catalysts

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Journal of Natural Gas Chemistry 2010年第2期19卷 193-197页

作者： ali Nakhaei Pour Seyed Mehdi kamali Shahri Yahya Zamani Akbar Zamanian Research Institute of Petroleum Industry (RIPI) of National Iranian Oil Company Gas Research DivisionP.O.Box 14665-137TehranIran

The effects of Mg,La and Ca promoters on primary and secondary CO2 and H2O formation pathways during Fischer-Tropsch synthesis on precipitated Fe/Cu/SiO2 catalysts are *** chemisorbed oxygen atoms in the primary pathway formed in the CO dissociation steps reacted with co-adsorbed hydrogen or carbon monoxide to produce H2O and CO2,*** secondary pathway was the water-gas shift *** results indicated that the CO2 production led to an increase in both primary and secondary pathways,and H2O production decreased when surface basicity of the catalyst increased in the order Ca 〉 Mg 〉 La.

关键词： Ca promoter Mg promoter La promoter Fischer-Tropsch synthesis iron-based catalyst water-gas shift reaction

Deactivation studies of bifunctional Fe-HZSM5 catalyst in Fischer-Tropsch process

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Journal of Natural Gas Chemistry 2008年第3期17卷 242-248页

作者： ali Nakhaei Pour Seyed Mehdi kamali Shahri Yahya Zamani Mohammad Irani Shohreh Tehrani Research Institute of Petroleum Industry National Iranian Oil Company

A physical mixture of alkali-promoted iron catalyst with binder based on Fischer-Tropsch synthesis and an acidic co-catalyst （HZSM5） for syngas conversion to hydrocarbons was studied in a fixed bed micro reactor. Deactivation data were obtained during the synthesis over a 1400 h period. The deactivation studies on iron catalyst showed that this trend followed the phase transformation Fe2.2C （ ε′） → Fe5C2 （χ） → Fe3C （θ）, and the final predominant phase of the catalyst was Fe3C （θ）. Deactivation of zeolite component in bifunctional catalyst may be caused by coking over the zeolitic component, dealumination of zeolite crystals, and migration of alkali promoters from iron catalyst under synthesis conditions. The deactivation rate of iron catalyst was also obtained.

关键词： catalyst deactivation Fischer-Tropsch synthesis iron catalyst HZSM5 zeolite

Hydrocarbon production rates in Fischer-Tropsch synthesis over a Fe/Cu/La/Si catalyst

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Journal of Energy Chemistry 2013年第1期22卷 119-129页

作者： ali Nakhaei Pour Farshad Riyahi Mohammad reza Housaindokht Mohammad Irani Seyed Mehdi kamali Shahri Behnam Hatami Department of Chemistry Ferdowsi University of Mashhad Department of Chemical Engineering Petroleum University of Technology (PUT) Research Institute of Petroleum Industry of National Iranian Oil Company Chemical Engineering Department Penn State University University Park

The detailed kinetics of Fischer-Tropsch synthesis over an industrial Fe/Cu/La/Si catalyst was studied in a continuous spinning basket re- actor under the conditions relevant to industrial operations. Reaction rate equations were derived on the basis of Langmuir-Hinshelwood- Hougen-Watson type models for Fischer-Tropsch synthesis based on possible reactions sets originated from the carbide, enolic and combined enol/carbide mechanisms. Kinetic model candidates were evaluated by the global optimization of kinetic parameters, which were realized by first minimization of multi-response objective functions with conventional Levenberg-Marquardt method. It was found that an enolic mech- anism based model could produce a good fit of the experimental data. The activation energy for paraffin formation is 95 ***1-1 which is smaller than that for olefin formation （121 ***-1）.

关键词： Fischer-Tropsch synthesis kinetics iron catalysts catalysts selectivity