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Re-evaluation of several heavy metals removal by natural limestones

Frontiers of Chemical Science and Engineering 2014年第4期8卷 418-432页

作者： ali sdiri Samir BOUAZIZ Laboratory of Water Energy and Environment National Engineering School University of Sfax Sfax 1173-3038 Tunisia

Different treatment technologies have been efficiently applied to remove heavy metals from waste- water. Efforts have been made to find out the most economic water treatment technology by using low cost and easily accessible natural materials. On the other hand, heavy metals are the most threatening groundwater contaminants because of their toxicity and harmful effects on human and biota. This review discusses the use of natural geological materials for heavy metal removal in aqueous systems. Special attention has been devoted to natural limestone through a systematic inventory of relevant published reports. The removal of toxic metals may include different mechanisms （e.g., physisorption, chemisorptions, precipitation, etc.）, depending on the physico-chemical properties of the material and the removed metal. Sorption of toxic metals （e.g., Pb, Cu, Cd, Zn, Cr, Hg, etc.） onto natural limestone involved precipitation of metal carbonate as a predominant removal process, but often subordinated by adsorption and ion exchange, depending on the physico-chemical properties of the studied limestone.

关键词： limestone heavy metals sorption waste-water passive treatment technology

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Technological Characterization and Industrial Application of Tunisian Clays from Makthar Area (Central Tunisia) in the Ceramic Industry

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Open Journal of Geology 2016年第7期6卷 626-639页

作者： Imed Ben Salah Moufida Ben M’Barek Jemai ali sdiri Najet Shimi Slim Mabrouk Boughdiri Department of Geology University of Sciences of Bizerte Bizerte Tunisia National Engineering School of Sfax Sfax Tunisia Department of Geology University of Sciences of Tunis Tunis Tunisia

This study focused on the geochemical, mineralogical and technological characterization of clays in Makthar area (Central of Tunisia) of Cretaceous-Paleogene. Its aims are to identify and promote use in the field of ceramics industry. The result of the mineralogical analysis of clays showed a dominance of illite with a percentage higher than 65%, of kaolinite and smectite with percentages of 15%. Geochemical analysis of the major elements of clay showed a SiO2 content exceeding 29% and a percentage of Al2O3 higher than 7.5%. The Fe2O3 percentage was ranging from 3% to 8%. The percentage of CaO was between 22.5% and 28% while that of K2O is 4%. The percentages of SO4, MgO and NaO2 were in very small fractions. Granulometric and microgranulometric analysis showed that the clay fraction (2/g to 178 m2/g reflecting illite dominance. Drying behavior indicated that clay mixture had a drying shrinkage less than 7%, while the firing shrinkage didn’t exceed 2% giving the possibility of clay using in the ceramics field.

关键词： Clay Mineral Mineralogy Chemical and Physical Properties Ceramic Industry

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Properties of Debadib Evaporates (Northern Tunisia) for Potential Use in Industrial Fields

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Open Journal of Geology 2016年第12期6卷 1525-1538页

作者： Imed Ben Salah Moufida M’barek Jemaii Narjess Karoui-Yaakoub ali sdiri Noureddine Ben Ayed Department of Geology Sciences University of Bizerte Bizerte Tunisia Department of Georesources and Environment National Engineering School University of Sfax Sfax Tunisia

Gypsum is widely distributed in Tunisia occurring in the formation of Triassic age. The gypsum deposit of Mellegue is the alabastine type with a little of the porphyroblast type and contains traces of clay minerals and calcite. It is a moderately strong rock in terms of its unconfined compressive strength of 16 Mpa and tensile strength of 3.35 Mpa. Triaxial testing values indicated an apparent cohesion of 10 Mpa and an angle of friction of 26°. The gypsum studied had a percentage of SO3 of 41.71% and a percentage of CaO of 32.9%. All the samples had low densities according to the International Association of Engineering Geology (IAEG) classification and exhibited a moderate porosity whether effective or absolute. The gypsum proved to be moderately strong when tested in unconfined compression and tensile strength. Thermal analysis indicated a total weight loss of 20.27% and the whiteness index about 90%. This proved a high degree of whiteness. The time of setting can be considered short and medium, which is quite favorable for industrial application compared with other gypsum deposits currently operated.

关键词： Triassic Gypsum Deposit Mineralogical Analysis Physicochemical Analysis Geotechnical Testing Industrial Use

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Effects of Lizardite Addition on Technological Properties of Forsterite- monticellite Rich Ceramics Prepared from Natural Magnesite and Dolomite

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Journal of Construction Research 2020年第1期2卷 9-20页

作者： Ahmed Manni Achraf Harrati Abdelilah El Haddar Abdelwahed Chari ali sdiri Fahd Oudrhiri Hassani Abdeslam El Bouari Iz-Eddine El Amrani El Hassani Chaouki Sadik Laboratory of Physical Chemistry of Applied Materials(LPCMA) Department of ChemistryFaculty of Sciences Ben MsikHassan II University of CasablancaMorocco Laboratory of Applied Geosciences Faculty of SciencesUniversity of Mohammed 1OujdaMorocco Materials Sciences Energy and Nano-engineering DepartmentMohammed VI Polytechnic UniversityBen GuerirMorocco Department of Georessources and Environment National Engineering SchoolUniversity of SfaxP.Box 3052SfaxTunisia LMPEQ University of Cadi AyyadENSA of SAFIMorocco Geomaterials and Geo environment Team/Geo-Biodiversity and Natural Patrimony Laboratory (GEOBIO)/GeophysicsNatural Patrimony and Green Chemistry Research Centre(GEOPAC)Scientific InstitutMohammed V University of RabatMorocco

Lizardite rich peridotite has never been used to prepare ceramic specimens,especially in *** this raison,potential use of naturally abundant lizarditic material from the Rif domain,as a supply for ceramic industry,has been *** effects of lizardite addition to magnesite and dolomite mixtures on the thermomechanical properties of the calcined ceramics were also *** achieve this target,natural lizardite,magnesite and dolomite samples were collected in ultrabasic Beni Bousra *** raw samples were used for the synthesis of a forsterite-monticellite rich *** raw and sintered samples were characterized by x-ray diffraction,scanning electron microscope and fourier transform *** obtained results showed that both magnesite and dolomite were mainly composed of MgCO_(3) and CaCO_(3).In contrast,lizardite sample showed high amounts of SiO_(2),MgO and Fe2O_(3).An increased amount of lizardite in the initial mixtures enhanced mechanical and dimensional properties of the prepared ceramic specimens,and subsequently,the production of ceramics with the required technological ***,the preparation of Moroccan lizardite-based ceramics is technically feasible,economically justifiable and socially desirable due to the contribution to the economic growth of the raw materials sector,especially ceramic industry.

关键词： Forsterite Monticellite Lizardite Basic ceramics Temperature

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