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Characterization and Electrochemical Properties of Nanostructured Zr-Doped Anatase TiO_2 Tubes Synthesized by Sol–Gel Template Route

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Journal of Materials Science & Technology 2017年第6期33卷 527-534页

作者： Denis P.Opra Sergey V.Gnedenkov Sergey L.Sinebryukhov Elena I.Voit alexander a.sokolov Evgeny B.Modin Anatoly B.Podgorbunsky Yury V.Sushkov Veniamin V.Zheleznov Institute of Chemistry Far Eastern Branch of Russian Academy of Sciences Far Eastern Federal University National Research Centre "Kurchatov Institute"

A series of nanostructured Zr-doped anatase TiO_2 tubes with the Zr/Ti molar ratio of 0.01, 0.02, 0.03, and0.09 were prepared by a sol–gel technology on a carbon fiber template. The electrochemical performance of Zr-doped anatase TiO_2 as anodes for rechargeable lithium batteries was investigated and compared with undoped titania. Tests represented that after 35-fold charge/discharge cycling at C/10 the reversible capacity of Zr-doped titania（Zr/Ti = 0.03） reaches 135 m A h g^（-1）, while the capacity of undoped titania（Zr/Ti = 0） yielded only 50 m A h g^（-1）. Based on the results of the physicochemical investigation, three reasons of improving electrochemical performance of Zr-doped titania were suggested. According to the scanning electron microscopy and transmission electron microscopy, Zr^（4＋） doping induces a decrease in nanoparticle size, which facilitates the Li＋diffusion. The Raman investigations show the more open structure of Zr-doped TiO_2 as compared to undoped titania due to changing of the unit cell parameters, that significantly affects on the reversibility of the insertion/extraction process. The electrochemical impedance spectroscopy results indicate that substitution of Zr^（4＋） for Ti^（4＋） into anatase TiO_2 has favorable effects on the conductivity.

关键词： Li-ion batteries Anatase titania Nanostructured materials Sol–gel template process Doping Electrochemical performance

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Submonolayer Eu superstructures—A class of 2D magnets

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Nano Research 2023年第1期16卷 1500-1506页

作者： Dmitry V.Averyanov Ivan S.sokolov alexander N.Taldenkov Oleg E.Parfenov Andrey M.Tokmachev Vyacheslav G.Storchak National Research Center“Kurchatov Institute” Kurchatov Sq.1Moscow 123182Russia

Two-dimensional(2D)magnetic materials promise unconventional properties and quantum phases as well as advances in ultracompact *** of 2D magnets often reaches a single monolayer but in general can go beyond this limit,as demonstrated by 2D magnetism of submonolayer Eu superstructures coupled with *** question is whether the submonolayer magnetism constitutes a general ***,we demonstrate that regular Eu lattices form a class of 2D magnets displaying various structures,stoichiometries,and chemical *** synthesized and studied a set of Eu superstructures on Ge(001).Their magnetic properties are consistent with the emergence of a magnetic order such as ferro-or *** particular,control over the magnetic transition temperature by weak magnetic fields indicates the 2D nature of the *** together,Eu/Ge and Eu/Si superstructures seed a nucleus of the research area addressing the emergence of magnetism in submonolayer chemical species.

关键词： two-dimensional(2D)magnetism submonolayer superstructure surface reconstruction germanium

A class of high-mobility layered nanomaterials by design

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Journal of Materials Science & Technology 2023年第33期164卷 179-187页

作者： Dmitry V.Averyanov Ivan S.sokolov Oleg E.Parfenov alexander N.Taldenkov Oleg A.Kondratev Andrey M.Tokmachev Vyacheslav G.Storchak National Research Center “Kurchatov Institute” Kurchatov Sq.1Moscow 123182Russia

Design of materials with particular functional properties is indispensable albeit very *** and structural analogies can be helpful in this endeavor,especially when a particular combination of properties is sought *** aim is to bundle together 3 characteristics:high carrier mobility,magnetism,and scalability to nanomaterials in the form of a film–such a combination is particularly advantageous for ***,inspired by recent studies of MAl_(2)Si_(2)and related compounds,we develop magnetic EuAl_(2)Ge_(2)and non-magnetic SrAl_(2)Ge_(2)nanomaterials with high carrier *** syntheses employing sacrificial 2D templates result in epitaxial films of MAl_(2)Ge_(2)seamlessly integrated with *** syntheses are followed by a study of the atomic structure,magnetic and electron transport *** particular,the films demonstrate high carrier mobility,exceeding 10,000 cm^(2)V^(-1)s^(-1)in the case of EuAl_(2)Ge_(2),making the materials appealing for *** together,MAl_(2)Ge_(2)and MAl_(2)Si_(2)form a class of high-mobility layered nanomaterials.

关键词： High carrier mobility Magnetism SrAl_(2)Ge_(2) EuAl_(2)Ge_(2) Germanium

Electromagnetic shielding effectiveness of amorphous metallic spheroidal-and flake-based magnetodielectric composites

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Journal of Materials Science & Technology 2021年第24期83卷 256-263页

作者： Kun Qian Qifan Li alexander sokolov Chengju Yu Piotr Kulik Ogheneyunume Fitchorova Yajie Chen Chins Chinnasamy Vincent G.Harris Center for Microwave Magnetic Materials and Integrated Circuits Department of Electrical and Computer EngineeringNortheastern UniversityBostonMA02115USA KRI at Northeastern University LLC141 South Bedford StreetBurlingtonMA01803USA Rogers Innovation Center Rogers Corporation141 South Bedford StreetBurlingtonMA01803USA Carpenter Technology Corporation ReadingPA19601USA

Flexible,lightweight,conductive materials,having both high rf losses and high permeability,are extremely desirable for applications as electromagnetic(EM)*** atomized spherical FeSi-based ferromagnetic metallic particles,having a mean diameter of 14.6μm with a standard deviation of 7.3μm,were measured to have a room temperature saturation magnetic flux density of 1.49 T with a coercivity of 160 A/*** milling of the amorphous particles led to aspect ratios from 1:1(spherical)to>100:1(flake-like).Flake-like particles,suspended in paraffin,were found to not only increase the surface area of fillers enhancing the polarization mechanism but also increase the complex permeability and complex permittivity,and thus provide broadband shielding effectiveness.A loading factor of 40 vol.%of the∼15μm diameter powders provided the largestΔW_(RL=-20 dB)of 9.49 GHz(i.e.,6.55

关键词： Amorphous particle Magnetic alloy powders Microwave absorption Electromagnetic interference shielding

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Competing magnetic states in silicene and germanene 2D ferromagnets

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Nano Research 2020年第12期13卷 3396-3402页

作者： Dmitry V.Averyanov Ivan S.sokolov Mikhail S.Platunov Fabrice Wilhelm Andrei Rogalev Pierluigi Gargiani Manuel Valvidares Nicolas Jaouen Oleg E.Parfenov alexander N.Taldenkov Igor A.Karateev Andrey M.Tokmachev Vyacheslav G.Storchak National Research Center“Kurchatov Institute” Kurchatov Sq.1Moscow123182Russia ESRF-The European Synchrotron CS 4022038043Grenoble Cedex 9France ALBA Synchrotron Light Source Cerdanyola del Vallès08290BarcelonaSpain L’Orme des Merisiers Synchrotron SOLEILGyf-sur-Yvette91192France

Two-dimension(2D)magnets have recently developed into a class of stoichiometric materials with prospective applications in ultra-compact spintronics and quantum *** functionality is particularly rich when different magnetic orders are competing in the same *** REX2(RE=Eu,Gd;X=Si,Ge),silicene or germanene—heavy counterparts of graphene—coupled with a layer of rare-earth metals,evolve from three-dimension(3D)antiferromagnets in multilayer structures to 2D ferromagnets in a few *** evolution,however,does not lead to fully saturated 2D ferromagnetism,pointing at a possibility of coexisting/competing magnetic ***,REX2 magnetism is explored with element-selective X-ray magnetic circular dichroism(XMCD).The measurements are carried out for GdSi2,EuSi2,GdGe2,and EuGe2 of different thicknesses down to 1 monolayer employing K absorption edges of Si and Ge as well as M and L edges of the *** access the magnetic state in REX2 and determine the seat of magnetism,orbital,and spin contributions to the magnetic ***-field measurements probe remnants of the bulk antiferromagnetism in 2D *** results provide a new platform for studies of complex magnetic structures in 2D materials.

关键词： silicene germanene 2D ferromagnetism X-ray magnetic circular dichroism(XMCD) monolayer

Decision Support System for Water-User Associations in the Aral Sea Basin

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Decision Support System for Water-User Associations in the A...

汽油机GPF碳载量模型和再生策略的试验研究

国际农业工程大会

作者： Dukhovny Viktor A. Tuchin alexander I. sokolov Vadim I. 11 Massiv Karasu 4 700187 Tashkent Uzbekistan Prof.Director SIC ICWC Chief Division SIC ICWC Manager of project “IWRM-Fergana” PhD

＜正＞ DSS for WUA in Aral Sea basin. Transition to the market economy in Central Asia states accompanied by change of irrigation institutional structure - instead of big collective or state farms a lot of private landowners keep most part of irrigated lands. It requested organization of Water users Associations. Members and staff of WUAs have certain requirements in tools for proper water management. SIC ICWC together with its partners and Lisbon University

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内燃机与动力装置 2018年第6期35卷 1-10,25页

作者：范明哲张宾 Sterzer alexander sokolov Dimitri 博世(中国)投资有限公司博世工程技术事业部上海200335 BoschEngineeringGmbH heilbronn74003

针对某V型六缸GDI机械增压汽油机,搭建基于Matlab Simulink平台的颗粒捕集器(gasoline particulate filter,GPF)碳载量模型,通过试验数据对模型中的相关脉谱进行仿真标定;并对样机的GPF主动及被动再生策略进行研究,评价分析策略表现。... 详细信息

针对某V型六缸GDI机械增压汽油机,搭建基于Matlab Simulink平台的颗粒捕集器(gasoline particulate filter,GPF)碳载量模型,通过试验数据对模型中的相关脉谱进行仿真标定;并对样机的GPF主动及被动再生策略进行研究,评价分析策略表现。模型试验验证结果表明,累碳模型的偏差值为+5.8%;主动再生模型的偏差值为+9%;被动再生(断油)模型的偏差值为+6%;综合碳载量模型的偏差值为+3%,模型精度良好。

关键词：汽油机 GPF 碳载量模型再生策略

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Emerging 2D magnetic states in a graphene-based monolayer of EuC_(6)

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Nano Research 2022年第1期15卷 408-413页

作者： Ivan S.sokolov Dmitry V.Averyanov Fabrice Wilhelm Andrei Rogalev Oleg E.Parfenov alexander N.Taldenkov Igor A.Karateev Andrey M.Tokmachev Vyacheslav G.Storchak National Research Center“Kurchatov Institute” Kurchatov Sq.1Moscow 123182Russia ESRF-The European Synchrotron CS 4022038043 Grenoble Cedex 9France

Recent discoveries of intrinsic two-dimensional(2D)magnets open up vast opportunities to address fundamental problems in condensed matter physics,giving rise to applications from ultra-compact spintronics to quantum *** ever-growing material landscape of 2D magnets lacks,however,carbon-based systems,prominent in other areas of 2D *** measurements of the Eu/graphene compound-a monolayer of the EuC_(6) stoichiometry-reveal the emergence of 2D ferromagnetism but detailed studies of competing magnetic states are still ***,we employ element-selective X-ray absorption spectroscopy(XAS)and magnetic circular dichroism(XMCD)to establish the magnetic structure of monolayer *** system exhibits the anomalous Hall effect,negative magnetoresistance,and magnetization consistent with a ferromagnetic state but the saturation magnetic moment(about 2.5/%/Eu)is way too low for the half-filled f-shells of Eu^(2+)*** XAS/XMCD studies at the Eu L3 absorption edge probe the EuC6 magnetism in high fields and reveal the nature of the missing magnetic *** results are set against XMCD studies in Eu/silicene and Eu/germanene to establish monolayer EuC6 as a prominent member of the family of Eu-based 2D magnets combining the celebrated graphene properties with a strong magnetism of europium.

关键词： two-dimensional(2D)ferromagnetism graphene EuC_(6) X-ray magnetic circular dichroism(XMCD) monolayer

Hepatobiliary system and intestinal injury in new coronavirus infection(COVID-19):A retrospective study

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World Journal of Clinical Cases 2023年第10期11卷 2226-2236页

作者： Konstantin V Kozlov Konstantin V Zhdanov Anna K Ratnikova Vyacheslav A Ratnikov Artem V Tishkov Vladimir Grinevich Yuriy A Kravchuk Panteley I Miklush Polina O Nikiforova Vera V Gordienko alexander F Popov Boris G Andryukov Department of Infectious Disease Military Medical Academy Named After SM.KirovSaint-Petersburg 194044Russia Department of Admission Federal State Budgetary Institution"North-West District Scientific and Clinical Center Named After LG.Sokolov Federal Medical and Biological Agency"Saint-Petersburg 194291Russia Department of Roentgenology Federal State Budgetary Institution"North-West District Scientific and Clinical Center Named After LG.Sokolov Federal Medical and Biological Agency"Saint-Petersburg 194291Russia Department of Physics Mathematics and InformaticsFSBEI HE IP.Pavlov SPbSMU MOH RussiaSaint-Petersburg 197022Russia 2nd Department of Therapy(Advanced Medical Education) Military Medical Academy Named After SM.KirovSaint-Petersburg 194044Russia School of Medicine Far Eastern Federal UniversityVladivostok 690922Russia

BACKGROUND An important area of effective control of the coronavirus disease 19(COVID-19)pandemic is the study of the pathogenic features of severe acute respiratory syndrome coronavirus 2 infection,including those based on assessing the state of the intestinal microbiota and *** To study the clinical features of the new COVID-19 in patients with mild and moderate severity at the stage of hospitalization,to determine the role of hepatobiliary injury,intestinal permeability disorders,and changes in the qualitative and quantitative composition of the microbiota in the development of systemic inflammation in patients with *** The study was performed in 80 patients with COVID-19,with an average age of 45 years,19 of whom had mild disease,and 61 had moderate disease *** scope of the examination included traditional clinical,laboratory,biochemical,instrumental,and radiation studies,as well as original methods for studying microbiota and intestinal *** The clinical course of COVID-19 was studied,and the clinical and biochemical features,manifestations of systemic inflammation,and intestinal microbiome changes in patients with mild and moderate severity were *** permeability characteristics against the background of COVID-19 were evaluated by measuring levels of proinflammatory cytokines,insulin,faecal calprotectin,and *** This study highlights the role of intestinal permeability and microbiota as the main drivers of gastroenterological manifestations and increased COVID-19 severity.

关键词： Novel coronavirus infection COVID-19 SARS-CoV-2 Zonulin Faecal calprotectin Microbiota