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Phase composition,conductivity,and sensor properties of cerium-doped indium oxide

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Nano materials Science 2024年第2期6卷 193-200页

作者： m.i.ikim G.N.Gerasimov V.F.Gromov o.J.ilegbusi L.i.Trakhtenberg N.N.Semenov Federal Research Center for Chemical Physics of RAS MoscowRussia University of Central Florida OrlandoFLUSA moscow institute of Physics and Technology(State University) DolgoprudnyMoscow RegionRussia Lomonosov moscow State University MoscowRussia

The hydrothermal synthesis of in_(2)o_(3)and Ceo_(2)–in_(2)o_(3)is investigated as well as the properties of sensor layers based on these compounds.During the synthesis of in_(2)o_(3),intermediate products in(oH)_(3)and inooH are formed,which are the precursors of stable cubic(c-in_(2)o_(3))and metastable rhombohedral(rh-in_(2)o_(3))phases,respectively.A transition from c-in_(2)o_(3)to rh-in_(2)o_(3)is observed with the addition of Ceo_(2).The introduction of cerium into rh-in_(2)o_(3)results in a decrease in the sensor response to hydrogen,while it increases in composites based on c-in_(2)o_(3).The data on the sensor activity of the composites correlate with XPS results in which Ceo_(2)causes a decrease in the concentrations of chemisorbed oxygen and oxygen vacancies in rh-in_(2)o_(3).The reverse situation is observed in composites based on c-in_(2)o_(3).Compared to in_(2)o_(3)and Ceo_(2)–in_(2)o_(3)obtained by other methods,the synthesized composites demonstrate maximum response to H_(2)at low temperatures by 70–100℃,and have short response time(0.2–0.5 s),short recovery time(6–7 s),and long-term stability.A model is proposed for the dependence of sensitivity on the direction of electron transfer between in_(2)o_(3)and Ceo_(2).

关键词： Cerium oxide indium oxide Nanocomposite Hydrothermal method Cubic phase Rhombohedral phase Sensor response Conductivity Hydrogen Response/recovery time

Biofabrication of nanocomposite-based scaffolds containing human bone extracellularmatrix for the differentiation of skeletal stem and progenitor cells

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Bio-design and manufacturing 2024年第2期7卷 121-136页

作者： Yang-Hee Kim Janos m.Kanczler Stuart Lanham Andrew Rawlings marta Roldo Gianluca Tozzi Jonathan i.Dawson Gianluca Cidonio Richard o.C.oreffo Faculty of medicine Bone and Joint Research GroupCentre for Human DevelopmentStem Cells and RegenerationInstitute of Developmental SciencesUniversity of SouthamptonSouthampton SO166YDUK School of Pharmacy and Biomedical Science University of PortsmouthPortsmouth PO12DTUK School of Engineering Faculty of Engineering and ScienceUniversity of GreenwichGreenwich ME44TBUK Center for Life Nano-and Neuro-Science(CLN2S) Italian Institute of Technology00161 RomeItaly

Autograft or metal implants are routinely used in skeletal repair.However,they fail to provide long-term clinical resolution,necessitating a functional biomimetic tissue engineering alternative.The use of native human bone tissue for synthesizing a biomimeticmaterial inkfor three-dimensional(3D)bioprintingof skeletal tissueis anattractivestrategyfor tissueregeneration.Thus,human bone extracellular matrix(bone-ECm)offers an exciting potential for the development of an appropriate microenvironment for human bone marrow stromal cells(HBmSCs)to proliferate and differentiate along the osteogenic lineage.in this study,we engineered a novel material ink(LAB)by blending human bone-ECm(B)with nanoclay(L,Laponite®)and alginate(A)polymers using extrusion-based deposition.The inclusion of the nanoﬁller and polymeric material increased the rheology,printability,and drug retention properties and,critically,the preservation of HBmSCs viability upon printing.The composite of human bone-ECm-based 3D constructs containing vascular endothelial growth factor(VEGF)enhanced vascularization after implantation in an ex vivo chick chorioallantoic membrane(CAm)model.The inclusion of bone morphogenetic protein-2(BmP-2)with the HBmSCs further enhanced vascularization and mineralization after only seven days.This study demonstrates the synergistic combination of nanoclay with biomimetic materials(alginate and bone-ECm)to support the formation of osteogenic tissue both in vitro and ex vivo and offers a promising novel 3D bioprinting approach to personalized skeletal tissue repair.

关键词： Extracellular matrix Nanoclay Bone 3D bioprinting

Enhancement of coercivity,permeability,and dielectric properties of Co_(0.2)Zn_(0.3)Ni_(0.5)Eu_(x)Fe_(2)-xo_(4) ferrites for memory and high frequency devices

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Journal of Rare Earths 2024年第6期42卷 1128-1135,I0005页

作者： i.Sardar m.D.Hossain m.S.Sikder m.N.i.Khan m.R.Rahman Physics Discipline Khulna UniversityKhulna9208Bangladesh department of Physics Khulna University of Engineering&TechnologyKhulna9203Bangladesh department ofComputer Science and Engineering Northern University of Business&Technology KhulnaKhulna9100Bangladesh material Science Division Atomic Energy CentreDhaka1000Bangladesh

Spinel cubic ferrites have huge applications in me mory and high frequency devices.For the improvement of these modern devices,the magnetic coercivity,permeability,and dielectric properties of a ferrite are the important issues.This article focuses on improving the magnetic coercivity,magnetic permeability,and dielectric properties of Co_(0.2)Zn_(0.3)Ni_(0.5)Eu_(x)Fe_(2)-xo_(4) ferrites,where x=0.00,0.06,and 0.10.The X-ray diffraction(XRD),Fourier transform infrared spectroscopy(FTiR),field emission scanning electron microscopy(FESEm),energy dispersive X-ray(EDX),vibrating sample magnetometer(VSm),and an impedance analyzer were used to characterize the structural,magnetic,and dielectric properties of the samples.The XRD patterns indicate the formation of spinel cubic structure of the samples with a secondary peak(EuFeo_(3))for Eu doped samples.The densities and porosities of the samples follow an inverse trend,where the doped samples’lattice parameters are increased with the increment of rare earth Eu concentration.The FTiR analysis also proves the spinel cubic phase of the samples.The average grain size of the ferrites is obtained via FESEm images,and it is increased from 121 to 198 nm.VSm analysis confirms that doping of the Eu content also changes other hysteresis loop properties of Co_(0.2)Zn_(0.3)Ni_(0.5)Eu_(x)Fe_(2)-xo_(4) ferrites.Particularly,the coercivity of the Eu doped samples is greater than that of the mother alloy(x=0.00).The EDX study shows that there is no impurity contamination in the ferrites.The permeability and dielectric measurements show an improved quality factor of the Eu-doped samples with low magnetic and dielectric losses.Frequency dependent resistivity and impedance analysis also show the improved nature.From the observed properties of the samples,all the investigated ferrites might be strong candidates for potential applications in memory devices,magnetic sensors,and high frequency applications.

关键词： Ferrites Raree arths Coercivity Permeability EDX Resistivity

Hydroxyapatite composites with carbon allotropes:Preparation,properties,and applications

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Particuology 2024年第5期88卷 239-265页

作者： Boris i.Kharisov oxana V.Kharissova Lucy T.González Yolanda Peña méndez igor E.Uflyand idalia Gómez de la Fuente Universidad Autónoma de Nuevo León Ave.UniversidadCiudad UniversitariaSan Nicolás de los GarzaNuevo León 66455Mexico Tecnologico de monterrey Escuela de Ingeniería y CienciasMonterreyNuevo Leon 64890Mexico department of Chemistry Southern Federal UniversityRostov-on-DonRussia

Hydroxyapatite(HA)and its composites with inorganic additives,dopants,and polymers is a rapidly developing branch in the materials chemistry.in particular,carbon allotropes are widely used in these composites being widely applied for medical purposes.observing a gap of insufficient generalization of recent achievements in the field of the HA/Carbon composites,in this review we present the state of the art of the field of HA composites and hybrids with classic carbon allotropes and nanocarbons.These composites are known for carbon nanotubes,nanofibers,graphene and its oxidized forms,as well as,in a lesser grade,for graphite,fullerenes,nanodiamonds,carbon nanofoams,etc.These composites can be fabricated by a variety of classic and less-common methods,such as co-precipitation(with or without ultrasonic treatment),CVD,hot isostatic pressing,hydrothermal,spark plasma sintering,biomimetic mineralization,thermal and plasma spray,electrochemical and electrophoretic deposition,self-assembling,3D printing,electrospinning,and lyophilisation,among others.Combination of various synthesis techniques can be also carried out for composite preparation.Natural or synthetic HA can be used as it is for further interaction with carbon allotropes or it can be first prepared and then reacted with carbon counterpart;similarly,carbon allotropes can be introduced into the interaction with HA directly or they can be first synthesized,in particular from biomass.Resulting biocompatible composites can be produced in the form of coatings,powders,and scaffolds and can additionally contain quantitative amounts of third phases,frequently natural or synthetic polymers.in these composites,especially with o-containing functionalizing groups,HA disadvantages could be considerably decreased with simultaneous enhancement of mechanical properties,becoming similar to human bone,chemical stability and biocompatibility,as well as possessing antibacterial effect.Go→G reduction and higher HA decoration were observed in several experiments.The morphology of p

关键词： Hydroxyapatite Carbon nanotubes Graphene Quantum dots Fullerenes Nanodiamonds

Efficacy of acupuncture on cancer pain:A systematic review and meta-analysis

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Journal of integrative medicine 2024年第3期22卷 235-244页

作者： miguel Faria mónica Teixeira maria João Pinto Paulo Sargento Núcleo de investigação em Ciências e Tecnologias da Saúde Instituto Politécnico da Lusofonia1950-396 LisboaPortugal Clínica São João de deus 1700-048 LisboaPortugal REQUimTE/LAQV(Rede de Química e Tecnologia/Laboratório Associado para a Química Verde) Instituto Superior de EngenhariaInstituto Politécnico do Porto4051-401 PortoPortugal Hospital SoERAD 2560-312 Torres VedrasPortugal Centro de Estudos Avançados em Direito“Francisco Suarez ”1749-024 LisboaPortugal

Background:Pain associated with cancer is one of the greatest causes of reduced quality of life in patients.Acupuncture is one of the treatments used to address this issue,with the great advantage of having little or no side effects,especially when compared with pharmacological pain-killers.objective:The aim of this systematic review and meta-analysis was to evaluate the current evidence regarding the efficacy of acupuncture for cancer pain.Search strategy:Six electronic databases(Pubmed,EBSCo,Cochrane Library,Scielo,b-on and Scopus)were searched for relevant articles about pain relief in cancer patients from their beginning until 2022using meSH terms such as“acupuncture,”“electroacupuncture,”“ear acupuncture,”“acupuncture analgesia,”“oncological pain,”and“cancer pain.”inclusion criteria:Studies included were randomized controlled trials(RCTs)where acupuncture was compared with no treatment,placebo acupuncture or usual care.Data extraction and analysis:Three independent reviewers participated in data extraction and evaluation of risk of bias,and a meta-analysis was conducted.The primary outcome was pain intensity,measured with the visual analog scale,numeric rating scale,or brief pain inventory.Secondary outcomes also assessed were quality of life,functionality,xerostomia,pain interference,and analgesic consumption.Results were expressed as standardized mean difference(SmD)with 95%confidence interval(Ci).Results:Sixteen RCTs with a total of 1124 participants were included in the meta-analysis,with the majority of the studies presenting a low or unclear risk of bias.Acupuncture was more effective in reducing pain than no treatment(SmD=–0.90,95%Ci[–1.68,–0.12]),sham acupuncture(SmD=–1.10,95%Ci[–1.59,–0.61])or usual care(SmD=–1.16,95%Ci[–1.38,–0.93]).Conclusion:The results of this study suggest that acupuncture may be an effective intervention to reduce pain associated with cancer.despite some limitations due to the low quality and small sample size of some included studies,as well as the different types and stages

关键词： Acupuncture Cancer pain meta-analysis Systematic review

Prompt neutron emission in 250No spontaneous fission associated with ground and isomeric state decays

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Chinese Physics C 2024年第6期48卷 112-117页

作者： R.S.mukhin A.V.isaev A.V.Andreev m.L.Chelnokov V.i.Chepigin H.m.devaraja i.N.izosimov A.A.Kuznetsova o.N.malyshev A.G.Popeko Yu.A.Popov A.Rahmatinejad B.Sailaubekov T.m.Shneidman E.A.Sokol A.i.Svirikhin m.S.Tezekbayeva m.A.Bychkov A.V.Yeremin o.Dorvaux B.Gall K.Kessaci K.Hauschild A.Lopez-martens Joint institute for Nuclear Research Dubna141980Russia Dubna State University Dubna141982Russia institute of Nuclear Physics Almaty050032Kazakhstan L.N.Gumilyov Eurasian National University Astana010008Kazakhstan Kazan Federal University Kazan420008Russia Universitéde Strasbourg CNRSStrasbourg67000France iJCLab IN2P3-CNRSUniversitéParis-SaclayOrsay91400France

The complete-fusion reaction^(204)Pb(^(48)Ca,2n)^(250)No was used to study two activities of^(250)No with distinct half-lives.A total of 1357 events were observed in the SFiNx neutron detection system.The average number of neutrons emitted per spontaneous fission of^(250)No was determined to be(4.1±0.1).The unusually symmetrical shape of the prompt neutron multiplicity distribution was restored and presented for the first time.Statistical tests were performed to compare the prompt neutron multiplicity distributions associated with the ground state and K-isomer state decays.

关键词： spontaneous fission prompt neutrons actinide

Solar-driven Co_(2) conversion to methane and methanol using different nanostructured Cu_(2)o-based catalysts modified with Au nanoparticles

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Journal of Energy Chemistry 2024年第4期91卷 287-298页

作者： João Angelo Lima Perini Lilian D.moura Torquato Juliana Fde Brito Gustavo A.Andolpho mateus A.Gonçalves Leonardo D.de Angelis Lucas D.Germano Susana i.Córdoba de Torresi Teodorico C.Ramalho maria V.Boldrin Zanoni São Paulo State University(UNESP) Institute of ChemistryRua Prof.Francisco Degni55AraraquaraSP 14800-060Brazil National institute of Alternative Technologies for detection Toxicological Evaluation and Removal of Micropollutants and Radioactive Substances(INCT-DATREM)São Paulo State University(UNESP)Institute of ChemistryRua Prof.Francisco Degni55AraraquaraSP 14800-060Brazil Laboratory of molecular modelling Department of ChemistryNatural Sciences InstituteFederal University of LavrasLavrasMG 37200-900Brazil department of Chemistry Faculty of ScienceUniversity of Hradec KrálovéHradec Králové50003Czech Republic instituto de Química Universidade de São PauloAv.Prof.Lineu Prestes 74805508-080São PauloSPBrazil

This work describes the use of Tio_(2)nanotubes-based electrodes(TNT)modified with Cu_(2)o nanostructures and gold nanoparticles for the photoelectroreduction of Co_(2)to produce value-added compounds.A thin layer of polydopamine was used as both an adherent agent and an electron transfer mediator,due to itsπ-conjugated electron system.The highest production yield was achieved using a TNT@PDA/Nc/Au40%electrode,with Faradaic efficiencies of 47.4%(110.5μm cm^(-2))and 27.8%(50.4μm cm^(-2))for methanol and methane,respectively.The performance of the photoelectrodes was shown to be Cu_(2)o facet-dependent,with cubic structures leading to greater conversion of Co_(2)to methanol(43%)and methane(27%),compared to the octahedral morphology,while a higher percentage of metallic gold on the nanostructured Cu_(2)o surface was mainly important for CH4production.density functional theory(DFT)calculations supported these findings,attributing the superior photoelectrocatalytic performance of the TNT@PDA/Nc/Au40%electrode for CH4generation to the formation of an oCH3intermediate bonded to Au atoms.Studies using isotope-labeling and analysis by gas chromatograph-mass(GC-mS)demonstrated that13Co_(2)was the source for photoelectrocatalytic generation of13CH3oH and13CH313CH2oH.

关键词： Cu_(2)o nanocubes Photoelectrocatalysis Polydopamine Co_(2) photoelectroreduction DFT calculations

A facile strategy for tuning the density of surface-grafted biomolecules for melt extrusion-based additive manufacturing applications

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Bio-design and manufacturing 2024年第3期7卷 277-291页

作者： i.A.o.Beeren G.Dos Santos P.J.Dijkstra C.mota J.Bauer H.Ferreira Rui L.Reis N.Neves S.Camarero-Espinosa m.B.Baker L.moroni department of Complex Tissue Regeneration MERLN Institute for Technology-Inspired Regenerative MedicineMaastricht University6229 ER MaastrichtThe Netherlands 3B’s Research Group I3Bs–Research Institute on BiomaterialsBiodegradables and BiomimeticsHeadquarters of the European Institute of Excellence on Tissue Engineering and Regenerative MedicineUniversity of MinhoAveParkZona Industrial da Gandra4805-017 BarcoGuimarãesPortugal iCVS/3B’s-PT Government Associate Laboratory 4806-909 Braga/GuimarãesPortugal PoLYmAT University of the Basque Country UPV/EHU20018 Donostia/San SebastiánSpain iKERBASQUE Basque Foundation for Science48009 BilbaoSpain

melt extrusion-based additive manufacturing(mE-Am)is a promising technique to fabricate porous scaffolds for tissue engi-neering applications.However,most synthetic semicrystalline polymers do not possess the intrinsic biological activity required to control cell fate.Grafting of biomolecules on polymeric surfaces of Am scaffolds enhances the bioactivity of a construct;however,there are limited strategies available to control the surface density.Here,we report a strategy to tune the surface density of bioactive groups by blending a low molecular weight poly(ε-caprolactone)5k(PCL5k)containing orthogonally reactive azide groups with an unfunctionalized high molecular weight PCL75k at different ratios.Stable porous three-dimensional(3D)scaf-folds were then fabricated using a high weight percentage(75 wt.%)of the low molecular weight PCL 5k.As a proof-of-concept test,we prepared films of three different mass ratios of low and high molecular weight polymers with a thermopress and reacted with an alkynated fluorescent model compound on the surface,yielding a density of 201-561 pmol/cm^(2).Subsequently,a bone morphogenetic protein 2(BmP-2)-derived peptide was grafted onto the films comprising different blend compositions,and the effect of peptide surface density on the osteogenic differentiation of human mesenchymal stromal cells(hmSCs)was assessed.After two weeks of culturing in a basic medium,cells expressed higher levels of BmP receptor ii(BmPRii)on films with the conjugated peptide.in addition,we found that alkaline phosphatase activity was only significantly enhanced on films contain-ing the highest peptide density(i.e.,561 pmol/cm^(2)),indicating the importance of the surface density.Taken together,these results emphasize that the density of surface peptides on cell differentiation must be considered at the cell-material interface.moreover,we have presented a viable strategy for mE-Am community that desires to tune the bulk and surface functionality via blending of(modified)polymers.Furthermore,the use of alkyne-a

关键词： Additive manufacturing Blending Surface functionalization Surface density Click chemistry Human

Associations between physical activity levels and ATPase inhibitory factor 1 concentrations in older adults

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Journal of Sport and Health Science 2024年第3期13卷 409-418页

作者： Jérémy Raffin Yves Rolland Annelise Genoux Guillaume Combes mikael Croyal Bertrand Perret Sophie Guyonnet Bruno Vellas Laurent o.martinez Philipe de Souto Barreto For the mAPT/DSA Group institut du Vieillissement Gérontopôle de ToulouseCentre Hospitalo-Universitaire de ToulouseToulouse 31000France Centre d'Epidémiologie et de Recherche en Santédes Populations UnitéMixte de Recherche 1295Institut National de la Santéet de la Recherche MédicaleUniversitéToulouse-III-Paul-SabatierToulouse 31000France LimitAging Team Institut des Maladies Métaboliques et CardiovasculairesUnitéMixte de Recherche 1297Institut National de la Santéet de la Recherche MédicaleUniversitéToulouse III-Paul SabatierToulouse 31432France Service de Biochimie Pôle de biologieHôpital de PurpanCentre Hospitalo-Universitaire de ToulouseToulouse 31300France L'institut du Thorax Institut National de la Santéet de la Recherche MédicaleCentre National de la Recherche ScientifiqueCentre Hospitalo-Universitaire de NantesNantes UniversitéNantes 44000France BioCore US16Structure Fédérative de Recherche BonamyInstitut National de la Santéet de la Recherche MédicaleCentre National de la Recherche ScientifiqueCentre Hospitalo-Universitaire de NantesNantes UniversitéNantes 44000France Plate-forme de spectrométrie de masse Centre de Recherche en Nutrition HumaineOuestNantes 44000France 不详

Background:Adenosine triphosphatase inhibitory factor 1(iF1)is a key protein involved in energy metabolism.iF1 has been linked to various agerelated diseases,although its relationship with physical activity(PA)remains unclear.Additionally,the apolipoprotein A-i(apoA-i),a PA-modulated lipoprotein,could play a role in this relationship because it shares a binding site with iF1 on the cell-surface ATP synthase.We examined here the associations between chronic PA and plasma iF1 concentrations among older adults,and we investigated whether apoA-i mediated these associations.methods:in the present work,1096 healthy adults(63.8%females)aged 70 years and over who were involved in the multidomain Alzheimer Prevention Trial study were included.iF1 plasma concentrations(square root of ng/mL)were measured at the 1-year visit of the multidomain Alzheimer Prevention Trial,while PA levels(square root of metabolic equivalent task min/week)were assessed using questionnaires administered each year from baseline to the 3-year visit.multiple linear regressions were performed to investigate the associations between the first-year mean PA levels and iF1 concentrations.mediation analyses were conducted to examine whether apoA-i mediated these associations.mixedeffect linear regressions were carried out to investigate whether the 1-year visit iF1 concentrations predicted subsequent changes in PA.Results:multiple linear regressions indicated that first-year mean PA levels were positively associated with iF1 concentrations(B=0.021;SE=0.010;p=0.043).mediation analyses revealed that about 37.7%of this relationship was mediated by apoA-i(B_(ab)=0.008;SE=0.004;p=0.023).Longitudinal investigations demonstrated that higher concentrations of iF1 at the 1-year visit predicted a faster decline in PA levels over the subsequent 2 years(time×iF1:B=0.148;SE=0.066;p=0.025).Conclusion:This study demonstrates that regular PA is associated with plasma iF1 concentrations,and it suggests that apoA-i partly mediates this association.Additionally,this study f

关键词： Aging Apolipoprotein Bioenergetics Exerkine mitochondria