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The role of aerial algae in the formation of the landscape of the Yunnan Stone Forest,Yunnan Province, china

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Science china earth sciences 2004年第9期47卷 846-864页

作者： TIAN Youping1,3. ZHANG Jie2, SONG Linhua1 & BAO Haosheng2 1. Institute of Geographic sciences and Natural resources Research, Chinese Academy of sciences, Beijing 100101,{3. 2. Department of Geography, Nanjing university, Nanjing 210093.{3. 3. school of earth sciences and resources, china university of geosciences, Beijing 100083.{3. Institute of Geographic sciences and Natural resources Research Chinese Academy of Sciences Beijing China school of earth sciences and {3. China University of Geosciences Beijing China Department of Geography Nanjing University Nanjing China

Aerial algae on the surface of carbonate rocks at the Stone Forest, Shilin County, Yunnan Province, china, and their bioerosion were investigated in the field and studied in the laboratory in detail. Through the observation, identification and statistics of more than one hun- dred algal samples and rock samples with the optical microscopes (stereomicroscope, biological microscope) and the scanning electronic microscope (SEM), the relationships between erosional forms on the surface of the Stone Forest and algae and/or algal communities and the genetic mechanism for the formation of erosional forms were analyzed. It is suggested that aerial algae play an active role in bioerosive processes that may affect the formation of karst erosional forms. These effects include both direct and indirect ones. The direct effect is the initiative control (algal shape-controlling role) of algae on the formation of karst forms of various scales, mostly mi- cro-scale (3.) and minor-scale (10-3.10-1m) erosional forms. The algal shape-controlling roles can be divided into the algal individual shape-controlling role and the algal community shape-controlling role. The former mostly controls the formation of micro-scale erosional forms, while the latter mostly controls the formation of micro-scale and smaller minor-scale erosional forms. The indirect effect refers to the promoting role of algae in the formation of karst forms, which may affect the formation of karst forms of all types and scales. The bioerosion of algae accelerates the weathering process of the whole Stone Forest karst landforms.

关键词： aerial algae, bioerosion, the Stone Forest, Yunnan Province, china.

Indian Ocean-MORB-type isotopic signature of Yushigou ophiolite in North Qilian Mountains and its implications

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Science china earth sciences 2006年第6期49卷 561-572页

作者： HOU Qingye1,2, ZHAO Zhidan1,2, ZHANG Hongfei3. ZHANG Benren3.& CHEN Yuelong2 1. State Key Laboratory of Geological Processes and Mineral resources, china university of geosciences, Beijing 100083. china 2. {3. of earth Science and Mineral resources, china university of geosciences, Beijing 100083. china 3. Faculty of earth sciences, china university of geosciences, Wuhan 43.074, china State Key Laboratory of Geological Processes and Mineral resources China University of Geosciences Beijing China school of earth Science and Mineral resources China University of Geosciences Beijing China Faculty of earth sciences China University of Geosciences Wuhan China

In order to explore the disputed issue concerning the tectonic affinity ofthe ancient ocean mantle of North Qilian Mountains (NQM), geochemical and Sr, Nd, Pb isotopiccompositions of pillow basalts of the Yushigou Ophiolite (YSGO) suite from NQM have been analyzedsystematically. The pillow basalts exhibit tholeiitic characteristics, with flatchondrite-normalized REE patterns ((La/Yb)_N = 0.98—1.27). They display no Nb, Ta, Zr, Hf negativeanomalies, and show MORB features in 2Nb-Zr/4-Y and Ti/100-Zr-YX3.tectonic discrimination *** results indicate that the Yushigou ophiolite is most likely to be formed in a mid-ocean ridgeor mature back-arc basin. Their isotopic data show a relatively broad and enriched ^(87)Sr/^(86)Sr(0.70509 — 0.70700), restricted ^(143.Nd/^(144)Nd (0.512.55-0.512.78). Pb isotopes are in the rangeof ^(206)Pb/^(204)Pb (18.054-20.562), ^(207)Pb/^(204)Pb (15.53.-15.743. and ^(208)Pb/^(204)Pb(3..068-3..53.). These isotopic data imply that the basalts originated from the depleted mantle(DMM), with the involvement of enriched mantle components (mainly EMII). Geochemical comparisonsbetween the basalts in YSGO and the MORB-type basalts of ophiolite suites occurring in the knownancient Tethyan tectonic domain indicate that the ancient oceanic mantle represented by YSGO suiteforming in early Paleozoic in the North Qilian Moutains is very similar to the Tethyan mantle inboth trace elements and isotopic compositions. The North Qilian Mountains should be a part of theTethyan tectonic domain in early Paleozoic. This further implies that the Tethyan tectonic domaincan be deduced to early Paleozoic in the study area, which will be helpful to discussing thetectonic affinity and evolution of the North Qilian Mountains.

关键词： geochemistry, Indian Ocean-MORB-type isotopic signatures, Tethyan tectonic domain, Yushigou ophiolite, North Qilian Mountains.

Some basic concepts and problems on the petrogenesis of intra-plate ocean island basalts

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Chinese Science Bulletin 2009年第22期54卷 4148-4160页

作者： NIU Yaoling1,2,3.1 Department of earth sciences, Durham university, Durham DH1 3.E, UK 2 {3. of earth sciences and resources, china university of geosciences, Beijing 100083. china 3.{3. of earth and Space sciences, Peking university, Beijing 100871, china Department of earth sciences Durham University Durham DH1 3LE UK school of earth sciences and {3. China University of Geosciences Beijing 100083 China school of earth and Space sciences Peking University Beijing 100871 China

Basaltic magmatism that builds intra-plate ocean islands is often considered to be genetically associated with "hotspots" or "mantle plumes". While there have been many discussions on why ocean island basalts (OIB) are geochemically highly enriched as an integral part of the mantle plume hypothesis, our current understanding on the origin of OIB source material remains unsatisfactory, and some prevailing ideas need revision. One of the most popular views states that OIB source material is recycled oceanic crust (ROC). Among many problems with the ROC model, the ocean crust is simply too depleted (e.g., [La/Sm]PM > 1) OIB. Another popular view states that the enriched component of OIB comes from recycled continental crust (RCC, i.e.; terrigenous sediments). While both CC and OIB are enriched in many incompatible elements (e.g., both have [La/Sm]PM >>1), the CC has characteristic enrichment in Pb and deletion in Nb, Ta, P and Ti. Such signature is too strong to be eliminated such that CC is unsuitable as source material for OIB. Plate tectonics and mantle circulation permit the presence of ROC and RCC materials in mantle source regions of basalts, but they must be volumetrically insignificant in contributing to basalt magmatism. The observation that OIB are not only enriched in incompatible elements, but also enriched in the progressively more incompatible elements indicates that the enriched component of OIB is of magmatic origin and most likely associated with low-degree melt metasomatism. H2O and CO2 rich incipient melt may form in the seismic low velocity zone (LVZ). This melt will rise because of buoyancy and concentrate into a melt rich layer atop the LVZ to metasomatize the growing lithosphere, forming the metasomatic vein lithologies. Erupted OIB melts may have three components: (1) fertile OIB source material from depth that is dominant, (2) the melt layer, and (3. assimilation of the metasomatic

关键词：岩石成因论海洋 OIB 矿物学

Exsolution of ilmenite and Cr-Ti magnetite from olivine of garnet-wehrlite

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Science china earth sciences 2005年第9期48卷 1368-1376页

作者： LIU Xiangwen1,2, JIN Zhenmin1,3. QU Jing2 & WANG Lu2 1. State Key Laboratory of Geological Processes and Mineral resources, china university of geosciences, Wuhan 43.074, china 2. Graduate {3. of china university of geosciences, Wuhan 43.074, china 3. Faculty of earth sciences, china university of geosciences, Wuhan 43.074, china State Key Laboratory of Geological Processes and Mineral resources China University of Geosciences Wuhan China Graduate school of china university of geosciences Wuhan China Faculty of earth sciences China University of Geosciences Wuhan China

Exsolution of rod-like ilmenite (Ilm) and Cr-Ti magnetite (Mt) have been found in olivine of garnet-wehrlite from the core of Chinese Continental sciences Drilling (CCSD). Their composition, morphology, crystal structure and their topotaxies with host olivine have been studied in detail by the transmission electron microscopy (TEM) and electron probe microanaly- sis (EPMA) technique. It shows that rod-like Ilm exsolution reported in this paper has similar characteristic with that of Alpe Arami olivine, while Cr-Ti magnetite exsolution mentioned in this paper has large discrepancy with chromite exsolution in Alpe Arami olivine. These observations suggest that both of the exsolutions found in this paper should be solid solution phases in β-olivine at their first period, then experiencing decomposition of solid solution and therefore forming Ilm and Cr-Ti magnetite exsolution with the pressure decreasing. So, this garnet-wehrlite perhaps had been ever located in mantle transition zone with a minimum depth of 3.0 km.

关键词： garnet-wehrlite, ilmenite, magnetite, exsolution, CCSD.

Experimental remolding on the caprock's 3. strain field of the Indosinian-Yanshanian epoch in Tongling deposit concentrating area

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Science china earth sciences 2005年第7期48卷 863-874页

作者： DENG Jun1,HUANG Dinghua2,WANG Qingfei1,WAN Li1,SUN Zhongshi3.YANG Liqiang1 & GAO Bangfei1 1. State Key Laboratory of Geological Processes and Mineral resources,china university of {3.,Beijing 100083.china 2. Faculty of earth sciences,china university of {3.,Wuhan 43.074,china 3. Department of earth sciences,Jilin university,Changchun 13.061,china State Key Laboratory of Geological Processes and Mineral resources China University of Geosciences Beijing 100083 China Faculty of earth sciences China University of Geosciences Wuhan 430074 China Department of earth sciences Jilin University Changchun 130061 China

Based on field observations and rheology analysis, we perform one analogue experiment and remold the 3. structural frame of Tongling deposit concentrating area firstly. Then we disassemble and dialyze the 3. structures of the model using the methods of "slicing" and "stripping". A series of sliced planes vertical to the fold hinges show similar landscapes of that in the drill hole profiles. Meanwhile, layer stripping analysis indicates that the deformation features of each layer in the model are qualitatively analogical to those obtained from field observations. Through contrasting the 3. structure between the experimental model and the field phenomena, we verify the following 3. deformation features of the caprock in this area: (1) the Tongling area mainly consists of three series of NE S-typed fold groups; (2) in the uniform stress field, the incoherent folds universally develop in different positions, along different axes as well as in different strata; (3. the faults propagate upward which are mostly inter-bedded detachment faults, while the fold amplitudes decrease while going deeper; and (4) the folds and cleavages are highly developed in the Silurian System indicating that the deformation effect of the Indosin-ian-Yanshanian structural layer terminates at this layer, which suggests that the Silurian System is the crucial layer for the inversion between brittle and plastic deformation domains and the underlying strata are subject to the control of another deformation system with distinct properties.

关键词： Tongling deposit concentrating area Indosinian-Yanshanian epoch 3. structural frame of the caprock analogue experiment slicing and stripping analysis structural model.

Petrogenesis and dating of the Kangding complex,Sichuan Province

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Science china earth sciences 2005年第5期48卷 622-634页

作者： CHEN Yuelong 1 , LUO Zhaohua 1 , ZHAO Junxiang, LI Zhihong, ZHANG Hongfei & SONG Biao 3.1. Faculty of earth sciences and Natural resources,{3., Beijing 100083. china 2. Faculty of earth sciences,{3., Wuhan 43.074, china 3. Beijing SHRIMP Center, Institute of Geology, Chinese Academy of Geological sciences, Beijing 10003., china Faculty of earth sciences and Natural resources China University of Geosciences Beijing China Faculty of earth sciences China University of Geosciences Wuhan China Beijing SHRIMP Center Institute of Geology Chinese Academy of Geological Sciences Beijing China

An analysis of major and trace element geochemistry and SHRIMP U-Pb zircon dating of mafic, intermediate, and felsic rocks from the Mianning metamorphic complex of Si- chuan Province was conducted. One of our conclusions is that a majority of the zircons crystal- lized between 721 and 773.Ma in a magmatic regime. The complexes contain early to late Pa- leo-proterozoic relict zircons from ancient continental crust. The oldest age, 2468 Ma, may rep- resent the basement of the Yangtze block. Overgrowth zircon rims and palingenetic zircons have been observed and dated, and are believed to have formed after crystallization, during Paleozoic and Mesozoic metamorphic-anatexis. We also conclude that depletion of Nb, Ta, HREE, in a spider-diagram normalized to primitive mantle and calc-alkaline association, implies that they formed in island-arc or under-plating settings.

关键词： Kangding complex, zircons, SHRIMP, tectonic setting.

Comparative study on CO_2 corrosion behavior of N80,P110,X52 and 13.r pipe lines in simulated stratum water

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Science china(Technological sciences) 2010年第9期53卷 2342-2349页

作者： CAI YiDong1,GUO PengChao1,LIU DaMeng1,CHEN ShiYu2 & LIU JunLai3.1 school of Energy resources,china {3. of geosciences,Beijing 100083.china 2 school of Materials Science and Engineering,{3. of Science and Technology Beijing,Beijing 100083.china 3.school of earth sciences and resources,china {3. of geosciences,Beijing 100083.china school of Energy resources China University of Geosciences

To better understand the carbon dioxide (CO2) corrosion behavior of carbon steel and its influence on petroleum development (including drilling,production and transportation) in the Daqing Oilfield,CO2 corrosion behaviors of N80,P110,X52 and 13.r pipe lines in simulated solution at high temperature and high pressure condition are investigated by dynamic corrosion experiments,scanning electron microscope (SEM) and energy dispersive X-ray spectroscopy (EDS) *** show that the corrosion rate of all pipe lines increases quickly when CO2 partial pressure increases from 0.5 to 1.5 MPa,but it slows down when CO2 partial pressure further increases from 1.5 to 4.5 MPa,during which localized corrosion is *** the experimental temperature ranges from 60 to 12.°C,localized corrosion *** corrosion rate of all pipe lines decreases sharply when the temperature changes from 60 to 100°C,and it becomes stable after the temperature is higher than 100°*** the flow rate is in the range of 0–1.5 m/s,the corrosion rate of sample X52 remains unchanged,but localized corrosion gradually becomes very serious when the flow rate further *** analyzing the corrosion product scales of sample 13.r,some remarkable phenomena are *** the temperature range of 60–100°C,the corrosion product scales are loose and thick,but become very compact when the temperature increases above 100°*** the later case,localized corrosion is *** main components of the corrosion product scales are FeCO3.and Cr2O3.

关键词： CO2 corrosion pipe lines weight loss SEM EDS

Geochemical characteristics and tectonic implications of HP-UHP eclogites and blueschists in southwestern Tianshan, china

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Progress in Natural Science:Materials International 2006年第6期16卷 624-632页

作者： AI Yongliang, ZHANG Lifei, LI Xuping and QU Junfeng (MOE Key Laboratory of Orogenic Belt and Crust Evolution, school of earth and Space sciences, Peking {3., Beijing 100871, china school of geosciences and resources, china university of geosciences, Beijing 100083. china) MOE Key Laboratory of Orogenic Belt and Crust Evolution School of Earth and Space Sciences Peking University Beijing 100871 China school of geosciences and resources China University of Geosciences Beijing 100083 China

Four rock assemblages in correspondence with two different tectonic settings have been recognized in the NEE-SWW extending HP-UHP metamorphic belt in southwestern Tianshan, northwest china. Eclogite assemblage EC1 is geochemically akin to alkaline within-plate oceanic island basalt (OIB). EC2 shows affinity to enriched mid-oceanic ridge basalt (EMORB). Rare earth element (REE) and other immobile trace element characteristics of blueschist assemblage BS1 resemble those of normal mid-oceanic ridge basalt (NMORB). These three assemblages are likely formed on a seamount setting, and the prevalent presence of carbonate minerals and om-phacite quartzite stripes/gobbets suggests ancient pelagic sediments including marls are probably developed upon the basaltic seamount. Whereas the geochemical characteristics of BS2 assemblage are of volcanic arc basalt-type. The seamount with the pelagic sediments on it is brought into the subduction zone, and volcanic arc basalts formed on the active continental margin and trench sediments are eroded and enwrapped in the subducting mass, they are altogether subjected to high to ultrahigh pressure metamorphism and subsequent exhumation towards surface. The HP-UHP metamorphic belt is thus interpreted as a subduct ion-accretionary complex formed by tectonic juxtaposition and imbrication of seamount, seafloor, trench and volcanic arc sequences during oceanic crust subduction.

关键词： southwestern Tianshan HP-UHP metamorphic belt snbduction-accretion complex trace element geochemistry.

Sm-Nd and zircon SHRIMP U-Pb dating of Huilanshan mafic granulite in the Dabie Mountains and its zircon trace element geochemistry

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Science china earth sciences 2005年第12期48卷 2081-2091页

作者： HOU Zhenhui1, LI Shuguang1, CHEN Nengsong2, LI Qiuli1 & LIU Xiaoming3.1. school of earth and Space sciences, {3. of Science and Technology of china, Hefei 23.026, china 2. The Key Laboratory of Continental Dynamics of the Ministry of Education, Northwest {3., Xi’an 710069, china 3. Faculty of earth sciences, china university of geosciences, Wuhan 43.074, china school of earth and Space sciences University of Science and Technology of China Hefei China The Key Laboratory of Continental Dynamics of the Ministry of Education Northwest University Xi’an China Faculty of earth sciences China University of Geosciences Wuhan China

The mafic granulites from Huilanshan are outcropped on the center of the Luotian dome in the northern Dabie Mountains. The Sm-Nd isochron defined by granulite-facies meta-morphic minerals (garnet + clinopyroxene + hypersthene) yields an age of 13. ± 18 Ma indicating the early Cretaceous granulite-facies metamorphism. The cathodoluminescence (CL) images of zircons from the granulite show clearly core-mantle-rim structures. The zircon cores are charac-terized by typical oscillatory zoning and highly HREE enriched patterns, which suggests their magma origin. Some zircon cores among them with little Pb loss give SHRIMP U-Pb ages rang-ing from 753.to 780 Ma, which suggests that the protolith of Huilanshan granulite is Neopro-terozoic mafic rocks. The zircon mantles usually cut across the oscillatory zone of the zircon cores have 3.10 times lower REE, Th, U, Y, Nb and Ta contents than the igneous zircon cores but have high common Pb contents. These characteristics suggest that they were formed by hydrothermal alteration of the igneous zircons. The part of zircon mantles with little Pb loss give a similar SHRIMP U-Pb age (716―780 Ma) to the igneous zircon cores, which implies that the hydrothermal events occurred closely to the magmatic emplacement. In view of the strong early Cretaceous magmatism in the Luotian dome, consequently, the Huilanshan mafic granulite was formed by heating of the Neoproterozoic mafic rocks in mid-low crust, which caused the granu-lite-facies metamorphism underneath the Dabie Mountains. The similarity between the granulite metamorphic age (13. ± 18 Ma) defined by Sm-Nd isochron and K-Ar age of 12.―12. Ma given by amphible from the gneiss in Luotian dome suggests a rapid uplifting of the Luotian dome, which may result in further exhumation of the ultrahigh pressure metamorphic rocks in the Dabie Mountains.

关键词： Dabie orogen, granulite, zircon U-Pb ages, Sm-Nd age.