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Comparative study on CO_2 corrosion behavior of N80,P110,X52 and 13Cr pipe lines in simulated stratum water

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Science china(Technological sciences) 2010年第9期53卷 2342-2349页

作者： CAI YiDong1,GUO PengChao1,LIU DaMeng1,CHEN ShiYu2 & LIU JunLai3 1 school of Energy resources,china university of geosciences,beijing 100083.china 2 school of Materials Science and Engineering,university of Science and Technology beijing,beijing 100083.china 3 school of earth sciences and resources,china university of geosciences,beijing 100083.china school of Energy resources China University of Geosciences Beijing China school of Materials Science and Engineering University of Science and Technology Beijing Beijing China school of earth sciences and resources China University of Geosciences Beijing China

To better understand the carbon dioxide (CO2) corrosion behavior of carbon steel and its influence on petroleum development (including drilling,production and transportation) in the Daqing Oilfield,CO2 corrosion behaviors of N80,P110,X52 and 13Cr pipe lines in simulated solution at high temperature and high pressure condition are investigated by dynamic corrosion experiments,scanning electron microscope (SEM) and energy dispersive X-ray spectroscopy (EDS) *** show that the corrosion rate of all pipe lines increases quickly when CO2 partial pressure increases from 0.5 to 1.5 MPa,but it slows down when CO2 partial pressure further increases from 1.5 to 4.5 MPa,during which localized corrosion is *** the experimental temperature ranges from 60 to 120°C,localized corrosion *** corrosion rate of all pipe lines decreases sharply when the temperature changes from 60 to 100°C,and it becomes stable after the temperature is higher than 100°*** the flow rate is in the range of 0–1.5 m/s,the corrosion rate of sample X52 remains unchanged,but localized corrosion gradually becomes very serious when the flow rate further *** analyzing the corrosion product scales of sample 13Cr,some remarkable phenomena are *** the temperature range of 60–100°C,the corrosion product scales are loose and thick,but become very compact when the temperature increases above 100°*** the later case,localized corrosion is *** main components of the corrosion product scales are FeCO3 and Cr2O3.

关键词： CO2 corrosion pipe lines weight loss SEM EDS

The role of aerial algae in the formation of the landscape of the Yunnan Stone Forest,Yunnan Province, china

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Science china earth sciences 2004年第9期47卷 846-864页

作者： TIAN Youping1,3, ZHANG Jie2, SONG Linhua1 & BAO Haosheng2 1. Institute of Geographic sciences and Natural resources Research, Chinese Academy of sciences, beijing 100101, china 2. Department of Geography, Nanjing university, Nanjing 210093, china 3. school of earth sciences and resources, china university of geosciences, beijing 100083, china Institute of Geographic sciences and Natural resources Research Chinese Academy of Sciences Beijing China school of earth sciences and resources China University of Geosciences Beijing China Department of Geography Nanjing University Nanjing China

Aerial algae on the surface of carbonate rocks at the Stone Forest, Shilin County, Yunnan Province, china, and their bioerosion were investigated in the field and studied in the laboratory in detail. Through the observation, identification and statistics of more than one hun- dred algal samples and rock samples with the optical microscopes (stereomicroscope, biological microscope) and the scanning electronic microscope (SEM), the relationships between erosional forms on the surface of the Stone Forest and algae and/or algal communities and the genetic mechanism for the formation of erosional forms were analyzed. It is suggested that aerial algae play an active role in bioerosive processes that may affect the formation of karst erosional forms. These effects include both direct and indirect ones. The direct effect is the initiative control (algal shape-controlling role) of algae on the formation of karst forms of various scales, mostly mi- cro-scale (3m) and minor-scale (10-3-10-1m) erosional forms. The algal shape-controlling roles can be divided into the algal individual shape-controlling role and the algal community shape-controlling role. The former mostly controls the formation of micro-scale erosional forms, while the latter mostly controls the formation of micro-scale and smaller minor-scale erosional forms. The indirect effect refers to the promoting role of algae in the formation of karst forms, which may affect the formation of karst forms of all types and scales. The bioerosion of algae accelerates the weathering process of the whole Stone Forest karst landforms.

关键词： aerial algae, bioerosion, the Stone Forest, Yunnan Province, china.

Some basic concepts and problems on the petrogenesis of intra-plate ocean island basalts

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Chinese Science Bulletin 2009年第22期54卷 4148-4160页

作者： NIU Yaoling1,2,3 1 Department of earth sciences, Durham university, Durham DH1 3LE, UK 2 school of earth sciences and resources, china university of geosciences, beijing 100083, china 3 school of earth and Space sciences, Peking university, beijing 100871, china Department of earth sciences Durham University Durham UK school of earth sciences and resources China University of Geosciences Beijing China school of earth and Space sciences Peking University Beijing China

Basaltic magmatism that builds intra-plate ocean islands is often considered to be genetically associated with "hotspots" or "mantle plumes". While there have been many discussions on why ocean island basalts (OIB) are geochemically highly enriched as an integral part of the mantle plume hypothesis, our current understanding on the origin of OIB source material remains unsatisfactory, and some prevailing ideas need revision. One of the most popular views states that OIB source material is recycled oceanic crust (ROC). Among many problems with the ROC model, the ocean crust is simply too depleted (e.g., [La/Sm]PM > 1) OIB. Another popular view states that the enriched component of OIB comes from recycled continental crust (RCC, i.e.; terrigenous sediments). While both CC and OIB are enriched in many incompatible elements (e.g., both have [La/Sm]PM >>1), the CC has characteristic enrichment in Pb and deletion in Nb, Ta, P and Ti. Such signature is too strong to be eliminated such that CC is unsuitable as source material for OIB. Plate tectonics and mantle circulation permit the presence of ROC and RCC materials in mantle source regions of basalts, but they must be volumetrically insignificant in contributing to basalt magmatism. The observation that OIB are not only enriched in incompatible elements, but also enriched in the progressively more incompatible elements indicates that the enriched component of OIB is of magmatic origin and most likely associated with low-degree melt metasomatism. H2O and CO2 rich incipient melt may form in the seismic low velocity zone (LVZ). This melt will rise because of buoyancy and concentrate into a melt rich layer atop the LVZ to metasomatize the growing lithosphere, forming the metasomatic vein lithologies. Erupted OIB melts may have three components: (1) fertile OIB source material from depth that is dominant, (2) the melt layer, and (3) assimilation of the metasomatic

关键词：岩石成因论海洋 OIB 矿物学

Geochemical characteristics and tectonic implications of HP-UHP eclogites and blueschists in southwestern Tianshan, china

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Progress in Natural Science:Materials International 2006年第6期16卷 624-632页

作者： AI Yongliang, ZHANG Lifei, LI Xuping and QU Junfeng (MOE Key Laboratory of Orogenic Belt and Crust Evolution, school of earth and Space sciences, Peking university, beijing 100871, china school of geosciences and resources, china university of geosciences, beijing 100083, china) MOE Key Laboratory of Orogenic Belt and Crust Evolution School of Earth and Space Sciences Peking University Beijing 100871 China school of geosciences and resources China University of Geosciences Beijing 100083 China

Four rock assemblages in correspondence with two different tectonic settings have been recognized in the NEE-SWW extending HP-UHP metamorphic belt in southwestern Tianshan, northwest china. Eclogite assemblage EC1 is geochemically akin to alkaline within-plate oceanic island basalt (OIB). EC2 shows affinity to enriched mid-oceanic ridge basalt (EMORB). Rare earth element (REE) and other immobile trace element characteristics of blueschist assemblage BS1 resemble those of normal mid-oceanic ridge basalt (NMORB). These three assemblages are likely formed on a seamount setting, and the prevalent presence of carbonate minerals and om-phacite quartzite stripes/gobbets suggests ancient pelagic sediments including marls are probably developed upon the basaltic seamount. Whereas the geochemical characteristics of BS2 assemblage are of volcanic arc basalt-type. The seamount with the pelagic sediments on it is brought into the subduction zone, and volcanic arc basalts formed on the active continental margin and trench sediments are eroded and enwrapped in the subducting mass, they are altogether subjected to high to ultrahigh pressure metamorphism and subsequent exhumation towards surface. The HP-UHP metamorphic belt is thus interpreted as a subduct ion-accretionary complex formed by tectonic juxtaposition and imbrication of seamount, seafloor, trench and volcanic arc sequences during oceanic crust subduction.

关键词： southwestern Tianshan HP-UHP metamorphic belt snbduction-accretion complex trace element geochemistry.

Indian Ocean-MORB-type isotopic signature of Yushigou ophiolite in North Qilian Mountains and its implications

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Science china earth sciences 2006年第6期49卷 561-572页

作者： HOU Qingye1,2, ZHAO Zhidan1,2, ZHANG Hongfei3, ZHANG Benren3 & CHEN Yuelong2 1. State Key Laboratory of Geological Processes and Mineral resources, china university of geosciences, beijing 100083, china 2. school of earth Science and Mineral resources, china university of geosciences, beijing 100083, china 3. Faculty of earth sciences, china university of geosciences, Wuhan 430074, china State Key Laboratory of Geological Processes and Mineral resources China University of Geosciences Beijing China school of earth Science and Mineral resources China University of Geosciences Beijing China Faculty of earth sciences China University of Geosciences Wuhan China

In order to explore the disputed issue concerning the tectonic affinity ofthe ancient ocean mantle of North Qilian Mountains (NQM), geochemical and Sr, Nd, Pb isotopiccompositions of pillow basalts of the Yushigou Ophiolite (YSGO) suite from NQM have been analyzedsystematically. The pillow basalts exhibit tholeiitic characteristics, with flatchondrite-normalized REE patterns ((La/Yb)_N = 0.98—1.27). They display no Nb, Ta, Zr, Hf negativeanomalies, and show MORB features in 2Nb-Zr/4-Y and Ti/100-Zr-YX3 tectonic discrimination *** results indicate that the Yushigou ophiolite is most likely to be formed in a mid-ocean ridgeor mature back-arc basin. Their isotopic data show a relatively broad and enriched ^(87)Sr/^(86)Sr(0.70509 — 0.70700), restricted ^(143)Nd/^(144)Nd (0.512955-0.512978). Pb isotopes are in the rangeof ^(206)Pb/^(204)Pb (18.054-20.562), ^(207)Pb/^(204)Pb (15.537-15.743) and ^(208)Pb/^(204)Pb(38.068-38.530). These isotopic data imply that the basalts originated from the depleted mantle(DMM), with the involvement of enriched mantle components (mainly EMII). Geochemical comparisonsbetween the basalts in YSGO and the MORB-type basalts of ophiolite suites occurring in the knownancient Tethyan tectonic domain indicate that the ancient oceanic mantle represented by YSGO suiteforming in early Paleozoic in the North Qilian Moutains is very similar to the Tethyan mantle inboth trace elements and isotopic compositions. The North Qilian Mountains should be a part of theTethyan tectonic domain in early Paleozoic. This further implies that the Tethyan tectonic domaincan be deduced to early Paleozoic in the study area, which will be helpful to discussing thetectonic affinity and evolution of the North Qilian Mountains.

关键词： geochemistry, Indian Ocean-MORB-type isotopic signatures, Tethyan tectonic domain, Yushigou ophiolite, North Qilian Mountains.

The Status of Organochlorine Pesticides Pollution in Hubei Section of the Yangtze River

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地学前缘 2009年第S1期16卷 81-82页

作者： Chen Liu,Liyuan Guo school of the earth sciences and resources,china university of geosciences(beijing),beijing 100083.china.

The Organochlorine Pesticides(OCPs),such as hexachlorocyclohexane(HCH)and dichlorodiphenyltrichloro ethane(DDT),are well known as typical persistent organic pollutions(POPs).They were worldwide used several decades ago,even today in some *** the water resource is very important in natural environments and essential to agriculture,the pollution of OCPs in water has emerged as worldwide environmental problem. Wuhan section of the Yangtze River is the drinking water source of Wuhan area in Hubei *** addition,Hubei province is an important production base of grain,cotton,oil and *** the rapid development of industry and mass-use of OCPs

关键词： organochlorine pesticides Yangtze River water residues

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Science china earth sciences 2004年第10期47卷 896-911页

作者： ZHANG Changhou1,2, WU Ganguo1,2, WANG Genhou2, ZHANG Weijie2 & SONG Honglin2 1. Key Laboratory of Lithospheric Tectonics and Lithoprobing Technology, china university of geosciences, Ministry of Education of china, beijing 100083, china 2. school of earth sciences and Mineral resources, china university of geosciences, beijing 100083, china Key Laboratory of Lithospheric Tectonics and Lithoprobing Technology China University of Geosciences Ministry of Education of China Beijing China school of earth sciences and Mineral resources China University of Geosciences Beijing China

The northwest trending tectonic belt in the middle part of the Mesozoic intraplate Yanshan Orogenic Belt, northeast Hebei Province, is composed of thrusts, extensional faults, strike-slip faults and syntectonic sedimentations as well. The northeastward basement-involved major thrusting deformation occurred between 174Ma and 168MaBP and was followed by an intrusion of the granitic plutonic rocks. As a part of the post-thrusting extensional deformations a northwest extending volcano-sedimentation system of Late Jurassic and Early Cretaceous formed in the southwest side of the belt. These volcano-sedimentary sequences are divided into Tuchengzi Formation, Zhangjiakou Formation, Yixian Formation and Jiufotang Formation re- spectively. They are characterized by southeastward migration as a result of the increasing down-dip slip displacement along the major extensional fault toward the southeast of the belt. The provenance area of the Jiufotang Formation north to it experienced southwestward thrusting during and after its later sedimentation. The thrusting in this stage resulted in the formation of an asymmetric footwall syncline with vergence to SW in the Jiufotang Formation in the NE side of the basin. Finally a dextral strike-slip deformation occurred along the NW tectonic belt. The striking tectono-geomorphological features and present seismic activities along this belt indicate that it has been being active since Cenozoic era and is still in the active state at present. This northwest extending tectonic belt was following the same direction and location as the existing fault systems within the basement as revealed by former geological and geophysical studies. So it is reasonable to infer the Mesozoic deformation along this belt to be a result of reactivation of the basement structures in a favorable tectonic stress field. The reactivation of basement struc- tures might be taken as one of the mechanisms of intraplate deformation and orogeny.

关键词： Yanshan Orogenic Belt, northwest extending tectonic complex, thrust system, geochronology.

TECC Applied in Geopark for a Case Study of Qixia Planning National Geopark

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地学前缘 2009年第S1期16卷 295-296页

作者： Feifei Hu,Mingzhong Tian school of the earth sciences and resources,china university of geosciences(beijing),beijing 100083.china.

This paper applied the theory of TECC(Tourism Environmental Carrying Capacity) into the case of Qixia Planning National *** adopt new planning framework to do the planning of TECC。

关键词： TECC geoheritages basic environment Qixia Planning National Geopark

Fractal Characteristics of Coal Pores Based on Classic Geometry and Thermodynamics Models

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Acta Geologica Sinica(English Edition) 2011年第5期85卷 1150-1162页

作者： CAI Yidong~1,LIU Dameng~(1,*),YAO Yanbin~1,LI Junqian~1 and LIU Junlai~2 1 school of Energy resources,china university of geosciences,beijing 100083.china 2 school of earth Science and resources,china university of geosciences,beijing 100083.china school of Energy resources China University of Geosciences Beijing 100083 China school of earth Science and resources China University of Geosciences Beijing 100083 China

To better understand the characteristics of coal pores and their influence on coal reservoirs, coal pores in eight main coalfields of North china were analyzed by mercury porosimetry and scanning electron microscopy（SEM）.Fractal characteristics of coal pores（size distribution and structure） were researched using two fractal models:classic geometry and *** two models establish the relationship between fractal dimensions and coal pores *** results include:（1） SEM imaging and fractal analysis show that coal reservoirs generally have very high heterogeneity;（2） coal pore structures have fractal characteristics and fractal dimensions characteristic of pore structures are controlled by the composition（e.g.,ash,moisture,volatile component） and pore parameters（e.g.,pore diameter,micro pores content） of coals;（3） the fractal dimensions（D;and D;） of coal pores have good correlations with the heterogeneity of coal pore *** fractal dimensions correlate to higher heterogeneity of pore *** fractal dimensions（D;and D;） have strong negative linear correlations with the sorted coefficient of coals （R;=0.719 and 0.639,respectively） that shows the heterogeneity of coal pores;（4） fractal dimension D;and petrologic permeability of coals have a strong negative exponential correlation（R;=0.82）.However, fractal dimension D;and petrologic permeability of coals have no obvious correlation;and（5） the model of classic geometry is more accurate for fractal characterization of coal pores in coal reservoirs than that of thermodynamics by optimization.

关键词： coal pores mercury porosimetry fractal dimensions thermodynamics model classic geometry model