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Electrolytes in solid-state dye-sensitized nanocrystalline solar cells

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Progress in Natural Science:Materials International 2006年第7期16卷 679-683页

作者： AN Hongli, XUE Bofei, LI Dongmei, MENG Qingbo and GUO Lin ( beijing national {2. for condensed matter physics, institute of physics, chinese academy of sciences, beijing 100080, China Department of Material Science and Engineering, Bei Hang University, beijing 100083, China) Bei Hang Univ Dept Mat Sci & Engn Beijing 100083 Peoples R China chinese Acad Sci Inst Phys Beijing Natl Lab Condensed Matter Phys Beijing 100080 Peoples R China

In this paper, the structure and operating principle of the dye-sensitized nanocrystalline solar cells (DSSC) are dis- cussed. The electrolytes can be divided into three types: liquid electrolyte, quasi-solid electrolyte and solid electrolyte. Based on the relevant study of our group, we summarized mainly the research progress of the quasi-solid electrolyte and solid electrolyte in solid-state DSSC.

关键词： solar cells electrolytes solid-state dye-sensitized.

Characteristics and geological significance of olivine xenocrysts in Cenozoic volcanic rocks from western Qinling

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Progress in Natural Science:Materials International 2006年第12期16卷 1300-1306页

作者： SU Benxun~ 1,2.**, ZHANG Hongfu~1, XIAO Yan~ 1,2.and ZHAO Xinmiao~ 1,2.(1. State Key laboratory of Lithospheric Evolution, institute of Geology and Geo{2., chinese academy of sciences, beijing 10002., China 2. Graduate School of chinese academy of sciences, beijing 100039, China) State Key laboratory of Lithospheric Evolution Institute of Geology and Geophysics Chinese Academy of Sciences Beijing 100029 China Graduate School of chinese academy of sciences Beijing 100039 China

Cenozoic volcanic rocks from the Haoti, Dangchang County of the western Qinling Mountains, contain a few clearly-zoned olivines. These olivines are relatively big in grain sizes and usually have cracks or broken features. Their cores have similar compositions （Mg#=90.4-91.0） to those for the peridotitic xenoliths entrained in host volcanic rocks and their rims are close to the compositions of olivine phenocrysts （Mg#=85.5-81.9）. The CaO contents in these zoned olivines are lower than 0.1%. These features demonstrate that the clearly-zoned olivines are xenocrysts and disaggregated from mantle peridotites. The zoned texture was the result of the interaction between the olivine and host magma. Available data show that the volcanic rocks would have been derived from the mantle source metasomatized by subducted hydrathermally-altered oceanic crust. The formation of these Cenozoic volcanic rocks was perhaps related to the rapid uplift of the Tibetan Plateau.

关键词： Western Qinling Dangchang Haoti Cenozoic volcanic rocks olivine xenocrysts zoned texture.

Containerless solidification of Zr_(41)Ti_(14)Cu_(12.5)Ni_(10)Be_(2..5) glass-forming alloy in drop tube

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chinese Science Bulletin 2002年第20期47卷 1700-1703页

作者： LI Gong, SUN Liling & WANG WenkuiCollege of Material sciences and Engineering, Yanshan University, Qinhuangdao 066004, China Center for condensed {2. physics, institute of physics, chinese academy of sciences, beijing 100080, China national Microgravit Coll. of Mat. Sci. and Engineering Yanshan University Qinhuangdao 066004 China Center for condensed matter {2. Institute of Physics Chinese Academy of Sciences Beijing 100080 China national Microgravity laboratory Chinese Academy of Sciences Beijing 100080 China

Droplets of Zr41Ti14Cu12.5Ni10Be2..5 glass forming alloys with different sizes are solidified in a drop tube containerless processing. Glass transition behavior, crystallization kinetics, and the phase evolution during annealing of the Zr41Ti14Cu12.5Ni10Be2..5 glassy spheres are investigated. The experimental results indicate that the apparent activation energy of the glass transition (Eg=435.5 kJ/mol), and the activation energy of the main crystallization reaction (Ep1 = 2.9.6 kJ/mol) are obviously different from those of bulk glass samples prepared by water quenched (Eg=559.1 kJ/mol and Ep1=192.5 kJ/mol). The difference is discussed in the view point of the atomic configuration of the liquid state of the metallic glass and nucleation mechanism.

关键词： ZrTiCuNiBe alloy containerless processing activation energy drop tube.

Large-scale boron nanowire nanojunctions and their highly-oriented arrays

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Science China(physics,Mechanics & Astronomy) 2004年第5期47卷 621-632页

作者： CAO Limin1,2. ZHANG Ze2.& WANG Wenkui1,2.1. Key laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, China 2. institute of physics, {2., beijing 100080, China Key laboratory of Metastable Materials Science and Technology Yanshan University Qinhuangdao China institute of physics Chinese Academy of Sciences Beijing China

Highly oriented multiple boron nanowire nanojunctions with unilateral feather- like morphology were first successfully prepared using a radio-frequency magnetron sputtering method. The branched boron nano-feathers always nucleate and grow on the same sidewall of the stems, and align in parallel to form multiple T- and/or Y-type nanojunctions. The diameters of the branches and the stems are in the range of 2.—40 and 60—80 nm, respectively. The thinner branches and thicker stems of the boron nanowires self-assembled into large-scale, highly ordered arrays on various substrates. During the formation and self-assembly of the arrays, no template or catalyst was needed. We believe that the approach presented here can be used to fabricate heterostructures with bottom-up assembly of a wide variety of one-dimensional nanostructures via the rational design of targets and the proper control of the experimental conditions.

关键词： boron nanowires, nanojunctions, self-assembly, magnetron sputtering.

Discovery of immune related factors in Fenneropenaeus chinensis by annotation of ESTs

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Progress in Natural Science:Materials International 2004年第1期14卷 48-55页

作者： SHEN Yaoqing 1,2. , XIANG Jianhai 1*, WANG Bing 1,2. , LI Fuhua 1 and TONG Wei 3(1. Experimental Marine Biology laboratory, institute of Oceanology, {2., Qingdao 2.6071,China 2. Graduate School of the {2., beijing 100039, China 3. Genomics & Bioinformatics institute, {2., beijing 101300, China) chinese Acad Sci Inst Oceanol Expt Marine Biol Lab Qingdao 266071 Peoples R China chinese Acad Sci Grad Sch Beijing 100039 Peoples R China chinese Acad Sci Geonom & Bioinformat Inst Beijing 101300 Peoples R China

A total of 10446 expressed sequence tags (ESTs) are obtained by a large scale sequencing of a cDNA library from cephalothorax of adult Fenneropenaeus chinensis . An EST analysis platform was built up based on local computers and bioinformatic techniques were used to annotate these ESTs in order to promptly find possible functional genes, especially for immune related factors. About 4% of the ESTs show similarity to the coding sequences of such factors, including lectin, serine protease, serpin, lysozyme, etc. These ESTs provide a partial profile of the immune system in F. chinensis and useful information for further study on these genes.

关键词： Fenneropenaeus chinensis bioinformatics ESTs immune factors

Atomic force microscopy studies of SrTiO_(3)(001)substrates treated by chemical etching and annealing in oxygen

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Science China(physics,Mechanics & Astronomy) 2005年第4期48卷 459-468页

作者： WANG Xu1, FEI Yiyan1, LU Huibin1, JIN Kui-juan1, ZHU Xiangdong1,3, CHEN Zhenghao1, ZHOU Yueliang1 & YANG Guozhen1 1. beijing national {2. for condensed matter physics,institute of physics,chinese academy of sciences,beijing 100080,China 2. Department of physics,University of California, Davis,California,USA beijing national {2. for condensed matter physics Institute of Physics Chinese Academy of Sciences Beijing China Department of physics University of California Davis USA

The SrTiO3 (001) substrates treated by chemical etching in NH4F-buffered HF solution and annealing in oxygen ambient have been studied by an atomic force microscopy (AFM). The SrTiO3 substrates with TiO2.termineted and atomically smooth surfaces and single unit cell steps have been obtained. The surface morphologies of SrTiO3 substrates strongly depend on the treated conditions and the quality of the substrates.

关键词： SrTiO3, AFM, surface morphology, surface defects.

Bio-regeneration of p-complexation desulfurization adsorbents

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Science China Chemistry 2005年第6期48卷 538-544页

作者： LI Wangliang1,2. XING Jianmin1, XIONG Xiaochao1,2. SHAN Guobin1,2.& LIU Huizhou1 1. laboratory of Separation Science and Engineering, institute of Process Engineering, {2., beijing 100080, China 2. Graduate School of the {2.,beijing 100039, China laboratory of Separation Science and Engineering Institute of Process Engineering Chinese Academy of Sciences Beijing China Graduate School of the chinese academy of sciences Beijing China

The coupling of adsorption desulfurization and biodesulfurization is a new approach to produce clean fuels. Sulfur compounds are firstly adsorbed on adsorbents, and then the ad-sorbents are regenerated by microbial conversion. p-Complexation adsorbent, Cu(I)-Y, was ob-tained by ion exchanging Y-type zeolite with Cu2. and then by auto-reduction in helium at 450℃ for 3 h. Dibenzothiophene (DBT) was used as a model compound. The effects of cell concentra-tion, volume of oil phase, the ratio of aqueous phase to adsorbent on DBT desorption by a bac-terium were studied. The amounts of DBT desorbed and 2.HBP produced can be apparently increased with addition of n-octane. BDS activity can be improved by increasing cell concentra-tion and the ratio of water-to-adsorbent. 89% of DBT desorbed from the adsorbents can be converted to 2.HBP within 6 h and almost 100% within 2. h, when the volume ratio of oil-to-water was 1/5 mL/mL, the cell concentration was 60 g·L?1, and the ratio of adsorbent-to-oil was 0.03 g·mL?1. The amount of 2.HBP produced was strongly dependent on the volume ratio of oil-to- water, cell concentration and amount of adsorbent. Adsorption capacity of the regenerated ad-sorbent is 95% that of the fresh one after being desorbed with Pseudomonas delafieldii R-8, washed with n-octane, dried at 100℃ for 2. h and auto-reduced in He.

关键词： adsorption desulfurization p-complexation adsorbents bio-regeneration Pseudomonas delafieldii desorption.

A new DNA algorithm to solve graph coloring problem

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Progress in Natural Science:Materials International 2007年第6期17卷 733-738页

作者： Jiang Xingpeng1, Li Yin2. Meng Ya3 and Meng Dazhi2.1. national laboratory of Pattern Recognition,{2. of Automation, chinese academy of sciences, beijing 100080, China 2. College of Applied sciences, beijing University of Technology, beijing 10002., China 3. School of Science, beijing {2. of Technology, beijing 100081, China) national laboratory of Pattern Recognition Institute of Automation Chinese Academy of Sciences Beijing 100080 China College of Applied sciences Beijing University of Technology Beijing 100022 China School of Science Beijing Institute of Technology Beijing 100081 China

Using a small quantity of DNA molecules and little experimental time to solve complex problems successfully is a goal of DNA computing. Some NP-hard problems have been solved by DNA computing with lower time complexity than conventional computing. However, this advantage often brings higher space complexity and needs a large number of DNA encoding molecules. One example is graph coloring problem. Current DNA algorithms need exponentially increasing DNA encoding strands with the growing of problem size. Here we propose a new DNA algorithm of graph coloring problem based on the proof of four-color theorem. This algorithm has good properties of needing a relatively small number of operations in polynomial time and needing a small number of DNA encoding molecules (we need only 6R DNA encoding molecules if the number of regions in a graph is R).

关键词： DNA computing NP-hard problem graph coloring problem.

Dynamics of morphological changes for mitochondrial fission and fusion

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Science China(physics,Mechanics & Astronomy) 2010年第4期53卷 680-689页

作者： WANG ShiQi 1,2.4 , FU ChangLiang 1,2., ZHANG Yan 1,2., CHEN Quan 3 & LONG Mian 1,2.1 Key laboratory of Microgravity (national Microgravity laboratory), beijing 100190, China 2.Center for Biomechanics and Bioengineering, institute of Mechanics, chinese academy of sciences, beijing 100190, China 3 State Key laboratory of Biomembrane and Membrane Biotechnology, institute of Zoology, chinese academy of sciences, beijing 100101, China 4 institute of Vertebrate Paleontology and Paleoanthropology, chinese academy of sciences, beijing 100044, China Key laboratory of Microgravity (national Microgravity laboratory) Beijing China Center for Biomechanics and Bioengineering Institute of Mechanics Chinese Academy of Sciences Beijing China institute of Vertebrate Paleontology and Paleoanthropology Chinese Academy of Sciences Beijing China State Key laboratory of Biomembrane and Membrane Biotechnology Institute of Zoology Chinese Academy of Sciences Beijing China

Mitochondria experience continuous fusion and fission in a living cell, but their dynamics remains poorly quantified. Here a theoretical model was developed, upon a simplified population balance equation (PBE), to predict the morphological changes induced by mitochondrial fission and fusion. Assuming that both fission and fusion events are statistically independent, the survival probability of mitochondria staying in the fission or fusion state was formulated as an exponentially-decayed function with time, which depended on the time-dependent distribution of the mitochondrial volume and the fission and fusion rates. Parametric analysis was done for two typical volume distributions. One was Gamma distribution and the other was Gaussian distribution, derived from the measurements of volume distribution for individual mitochondria in a living cell and purified mitochondria in vitro. The predictions indicated that the survival probability strongly depended on morphological changes of individual mitochondria and was inversely correlated to the fission and fusion rates. This work provided a new insight into quantifying the mitochondrial dynamics via monitoring the evolution of the mitochondrial volume.

关键词： mitochondria morphology fission fusion dynamics modeling