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Bio-regeneration of p-complexation desulfurization adsorbents

Science china Chemistry 2005年第6期48卷 538-544页

作者： LI Wangliang1,2. XING Jianmin1, XIONG Xiaochao1,2. SHAN Guobin1,2.& LIU Huizhou1 1. Laboratory of Separation Science and Engineering, institute of Process Engineering, chinese academy of sciences, {2. 100080, china 2. Graduate School of the chinese academy of sciences,{2. 100039, china 1. Laboratory of Separation Science and Engineering Institute of Process Engineering Chinese Academy of Sciences 100080 Beijing China 2. Graduate School of the chinese academy of sciences 100039 Beijing China

The coupling of adsorption desulfurization and biodesulfurization is a new approach to produce clean fuels. Sulfur compounds are firstly adsorbed on adsorbents, and then the ad-sorbents are regenerated by microbial conversion. p-Complexation adsorbent, Cu(I)-Y, was ob-tained by ion exchanging Y-type zeolite with Cu2. and then by auto-reduction in helium at 450℃ for 3 h. Dibenzothiophene (DBT) was used as a model compound. The effects of cell concentra-tion, volume of oil phase, the ratio of aqueous phase to adsorbent on DBT desorption by a bac-terium were studied. The amounts of DBT desorbed and 2.HBP produced can be apparently increased with addition of n-octane. BDS activity can be improved by increasing cell concentra-tion and the ratio of water-to-adsorbent. 89% of DBT desorbed from the adsorbents can be converted to 2.HBP within 6 h and almost 100% within 2. h, when the volume ratio of oil-to-water was 1/5 mL/mL, the cell concentration was 60 g·L?1, and the ratio of adsorbent-to-oil was 0.03 g·mL?1. The amount of 2.HBP produced was strongly dependent on the volume ratio of oil-to- water, cell concentration and amount of adsorbent. Adsorption capacity of the regenerated ad-sorbent is 95% that of the fresh one after being desorbed with Pseudomonas delafieldii R-8, washed with n-octane, dried at 100℃ for 2. h and auto-reduced in He.

关键词： adsorption desulfurization p-complexation adsorbents bio-regeneration Pseudomonas delafieldii desorption.

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Electrochemical properties and interfacial reactions of LiNi0.5Mn1.5O4-δ nanorods

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Progress in Natural Science:Materials International 2012年第3期22卷 207-212页

作者： Liping Wang, Hong Li, Xuejie Huang institute of physics, {2., beijing 100190, china institute of physics Chinese Academy of Sciences Beijing 100190 China

LiNi0.5Mn1.5O4-δ which possesses a high voltage of 4.7 V vs. Lit/Li and stable structure has been considered as a promising cathode material for high energy Li-ion batteries. In this study, well-crystallized LiNi0.5Mn1.5O4-δ nanorods with diameter of ～50 nm and length of ～500 nm were synthesized by a hydrothermal-solid state process followed by a lithiation reaction. It delivers ～12. mA h-g 1 discharge capacity under 30 mA g-1 at 3.5-4.9 V, and 90 mA h g-1 at 150 mA g-1. An unstable solid electrolyte interphase (SEI) film with thickness 2.10 nm was observed by transmission electron microscopy. The thick and unstable SEI layers are responsible for its low rate performance and low coulombic efficiency during cycling.

关键词： Lithium ion battery High voltage spinel Nanorods Surface reaction

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Biodegradable amphiphilic block copolymers containing functionalized PEO blocks:Controlled synthesis and biomedical potentials

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Science china Chemistry 2010年第3期53卷 519-527页

作者： ZHANG Yu1,2.SUN PeiJian1,2.& GAN ZhiHua1 1CAS Key Laboratory of Engineering Plastics,institute of Chemistry,chinese academy of sciences,{2.,china 2.raduate University of chinese academy of sciences,beijing 100039,china 1. CAS Key Laboratory of Engineering Plastics Institute of Chemistry Chinese Academy of Sciences Beijing 100190 China2. Graduate University of Chinese Academy of Sciences Beijing 100039 China

A series of controllable amphiphilic block copolymers composed of poly(ethylene oxide)(PEO) as the hydrophilic block and poly(ε-caprolactone)(PCL) as the hydrophobic block with the amino terminal group at the end of the PEO chain(PCL-b-PEO-NH2. were *** on the further reaction of reactive amino groups,diblock copolymers with functional carboxyl groups(PCL-b-PEO-COOH) and functional compounds RGD(PCL-b-PEO-RGD) as well as the triblock copolymers with thermosensitive PNIPAAm blocks(PCL-b-PEO-b-PNIPAAM) were *** well-controlled structures of these copolymers with functional groups and blocks were characterized by gel permeation chromatography(GPC) and 1H NMR *** copolymers with functionalized hydrophilic blocks were fabricated into microspheres for the examination of biofunctions via cell culture experiments and in vitro drug *** results indicated the significance of introducing functional groups(e.g.,NH2.COOH and RGD) into the end of the hydrophilic block of amphiphilic block copolymers for biomedical potentials in tissue engineering and controlled drug release.

关键词： amphiphilic block copolymers biodegradable polymers functional terminal group cell growth drug release

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Dynamic tree-based authenticated group key exchange protocol

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Science china(Information sciences) 2010年第8期53卷 1591-1602页

作者： LI Hui 1,2., WU ChuanKun 1 & TENG JiKai 1,2.1 State Key Laboratory of Information Security, institute of Software, chinese academy of sciences, {2., china 2.Graduate University of chinese academy of sciences, beijing 100049, china 1. State Key Laboratory of Information Security Institute of Software Chinese Academy of Sciences Beijing 100190 China2. Graduate University of Chinese Academy of Sciences Beijing 100049 China

Authenticated group key exchange protocols allow a group of users over a public network to establish a shared secret key for the subsequent cryptographic goals. In this paper, we extend BD-II scheme into a dynamic setting, and propose a tree-based authenticated key exchange protocol which is more suitable for dynamic groups in such as ad hoc networks. Our protocol is proven secure in random-oracle model. Additionally, we analyze the costs of our protocols in both communication and computation terms, and compare its performance with three well-known protocols.

关键词： tree-based group key exchange dynamic provable security

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Input function and simulated distributions of tritium in the North Pacific

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Science china Earth sciences 2010年第3期53卷 441-453页

作者： BA Qi1,2.& XU YongFu1 1 State Key Laboratory of Atmospheric Boundary Layer physics and Atmospheric Chemistry, institute of Atmospheric physics, chinese academy of sciences, beijing 10002., china 2.Graduate University of chinese academy of sciences, beijing 100049, china 1. State Key Laboratory of Atmospheric Boundary Layer physics and Atmospheric Chemistry Institute of Atmospheric Physics Chinese Academy of Sciences Beijing 100029 China2. Graduate University of Chinese Academy of Sciences Beijing 100049 China

An ocean general circulation model (OGCM) of the North Pacific with a southern open boundary condition is used to simulate the distribution and transport of tritium in the North Pacific. First, the observed tritium in precipitation dataset of GNIP/ISOHIS is chosen, and used to develop an input function of tritium for the model domain from 1951 to 1997 in terms of the triangulation for interpolation. Then, the input function is used as an upper flux for the tritium model. The OGCM with tritium is integrated for 47 years with the initial condition of zero tritium concentrations. Compared with the observations from GEOSECS and WOCE, the model generates a meridional gradient of surface tritium concentrations and the high tritium concentrations in the subsurface layer, which is consistent with that indicated in the observations. The simulated time series of total tritium fluxes from the atmosphere to the ocean shows a spike in 1963. The total inventory of tritium in the ocean changes slowly with time after 1975. Tritium enters the higher-latitude region, and then is mainly transported by the subsurface process towards the equatorial region, which is well simulated in the model. However, the difference mainly occurs at 30°N–40°N, which can be seen also in the simulation of CFCs. This difference may partly originate from the insufficient description of physical processes in the OGCM. Nevertheless, some uncertainties exist in the development of the tritium input function, which can also influence the simulated results.

关键词： North Pacific basin-wide ocean general circulation model tritium input function tritium distributions

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Mineralogy and crystal structure determination of Mg-fillowite

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Science china Earth sciences 2005年第5期48卷 635-646页

作者： MA Zhesheng 1 , SHI Nicheng 1 & YE Danian 2.1. china University of Geosciences, {2. 100083, china 2. institute of Geology, chinese academy of sciences, {2. 10002., china 1. china University of Geosciences 100083 Beijing China 2. institute of Geology Chinese Academy of Sciences 100029 Beijing China

Accurate crystal structure determination of complex phosphate Mg-fillowite ? Na2.a(Mn4Mg2.e)7[PO4]6 has been finished. Mg-fillowite occurs in muscovite-pegmatite in the Altay area, Xinjiang, china. It is of the trigonal lattice, with space group R-3, unit cell a=1.5143(3) nm, c=4.3191(2. nm, V=8.5736 nm3, Z = 18. The R-factor of the determination accuracy is R (I > 2. ( I )) = 0.0776. The cationic polyhedra consist of two kinds of structural units: compound col- umn and screw column. In three-dimensional space, they are linked with each other through corner sharing or edge sharing to build the entire structure. There are 45 atoms in an asymmetric unit and 72. atoms in a unit cell. In terms of types and connection manners of the coordination polyhedra, the degree of complicity is rarely seen in all mineral crystal structures. Study of such a structure is significant for the classification of phosphate and the building rule of coordination polyhedra in a complex crystal structure.

关键词： Mg-fillowite, complex phosphate, crystal structure, coordination polyhedron.

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Explicit analytical solutions of the anisotropic Brinkman model for the natural convection in porous media(Ⅱ)

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Science china(physics,Mechanics & Astronomy) 2005年第4期48卷 422-430页

作者： CAI Ruixian1, GOU Chenhua1, 2.& ZHANG Na1 1. institute of Engineering Thermophysics, {2., beijing 100080, china 2. Graduate School, {2., beijing 100080, china 1. institute of Engineering Thermophysics Chinese Academy of Sciences 100080 Beijing China 2. Graduate School Chinese Academy of Sciences 10080 Beijing China

Some algebraically explicit analytical solutions are derived for the anisotropic Brinkman model―an improved Darcy model―describing the natural convection in porous media. Besides their important theoretical meaning (for example, in analyzing the non-Darcy and anisotropic effects on the convection), such analytical solutions can be the benchmark solutions that can promote the development of computational heat and mass transfer. Some solutions considering the anisotropic effect of permeability have been given previously by the authors, and this paper gives solutions including the anisotropic effect of thermal conductivity and the effect of heat sources.

关键词： explicit analytical solution, porous medium, natural convection, Brinkman model, anisotropic.

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Structures and physical properties of rigid polyurethane foams with water as the sole blowing agent

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Science china Chemistry 2006年第4期49卷 363-370页

作者： LI Xiaobin1,2. CAO Hongbin1 & ZHANG Yi1 1. institute of Process Engineering, chinese academy of sciences, {2. 100080, china 2. Graduate School of the chinese academy of sciences, {2. 100039, china 1. institute of Process Engineering Chinese Academy of Sciences Beijing 100080 China 2. Graduate School of the chinese academy of sciences Beijing 100039 China

Rigid polyurethane foams blown by varying water level were prepared in this study. The structures and physical properties of rigid polyurethane foams blown by water were measured with FT-IR, universal testing machine (Instron3365), scanning electron microscope (SEM) and differential scanning calorimeter (DSC). The results show that polyurea and polybiuret were the typical charac- teristics, and the cream time and gel time were shorter for the fully water blown rigid foams than that for the fully cyclopentane blown foams. The density of foam samples decreased from 45.0 kg/m3 to 2..4 kg/m3 with the increase of water level from 3 pph to 7 pph. Compressive strength exhibited the similar behavior with density. The average cell size of foam samples ranged from 2.1 μm to 356 μm with the increase of water level from 3 pph to 7 pph, respectively. At the same time, poorer dimen- sional stability was encountered with the increase of average cell size due to fast diffusion rate of CO2.out of the foam. The results of thermal analysis show that the glass transition temperature (Tg) shifted to a higher temperature with the increase of isocyanate level when more water was used as chemical blowing agent.

关键词： polyether polyol, polyurethane rigid foam, compressive strength, dimensional stability, cell size, glass transition temperature.

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Assessing the Carrying Capacity of Tourist Resorts: An Application of Tourists’ Spatial Behavior Simulator Based on GIS and Multi-Agent System

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Wuhan University Journal of Natural sciences 2005年第4期10卷 779-784页

作者： ZHANG Ren-jun 1,2.1. institute of Mountain Hazards and Environment, chinese academy of sciences, Chengdu 610041, Sichuan, {2. 2. Graduated School of the chinese academy of sciences, beijing 100039, {2. chinese academy of sciences Institute of Mountain Hazards and Environment Chengdu Sichuan China (GRID:grid.9227.e) (ISNI:***) Graduated School of the chinese academy of sciences Beijing China (GRID:grid.9227.e) (ISNI:***)

Based on the study of visitors' individual spatial behaviors, a tourists'spatial behavior simulator (TSBS) to assess the carrying capacity of tourist resorts was developed,TSBS employs GIS (Geographic Information System) to manage the spatial data,and Multi-Agent systemto simulate the actions of individual visitors. By utilizing TSBS, visitors' travel patterns such aslocation, cost, and state can be analyzed and predicted. Based on this analysis and prediction, themodel of assessing the carrying capacity of resorts is built. Our results show that TSBS will be aneffective tool to accurately assess the carrying capacity of tourist resorts.

关键词： tourist resort carrying capacity TSBS GIS Multi-Agent simulator

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Ambient noise near the sea-route

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Science china(physics,Mechanics & Astronomy) 2009年第1期52卷 40-45页

作者： HE Li1,2. LI ZhengLin1,3 & PENG ZhaoHui1 1 National Laboratory of Acoustics, institute of Acoustics, chinese academy of sciences, {2., china 2.institute of Geology and Geophysics, chinese academy of sciences, beijing 10002., china 3 NanHai Laboratory of Acoustics, institute of Acoustics, chinese academy of sciences, Haikou 5702.6, china National Laboratory of Acoustics Institute of Acoustics Chinese Academy of Sciences Beijing 100190 China institute of Geology and Geophysics Chinese Academy of Sciences Beijing 100029 China NanHai Laboratory of Acoustics Institute of Acoustics Chinese Academy of Sciences Haikou 570206 China

Ambient noise data measured in an experiment conducted in shallow water near a sea-route were analyzed. It was observed that, at low frequency, the horizontal correlation has an obvious difference from that predicted by the classical ambient noise model. The theoretical analyses show that this phenomenon is caused by wind noise together with the discrete shipping noise nearby. An ambient noise model was proposed to include the effects caused by both the noise sources. Data measured at different times verify that the proposed model can be used to forecast the ambient noise field in shallow water near the sea-route.

关键词： ambient noise model horizontal correlation discrete ships

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