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Some key technics of drop tower experiment device of National Microgravity Laboratory (China) (NMLC)

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Science China(Technological sciences) 2005年第3期48卷 305-316页

作者： ZHANG Xiaoqian 1 , YUAN Longgen 1 , WU Wendong 1 , TIAN Lanqiao 2.& YAO Kangzhuang 2.1. institute of Engineering Thermophysics, chinese Academy of {2., beijing 100080, China 2. institute of Mechanics, chinese Academy of {2., beijing 100080, China 1. institute of Engineering Thermophysics Chinese Academy of Sciences 100080 Beijing China 2. institute of Mechanics Chinese Academy of Sciences 100080 Beijing China

Drop tower is an important ground based facility for microgravity science experiment. The technical performances of the drop tower NMLC are advanced compared with similar facilities in the US, Germany and Japan. The main components such as drop capsule, deceleration devices, release mechanism present its advantages and creativities.

关键词： drop tower facility,drop capsule,deceleration devices,release mechanism.

Interfacial behaviors of PMMA-PEO block copolymers at the air/water interface

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Science China chemistry 2005年第6期48卷 567-573页

作者： CHENG Caixia1, JIAO Tifeng2. TANG Rupei1, LIU Minghua2.& XI Fu1 1. State Key Laboratory of Polymer Physics and chemistry, Joint Laboratory of Polymer Science and Materials, institute of chemistry, chinese Academy of {4., beijing 100080, China 2. CAS Key Laboratory of Colloid and Interface Science, institute of chemistry, chinese Academy of {4., beijing 100080, China 1. State Key Laboratory of Polymer Physics and chemistry Joint Laboratory of Polymer Science and Materials Institute of Chemistry Chinese Academy of Sciences 100080 Beijing China 2. CAS Key Laboratory of Colloid and Interface Science Institute of Chemistry Chinese Academy of Sciences 100080 Beijing China

Diblock copolymer of PMMA2.1-b-PEO114.and triblock copolymer of PMMA12.-b- PEO2.7-b-PMMA12. were synthesized and their interfacial properties at the air-water interface were investigated, where both blocks of polyethylene oxide (PEO) and poly(methyl methacrylate) (PMMA) are surface active but the former is soluble in water while the latter is not. Both the block copolymers could form monolayers with two obvious transition regions. The first transition point is around 10 mN/m, which could be assigned to the pancake-brush change of the PEO chains. The other is around 18 mN/m, which could be ascribed to the condensed packing of PMMA. The surface morphological changes during the compression of the Langmuir monolayers are inves-tigated by using the AFM and SEM methods for the films deposited at different surface pressure or molecular areas. At a lower surface pressure, a typical morphology of PEO-con- taining lipopolymers is observed. Upon compression, sphere-dominant morphologies were observed. While the diblock copolymer is easy to folding, the triblock copolymer is in favor of formation of circular domains through vesiculation.

关键词： PMMA-PEO, block copolymers, monolayer, Langmuir-Blodgett films, AFM.

Algebraically explicit analytical solu-tions for the unsteady non-Newtonian swirling flow in an annular pipe

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Science China(Physics,Mechanics & Astronomy) 2006年第4期49卷 396-400页

作者： CAI Ruixian1 & GOU Chenhua1,2.1. institute of Engineering Thermophysics, chinese Academy of {2., {4., China 2. Graduate School, chinese Academy of {2., {4., China 1. institute of Engineering Thermophysics Chinese Academy of Sciences Beijing 100080 China 2. Graduate School Chinese Academy of Sciences Beijing 100080 China

This paper presents two algebraically explicit analytical solutions for the incompressible unsteady rotational flow of Oldroyd-B type in an annular pipe. The first solution is derived with the common method of separation of variables. The second one is deduced with the method of separation of variables with addition developed in recent years. The first analytical solution is of clear physical meaning and both of them are fairly simple and valuable for the newly developing computational fluid dynamics. They can be used as the benchmark solutions to verify the applicability of the existing numerical computational methods and to inspire new differencing schemes, grid generation ways, etc. Moreover, a steady solution for the generalized second grade rheologic fluid flow is also presented. The correctness of these solutions can be easily proven by substituting them into the original governing equation.

关键词： analytical solution, Oldroyd-B type fluid, swirling flow, non-Newtonian.

Explicit analytical solutions of the anisotropic Brinkman model for the natural convection in porous media(Ⅱ)

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Science China(Physics,Mechanics & Astronomy) 2005年第4期48卷 422-430页

作者： CAI Ruixian1, GOU Chenhua1, 2.& ZHANG Na1 1. institute of Engineering Thermophysics, chinese Academy of {2., {4., China 2. Graduate School, chinese Academy of {2., {4., China 1. institute of Engineering Thermophysics Chinese Academy of Sciences 100080 Beijing China 2. Graduate School Chinese Academy of Sciences 10080 Beijing China

Some algebraically explicit analytical solutions are derived for the anisotropic Brinkman model―an improved Darcy model―describing the natural convection in porous media. Besides their important theoretical meaning (for example, in analyzing the non-Darcy and anisotropic effects on the convection), such analytical solutions can be the benchmark solutions that can promote the development of computational heat and mass transfer. Some solutions considering the anisotropic effect of permeability have been given previously by the authors, and this paper gives solutions including the anisotropic effect of thermal conductivity and the effect of heat sources.

关键词： explicit analytical solution, porous medium, natural convection, Brinkman model, anisotropic.

Pattern phenomena in an rf discharge dusty plasma system

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Science China(Physics,Mechanics & Astronomy) 2006年第5期49卷 588-596页

作者： HUANG Feng1,2. YE Maofu2.& WANG Long2.1. College of Science, China Agricultural University, beijing 100083, China 2. institute of Physics, {2. Academy of sciences, {4., China 1. College of Science China Agricultural University Beijing 100083 China 2. institute of Physics Chinese Academy of Sciences Beijing 100080 China

Various dust patterns are observed in an rf discharge dusty plasma system. According to the dust growth process from small to large in size, the formation of different dust patterns can be divided into two stages: the small-particle stage (or dust cloud stage), and the large-particle stage (or dust crystal stage). The evolution relations between different dust patterns with gas pressure changing are investigated. Dust voids, dust acoustic waves and strong turbulence modes are presented at the small-particle stage. The self-organized dust lattices and dust clusters are investigated at the large-particle stage. The static structure of a dust lattice is characterized by means of the pair correlation function. Dust clusters formed by particles with different numbers and the regular evolution of the clusters with gas pressure are also investigated. The packing sequences of dust clusters are verified through two-dimensional confined molecular dynamics simulations.

关键词： dusty plasma dust patterns

Fluorescence dynamics of interactions between polyamide PyPyPyβDp and DNA

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Science China chemistry 2006年第1期49卷 75-80页

作者： ZHANG Huijuan1,2. WANG Jin3, WU Yishi1, YUAN Gu3, AI Xicheng1, WANG Li4.& ZHANG Jianping1 1. State Key Laboratory for Structural chemistry of Unstable and Stable Species, institute of chemistry, {4. Academy of {4., beijing 100080, China 2. School of Life Science and Technology, beijing institute of Technology, beijing 100081, China 3. College of chemistry and Molecular Engineering, Peking University, beijing 100080, China 4. Center for Condensed Matter Physics, institute of Physics, {4. Academy of {4., beijing 100080, China Correspondence should be addressed to Ai Xicheng and Zhang Jianping 1. State Key Laboratory for Structural chemistry of Unstable and Stable Species Institute of Chemistry Chinese Academy of Sciences Beijing 100080 China 2. School of Life Science and Technology Beijing Institute of Technology Beijing 100081 China 3. College of chemistry and Molecular Engineering Peking University Beijing 100080 China 4. Center for Condensed Matter Physics Institute of Physics Chinese Academy of Sciences Beijing 100080 China

The photophysical properties of the polyamide PyPyPyβDp (PPP) were investigated by means of steady-state absorption and fluorescence spectroscopies, as well as time-resolved fluo-rescence spectroscopy. It was found that the excited-state properties of PPP are very sensitive to solvents. In TKMC buffer PPP exhibited weak fluorescence with a decay time constant of 16 ps, while with the decrease of the solvent polarity PPP showed the blue-shifted peak position, increased inten-sity and lengthened life-time for its fluorescence behavior. In the presence of calf thymus DNA, it was observed that the fluorescence intensity was enhanced and the fluorescence lifetime increased from 16 to 32.ps for PPP, which verified that PPP bound into the minor groove of DNA duplex.

关键词： polyamide (PPP), calf thymus DNA (ctDNA), time-resolved fluorescence spectroscopy, recognition dynamics.

SYNTHESIS AND CHARACTERIZATION OF NEW STABILIZERS WITH OPTIMAL MOLECULAR WEIGHT

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chinese Journal of Polymer Science 2001年第4期19卷 341-350页

作者： Jiang-qing Pan institute of chemistry {2. Academy of sciences, {4. China chinese Acad Sci Inst Chem Beijing 100080 Peoples R China

Over 2.x 10(8) tons of polymers are produced every year, and a large portion of polymers faces the degradation problem. There are many effective methods to protect polymers against degradation and the addition of stabilizers to polymer remains the most convenient and effective way of enhancing polymer life and performance. In this article, a series of effective stabilizers with optimal molecular weight (MW), including common, monomeric and polymeric stabilizers (antioxidant and light stabilizer) were synthesized using isocyanation, controlled isocyanation, hydrosilylation, epoxide addition, macroreaction of stabilizing functional compounds and polymerization of monomeric stabilizers. The structure and performance of these new stabilizers were characterized by using IR, NMR, MS, UV-spectra, XPS and elemental analysis. The current development of stabilizer synthesis was also reviewed.

关键词： preparation of stabilizer antioxidant hindered amine light stabilizer isocyanation hydrosilylation

Bio-regeneration of p-complexation desulfurization adsorbents

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Science China chemistry 2005年第6期48卷 538-544页

作者： LI Wangliang1,2. XING Jianmin1, XIONG Xiaochao1,2. SHAN Guobin1,2.& LIU Huizhou1 1. Laboratory of Separation Science and Engineering, institute of Process Engineering, {4. Academy of {2., beijing 100080, China 2. Graduate School of the {4. Academy of {2.,beijing 100039, China 1. Laboratory of Separation Science and Engineering Institute of Process Engineering Chinese Academy of Sciences 100080 Beijing China 2. Graduate School of the chinese Academy of sciences 100039 Beijing China

The coupling of adsorption desulfurization and biodesulfurization is a new approach to produce clean fuels. Sulfur compounds are firstly adsorbed on adsorbents, and then the ad-sorbents are regenerated by microbial conversion. p-Complexation adsorbent, Cu(I)-Y, was ob-tained by ion exchanging Y-type zeolite with Cu2. and then by auto-reduction in helium at 4.0℃ for 3 h. Dibenzothiophene (DBT) was used as a model compound. The effects of cell concentra-tion, volume of oil phase, the ratio of aqueous phase to adsorbent on DBT desorption by a bac-terium were studied. The amounts of DBT desorbed and 2.HBP produced can be apparently increased with addition of n-octane. BDS activity can be improved by increasing cell concentra-tion and the ratio of water-to-adsorbent. 89% of DBT desorbed from the adsorbents can be converted to 2.HBP within 6 h and almost 100% within 2. h, when the volume ratio of oil-to-water was 1/5 mL/mL, the cell concentration was 60 g·L?1, and the ratio of adsorbent-to-oil was 0.03 g·mL?1. The amount of 2.HBP produced was strongly dependent on the volume ratio of oil-to- water, cell concentration and amount of adsorbent. Adsorption capacity of the regenerated ad-sorbent is 95% that of the fresh one after being desorbed with Pseudomonas delafieldii R-8, washed with n-octane, dried at 100℃ for 2. h and auto-reduced in He.

关键词： adsorption desulfurization p-complexation adsorbents bio-regeneration Pseudomonas delafieldii desorption.

Structures and physical properties of rigid polyurethane foams with water as the sole blowing agent

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Science China chemistry 2006年第4期49卷 363-370页

作者： LI Xiaobin1,2. CAO Hongbin1 & ZHANG Yi1 1. institute of Process Engineering, chinese Academy of {2., {4., China 2. Graduate School of the chinese Academy of {2., beijing 100039, China 1. institute of Process Engineering Chinese Academy of Sciences Beijing 100080 China 2. Graduate School of the chinese Academy of sciences Beijing 100039 China

Rigid polyurethane foams blown by varying water level were prepared in this study. The structures and physical properties of rigid polyurethane foams blown by water were measured with FT-IR, universal testing machine (Instron3365), scanning electron microscope (SEM) and differential scanning calorimeter (DSC). The results show that polyurea and polybiuret were the typical charac- teristics, and the cream time and gel time were shorter for the fully water blown rigid foams than that for the fully cyclopentane blown foams. The density of foam samples decreased from 4..0 kg/m3 to 2..4.kg/m3 with the increase of water level from 3 pph to 7 pph. Compressive strength exhibited the similar behavior with density. The average cell size of foam samples ranged from 2.1 μm to 356 μm with the increase of water level from 3 pph to 7 pph, respectively. At the same time, poorer dimen- sional stability was encountered with the increase of average cell size due to fast diffusion rate of CO2.out of the foam. The results of thermal analysis show that the glass transition temperature (Tg) shifted to a higher temperature with the increase of isocyanate level when more water was used as chemical blowing agent.

关键词： polyether polyol, polyurethane rigid foam, compressive strength, dimensional stability, cell size, glass transition temperature.