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An efficient chiral synthesis of (R)-N-[3-acetyl-4-(2.hydroxy-3-isopropylamino-propoxy)phenyl]-butanamide with high enantioselectivity

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Science China Chemistry 2009年第8期52卷 1216-1219页

作者： WANG NaiXing1,2.& TANG XinLiang1,3 1 Technical Institute of Physics and Chemistry,chinese academy of{2.,beijing 100080,China 2.College of Chemistry and Chemical Engineering,graduate university of chinese academy of{2.,beijing 100049,China 3 School of Chemical Engineering and Environment,beijing Institute of Technology,beijing 100081,China 1. Technical Institute of Physics and Chemistry Chinese Academy of Sciences Beijing 100080 China 2. College of Chemistry and Chemical Engineering Graduate University of Chinese Academy of Sciences Beijing 100049 China 3. School of Chemical Engineering and Environment Beijing Institute of Technology Beijing 100081 China

R-Enantiomer of the β-receptor antagonist N-[3-acetyl-4-(2.hydroxy-3-isopropylamino-propoxy)phenyl] butanamide with high enantioselectivity was synthesized from cheap starting materials and enantiopure chiral reagent through an efficient,convenient and practical synthetic *** product was detected by 1H NMR,13C NMR,and MS,and the enatiomeric excess was determined by chiral HPLC analysis using a chiracel AD-H column.

关键词： chiral synthesis enantioselectivity enatiomeric excess chiral HPLC analysis

Kumada chain-growth polycondensation as a universal method for synthesis of well-defined conjugated polymers

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Science China Chemistry 2010年第8期53卷 1620-1633页

作者： GENG YanHou1,HUANG Li1,2.WU ShuPeng1,2.& WANG FoSong1 1State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied Chemistry,chinese academy of{2.,Changchun 13002.,China 2.3} university of chinese academy of{2.,beijing 100049,China 1. State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun 130022 China2. Graduate University of Chinese Academy of Sciences Beijing 100049 China

Kumada chain-growth polycondensation (KCGP) is a novel method for the synthesis of well-defined conjugated *** the Ni-catalyst can transfer in an intramolecular process to the propagating chain end,the polymerization follows chain-growth *** this newly developed method,various conjugated polymers,such as polythiophenes,poly(p-phenylene) (PPP),polypyrrole (PPy),and polyfluorene with controlled molecular weights and relatively narrow polydispersities (PDIs),have been ***,the polymerizations for poly(3-alkylthiophene)s (P3ATs),PPP,and PPy exhibited quasi-living characteristics,which allows preparing polymer brushes,fully-conjugated block copolymers,and macroinitiators and macro-reactants for the synthesis of rod-coil block *** the current review,the progress in this new area is summarized.

关键词： chain growth polycondensation conjugated polymers Kumada reaction block copolymers polymer brush

Forecasting the summer rainfall in North China using the year-to-year increment approach

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Science China Earth sciences 2009年第4期52卷 532-539页

作者： FAN Ke1, LIN MeiJing1,2.& GAO YuZhong3 1 Nansen-Zhu International Research Center, Institute of Atmospheric Physics, chinese academy of{2., beijing 10002., China 2.graduate university of the chinese academy of{2., beijing 100049, China 3 Heilongjiang Meteorological Administration, Harbin 150030, China Nansen-Zhu International Research Center Institute of Atmospheric Physics Chinese Academy of Sciences Beijing 100029 China graduate university of the{2. academy of sciences Beijing 100049 China Heilongjiang Meteorological Administ

A new approach to forecasting the year-to-year increment of rainfall in North China in July-August (JA) is proposed. DY is defined as the difference of a variable between the current year and the preceding year (year-to-year increment). NR denotes the seasonal mean precipitation rate over North China in JA. After analyzing the atmospheric circulation anomalies associated with the DY of NR, five key predictors for the DY of NR have been identified. The prediction model for the DY of NR is established by using multi-linear regression method and the NR is obtained (the current forecasted DY of NR added to the preceding observed NR). The prediction model shows a high correlation coefficient (0.8) between the simulated and the observed DY of NR throughout period 1965-1999, with an average relative root mean square error of 19% for the percentage of precipitation rate anomaly over North China. The prediction model makes a hindcast for 2.00-2.07, with an average relative root mean square error of 2.% for the percentage of precipitation rate anomaly over North China. The model reproduces the downward trend of the percentage of precipitation rate anomaly over North China during 1965-2.06. Because the current operational prediction models of the summer precipitation have average forecast scores of 60%-70%, it has been more difficult to forecast the summer rainfall over North China. Thus this new approach for predicting the year-to-year increment of the summer precipitation (and hence the summer precipitation itself) has the potential to significantly improve operational forecasting skill for summer precipitation.

关键词： annual increment North China precipitation prediction prediction skill

Experimental and discrete element numerical analysis of side slope instability induced by fissure water underlying impervious bed

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Science China(Technological sciences) 2005年第z1期48卷 65-80页

作者： LIU Bingshan1, LI Shihai1, ZHANG Lei1,2.& WANG Jianguo31. Institute of Mechanics, chinese academy of{2., beijing 100080, China 2. graduate School, chinese academy of{2., beijing 100060, China 3. Tropical Marine Science Institute, National university of Singapore, 10 Kent Ridge Crescent, Singapore 1192.0 chinese Acad Sci Inst Mech Beijing 100080 Peoples R China chinese Acad Sci Grad Sch Beijing 100060 Peoples R China Natl Univ Singapore Trop Marine Sci Inst Singapore 119260 Singapore

When the sliding mass contains impervious bed, rainfall can infiltrate into mountain via crevices and form higher artesian aquifer at impervious bed inferior. This will decrease slip resistance and increase sliding forces of the sliding mass, thus lowering the safety factor, and inducing landslide disasters. In this paper, a landslide experimental apparatus is designed for experimental studies on the mechanism of this type of landslides. Meanwhile, the non-dimensional parameters in the model experiment are taken into account using dimensional analysis. The experimental results show that (1) the ratio of the cleft water pressure to the overlying pressure is a crucial parameter affecting the stability of the slope; (2. when the shut-in pressure reaches 80% of the normal component of the pressure on the slip surface made up of rock and soil, landslide will occur; (3) the whole slope will start to slide when the shut-in pressure is equal to the normal component of the pressure formed by the overlying rock and soil on the upper 30% area. In this article, a discrete element method simulation is used to investigate the influence of cleft water pressure and shearing strength on the landslide stability. It can be concluded that the critical value of Ccr, ?cr, which determines the slide mass stability, increases with the increase of the water pressure; if the water pressure reaches a high level, the stability of the slide mass depends mainly on C, while the influence of ? becomes smaller than C.

关键词： impervious bed, rainfall infiltration, pore water pressure, landslide experiment, displacement monitor, discrete element method.

Birthrates and delay times of Type Ia supernovae

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Science China(Physics,Mechanics & Astronomy) 2010年第3期53卷 586-590页

作者： WANG Bo1,2.3, LIU ZhengWei1,2.3, HAN YunKun1,2.3, LEI ZhenXin1,2.3, LUO YangPing1,2.3 & HAN ZhanWen1,2.1National Astronomical Observatories/Yunnan Observatory, chinese academy of{2., Kunming 650011, China 2.ey Laboratory for the Structure and Evolution of Celestial Objects, chinese academy of{2., Kunming 650011, China 3graduate university of chinese academy of{2., beijing 100049, China 1. National Astronomical Observatories/Yunnan Observatory Chinese Academy of Sciences Kunming 650011 China2. Key Laboratory for the Structure and Evolution of Celestial Objects Chinese Academy of Sciences Kunming 650011 China3. Graduate University of Chinese Academy of Sciences Beijing 100049 China

Type Ia supernovae (SNe Ia) play an important role in diverse areas of astrophysics, from the chemical evolution of galaxies to observational cosmology. However, the nature of the progenitors of SNe Ia is still unclear. In this paper, according to a detailed binary population synthesis study, we obtained SN Ia birthrates and delay times from different progenitor models, and compared them with observations. We find that the Galactic SN Ia birthrate from the double-degenerate (DD) model is close to those inferred from observations, while the birthrate from the single-degenerate (SD) model accounts for only about 1/2.2.3 of the observations. If a single starburst is assumed, the distribution of the delay times of SNe Ia from the SD model is a weak bimodality, where the WD + He channel contributes to the SNe Ia with delay times shorter than 100 Myr, and the WD + MS and WD + RG channels to those with age longer than 1 Gyr.

关键词： binaries: close stars: evolution supernovae: general white dwarfs

Spatial heterogeneity of the driving forces of cropland change in China

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Science China Earth sciences 2005年第12期48卷 2231-2240页

作者： LIU Xuhua1,2. WANG Jinfeng1, LIU Mingliang4,1 & MENG Bin1,2.3 1. Institute of Geographic sciences and Natural Resources Research, chinese{2. of sciences, beijing 100101, China 2. graduate School of the chinese{2. of sciences, beijing 100039, China 3. College of Arts and sciences of beijing Union {12., beijing 100083, China 4. School of Forestry and Wildlife sciences, Auburn {12., Auburn, Alabama, AL36849, USA 1. Institute of Geographic sciences and Natural Resources Research Chinese Academy of Sciences 100101 Beijing China 2. graduate School of the chinese{2. of sciences 100039 Beijing China 3. School of Forestry and Wildlife sciences Auburn University Auburn AL36849 Alabama USA 4. College of Arts and sciences of beijing Union{2. 100083 Beijing China

By using digital satellite remote sensing data acquired in 1987―1989 and 1999―2.00 and GIS combined with the natural and socio-economic data, this paper drew an integrated zonation of the cropland change and its driving forces in China. The results indicated that the cropland change in the study period was constrained by geographical factors and driven by cli-mate change as well as socio-economic system. Moreover, the regional differences of the drivers for cropland change were significant. In the midwest of China, natural condition changes and geographical background were the main constraints and drivers, while in Eastern China, social and economic changes and economic policies were the main driving forces. The cropland loss was nationwide. The dominant factors to cause this decrease included buildup of developing area to attract foreign capital and technologies, changes of industry structure due to urban in-fluence, the change of employment notions thanks to living standard improvement, rapid ur-banization due to the expansion of cities and towns, the diminished farming net income partly because of the global warming effects, and the rapid economic growth stimulated by the con-venient transportation system. These factors interact and interdepend with each other to cause the cropland loss in China recently. The reasons for the increase of cropland were primarily the cultivation and deforestation by the farmers who want to increase income. This study on the mechnism of LUCC relied on the cropland change integrated classification considering the natural or human factors both inside and outside the region, which provides a new approach to study the integrated regionalization and LUCC mechanism.

关键词： land use change, driving force, integrated classification, spatial statistics, cropland, China.

Cloning,expression and characterization of a nucleoside diphosphate kinase (NDPK) gene from tobacco

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Progress in Natural Science:Materials International 2007年第08期17卷 906-912页

作者： Zhou Qiyun~(1,2.*) Xie Zongming~(1**) Zhang Zhigang~1 Cao Yangrong~1 Zhang jinsong~(1***) Chen Shouyi~(1***) (1.National Key Laboratory of Plant Genomics,Institute of Genetics and Developmental Biology,chinese academy of{2.,beijing100101,China 2.graduate university of chinese academy of{2.,beijing 100039,China) [a]National Key Laboratory of Plant Genomics Institute of Genetics and Developmental Biology Chinese Academy of Sciences Beijing China [b]graduate university of{2. academy of sciences Beijing China

Nucleoside diphosphate kinase (NDPK) is a housekeeping enzyme that maintains the intracellular levels of all (d)NTPs used in biosynthesis except *** we report that a full-length cDNA encoding nucleoside diphosphate kinase (NDPK) was cloned us- ing yeast two-hybrid approach.A tobacco NDPK gene was obtained and designated as ***1 is 704 bp in length and en- codes a putative 16.2.kD protein of 148 amino *** analysis showed that NtNDPK1 is highly homologous to other plant NDPK genes and identified as type I (NDPK1).RNA-gel blot analysis showed that there was no significant difference of NtNDPK1 ex- pression in roots,stems,leaves and *** expression of NtNDPK1 was induced by ABA and PEG and repressed by NaCl,but not significantly affected by Paraquat,wounding and low temperature (4℃) treatments,indicating that NtNDPK1 may play a certain role in response to abiotic *** vitro phosphorylation assay demonstrated that NtNDPK1 had autophosphoryLation activity.

关键词： abiotic stress autophosphorylation activity NtNDPK1 tobacco yeast two-hybrid

Impact Assessment and Protection of Outstanding Landscape Integrity in a Natural Heritage Site:Fairy Valley,Kanas Nature Reserve,Xinjiang,China

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Journal of Mountain Science 2011年第1期8卷 46-52页

作者： HAN Fang1,2.YANG Zhaoping1,LIU Xinyu1,2.DI Feng3 1 Xinjiang Institute of Ecology and Geography,chinese academy of{2.,Urumqi 830011,China 2.graduate university of chinese academy of{2.,beijing 100049,China 3 Xinjiang Department of Science and Technology,Urumqi 830011,China Xinjiang Institute of Ecology and Geography Chinese Academy of Sciences Urumqi China graduate university of{2. academy of sciences Beijing China Xinjiang Department of Science and Technology Urumqi China

The essential purpose of the Convention Concerning the Protection of World Cultural and Natural Heritage is to protect the integrity of heritage *** landscape is the core embodiment of the aesthetic value of a natural heritage *** paper proposes a new assessment method from the point of view of the protection of heritage *** is used to measure the degree of outstanding landscape integrity under the human and natural impact in natural heritage *** paper employ three indices,a visual index of outstanding landscape,a harmony index of the artificial landscape and a disturbance index of damaged landscape,to measure the impact of landscape *** impact assessment model is based on a weighted combination of the three *** study site is the Fairy Valley,Kanas Nature Reserve,Xinjiang Uygur Autonomous Region in northwest *** information employed is derived from field investigation and a Digital Elevation Model(DEM).A comprehensive evaluation of the Fairy valley was undertaken and it was determined that the outstanding landscape values are being *** protection methods are proposed to reduce the adverse effects and maintain landscape quality,thereby providing site managers with suggestions for the protection of natural heritage *** broadly,the paper contributes novel methods of landscape assessment applicable to natural protected areas.

关键词： Landscape integrity Landscape impact assessment Landscape protection Natural heritage site Kanas Nature Reserve Xinjiang

A Test on Different Types of the Time Curve of Hardness Ratio of Gamma-Ray Bursts based on the Curvature Effect

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chinese Journal of Astronomy and Astrophysics 2008年第4期8卷 451-464页

作者： Lan-Wei Jia National Astronomical Observatories/Yunnan Observatory,chinese academy of{2.,Kunming 650011,China graduate School of chinese academy of{2.,beijing 100049,China National Astronomical Observatories/ Yunnan Observatory Chinese Academy of Sciences Kunming 650011 China and graduate School of chinese{2. of sciences Beijing 100049 China

We analyzed a sample of 66 gamma-ray bursts （GRBs） and statistically confirmed the prediction on the time curve of the hardness ratio of GRBs made by Qin et al. based on the curvature effect. In their analysis, GRB pulses are divided into three types according to the shape of their raw hardness ratio （RHR） time curves, defined as to include the background counts to the signal counts, so as to make use of counts within small time intervals. Of the three types, very hard sources exhibit a perfect pulse-like profile （type 1）, hard bursts possess a pulse-like profile with a dip in the decay phase （type 2., and soft bursts show no pulse-like profile but have only a dipped profile （type 3）. In terms of the conventional hardness ratio, type 3 sources are indeed generally softer than those of type 1 and type 2. in agreement with the prediction. We found that the minimum value of RHR is sensitive in distinguishing the different types. We propose that GRB pulses can be classified according to the minimum value of RHR and that the different type sources may be connected with different strengths of the shock or/and the magnetic field.

关键词： gamma-rays burst -- gamma-rays observations - methods statistical