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Indian Ocean-MORB-type isotopic signature of Yushigou ophiolite in North Qilian Mountains and its implications

science china {2. sciences 2006年第6期49卷 561-572页

作者： HOU Qingye1,2. ZHAO Zhidan1,2. ZHANG Hongfei3, ZHANG Benren3 & CHEN Yuelong2.1. State Key Laboratory of Geological Processes and mineral resources,{2., beijing 100083, china 2. school of earth science and mineral resources,{2., beijing 100083, china 3. Faculty of earth sciences,{2., Wuhan 430074, china 1. State Key Laboratory of Geological Processes and mineral resources China University of Geosciences Beijing 100083 China 2. school of earth science and mineral resources China University of Geosciences Beijing 100083 China 3. Faculty of earth sciences China University of Geosciences Wuhan 430074 China

In order to explore the disputed issue concerning the tectonic affinity ofthe ancient ocean mantle of North Qilian Mountains (NQM), geochemical and Sr, Nd, Pb isotopiccompositions of pillow basalts of the Yushigou Ophiolite (YSGO) suite from NQM have been analyzedsystematically. The pillow basalts exhibit tholeiitic characteristics, with flatchondrite-normalized REE patterns ((La/Yb)_N = 0.98—1.2.). They display no Nb, Ta, Zr, Hf negativeanomalies, and show MORB features in 2.b-Zr/4-Y and Ti/100-Zr-YX3 tectonic discrimination *** results indicate that the Yushigou ophiolite is most likely to be formed in a mid-ocean ridgeor mature back-arc basin. Their isotopic data show a relatively broad and enriched ^(87)Sr/^(86)Sr(0.70509 — 0.70700), restricted ^(143)Nd/^(144)Nd (0.512.55-0.512.78). Pb isotopes are in the rangeof ^(2.6)Pb/^(2.4)Pb (18.054-2..562., ^(2.7)Pb/^(2.4)Pb (15.537-15.743) and ^(2.8)Pb/^(2.4)Pb(38.068-38.530). These isotopic data imply that the basalts originated from the depleted mantle(DMM), with the involvement of enriched mantle components (mainly EMII). Geochemical comparisonsbetween the basalts in YSGO and the MORB-type basalts of ophiolite suites occurring in the knownancient Tethyan tectonic domain indicate that the ancient oceanic mantle represented by YSGO suiteforming in early Paleozoic in the North Qilian Moutains is very similar to the Tethyan mantle inboth trace elements and isotopic compositions. The North Qilian Mountains should be a part of theTethyan tectonic domain in early Paleozoic. This further implies that the Tethyan tectonic domaincan be deduced to early Paleozoic in the study area, which will be helpful to discussing thetectonic affinity and evolution of the North Qilian Mountains.

关键词： geochemistry, Indian Ocean-MORB-type isotopic signatures, Tethyan tectonic domain, Yushigou ophiolite, North Qilian Mountains.

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Spatio-temporal carbon isotope variation during the Ediacaran period in South china and its impact on bio-evolution

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science china {2. sciences 2009年第10期52卷 1520-1528页

作者： WANG XinQiang1 & SHI XiaoYing1,2.1 school of earth {2. and mineral resources, china university of geosciences, beijing 100083, china 2.State Key Laboratory of Geological Processes and mineral resources, beijing 100083, china school of earth {2. and mineral resources China University of Geosciences Beijing 100083 China State Key Laboratory of Geological Processes and mineral resources Beijing 100083 China

The Ediacaran period is characterized by the extremely negative carbon isotope anomalies and great biotic evolution in earth history. At least four negative carbon isotope anomalies have been reported from this interval in South china so far. It is traditionally argued that the isotope variations can be used as a useful tool for global correlation of Ediacaran succession; however, more and more researches argued against this idea. We reviewed the previously published carbon isotope data in South china, and distributed the mean values of a certain time to the paleogeographic maps. The results show that the carbon isotope values (δ13C) vary greatly in different environments, but a clear tendency of becoming lighter from shallow platform to deep basin, with a maximum variation up to 1‰ Moreover, the important changes in Ediacaran biota, marked by the introducing of new taxa or ecologic groups, seemed to always postdate the negative anomalies but coincide with the positive shift. If the negative excursions represented the oxidation of a large dissolved organic carbon (DOC) reservoir in the ocean, the diverse Ediacaran organisms and the carbon isotope anomalies may suggest totally different environments: oxic and anoxic/euxinic. We also suggest that the elimination of euxinic state through precipitation of pyrites is one of the important environment factors in prompting the Ediacaran bio-evolution.

关键词： Ediacaran South china carbon isotope spatio-temporal variations bio-evolution

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science china {2. sciences 2004年第10期47卷 896-911页

作者： ZHANG Changhou1,2. WU Ganguo1,2. WANG Genhou2. ZHANG Weijie2.& SONG Honglin2.1. Key Laboratory of Lithospheric Tectonics and Lithoprobing Technology, china university of geosciences, Ministry of Education of china,{2., china 2. school of earth sciences and mineral resources, china university of geosciences,{2., china 1. Key Laboratory of Lithospheric Tectonics and Lithoprobing Technology China University of Geosciences Ministry of Education of China 100083 Beijing China 2. school of earth {2.s and mineral resources China University of Geosciences 100083 Beijing China

The northwest trending tectonic belt in the middle part of the Mesozoic intraplate Yanshan Orogenic Belt, northeast Hebei Province, is composed of thrusts, extensional faults, strike-slip faults and syntectonic sedimentations as well. The northeastward basement-involved major thrusting deformation occurred between 174Ma and 168MaBP and was followed by an intrusion of the granitic plutonic rocks. As a part of the post-thrusting extensional deformations a northwest extending volcano-sedimentation system of Late Jurassic and Early Cretaceous formed in the southwest side of the belt. These volcano-sedimentary sequences are divided into Tuchengzi Formation, Zhangjiakou Formation, Yixian Formation and Jiufotang Formation re- spectively. They are characterized by southeastward migration as a result of the increasing down-dip slip displacement along the major extensional fault toward the southeast of the belt. The provenance area of the Jiufotang Formation north to it experienced southwestward thrusting during and after its later sedimentation. The thrusting in this stage resulted in the formation of an asymmetric footwall syncline with vergence to SW in the Jiufotang Formation in the NE side of the basin. Finally a dextral strike-slip deformation occurred along the NW tectonic belt. The striking tectono-geomorphological features and present seismic activities along this belt indicate that it has been being active since Cenozoic era and is still in the active state at present. This northwest extending tectonic belt was following the same direction and location as the existing fault systems within the basement as revealed by former geological and geophysical studies. So it is reasonable to infer the Mesozoic deformation along this belt to be a result of reactivation of the basement structures in a favorable tectonic stress field. The reactivation of basement struc- tures might be taken as one of the mechanisms of intraplate deformation and orogeny.

关键词： Yanshan Orogenic Belt, northwest extending tectonic complex, thrust system, geochronology.

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South china's Gondwana connection in the Paleozoic:Paleomagnetic evidence

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Progress in Natural science:Materials International 2004年第1期14卷 86-91页

作者： ZHANG Shihong*(school of earth {2.s and resources, china university of geosciences, beijing 100083, china) china Univ Geosci Sch Earth Sci & Resources Beijing 100083 Peoples R China

The reconstruction in which the South china Block (SCB) lies along the Great India Australia region of Gondwana margin is tested by using existing Paleozoic paleomagnetic data. Under the proposed reconstruction, all six high quality paleopoles from the SCB between the Early Cambrian and late Early Devonian (～400 Ma) are in good agreement with coeval paleopoles from Gondwana. Thereafter, the apparent polar wander paths for the SCB and Gondwana diverge markedly. This indicates that the SCB had been part of Gondwana and the connection was intact from at least Early Cambrian until late Early Devonian, but they began to separate by late Middle Devonian (～375 Ma).

关键词： South china block Gondwana paleomagnetism reconstruction

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Fractal Characteristics of Coal Pores Based on Classic Geometry and Thermodynamics Models

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Acta Geologica Sinica(English Edition) 2011年第5期85卷 1150-1162页

作者： CAI Yidong~1,LIU Dameng~(1,*),YAO Yanbin~1,LI Junqian~1 and LIU Junlai~2.1 school of Energy resources,{2. university of geosciences,beijing 100083,{2. 2.school of earth science and resources,{2. university of geosciences,beijing 100083,{2. school of Energy resources China University of Geosciences Beijing 100083 China school of earth {2. and resources China University of Geosciences Beijing 100083 China *Correspondence: Dameng LIU *Correspondence: Corresponding author. E-mail: dmliu@***

To better understand the characteristics of coal pores and their influence on coal reservoirs, coal pores in eight main coalfields of North china were analyzed by mercury porosimetry and scanning electron microscopy（SEM）.Fractal characteristics of coal pores（size distribution and structure） were researched using two fractal models:classic geometry and *** two models establish the relationship between fractal dimensions and coal pores *** results include:（1） SEM imaging and fractal analysis show that coal reservoirs generally have very high heterogeneity;（2. coal pore structures have fractal characteristics and fractal dimensions characteristic of pore structures are controlled by the composition（e.g.,ash,moisture,volatile component） and pore parameters（e.g.,pore diameter,micro pores content） of coals;（3） the fractal dimensions（D;and D;） of coal pores have good correlations with the heterogeneity of coal pore *** fractal dimensions correlate to higher heterogeneity of pore *** fractal dimensions（D;and D;） have strong negative linear correlations with the sorted coefficient of coals （R;=0.719 and 0.639,respectively） that shows the heterogeneity of coal pores;（4） fractal dimension D;and petrologic permeability of coals have a strong negative exponential correlation（R;=0.82..However, fractal dimension D;and petrologic permeability of coals have no obvious correlation;and（5） the model of classic geometry is more accurate for fractal characterization of coal pores in coal reservoirs than that of thermodynamics by optimization.

关键词： coal pores mercury porosimetry fractal dimensions thermodynamics model classic geometry model

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Comparative study on CO_2.corrosion behavior of N80,P110,X52.and 13Cr pipe lines in simulated stratum water

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science china(Technological sciences) 2010年第9期53卷 2342-2349页

作者： CAI YiDong1,GUO PengChao1,LIU DaMeng1,CHEN ShiYu2.& LIU JunLai3 1 school of Energy resources,{2. university of geosciences,beijing 100083,{2. 2.school of Materials science and Engineering,university of science and Technology beijing,beijing 100083,{2. 3 school of earth sciences and resources,{2. university of geosciences,beijing 100083,{2. 1. school of Energy resources China University of Geosciences Beijing 100083 China2. School of Materials Science and Engineering University of Science and Technology Beijing Beijing 100083 China3. School of Earth Sciences and Resources China University of Geosciences Beijing 100083 China

To better understand the carbon dioxide (CO2. corrosion behavior of carbon steel and its influence on petroleum development (including drilling,production and transportation) in the Daqing Oilfield,CO2.corrosion behaviors of N80,P110,X52.and 13Cr pipe lines in simulated solution at high temperature and high pressure condition are investigated by dynamic corrosion experiments,scanning electron microscope (SEM) and energy dispersive X-ray spectroscopy (EDS) *** show that the corrosion rate of all pipe lines increases quickly when CO2.partial pressure increases from 0.5 to 1.5 MPa,but it slows down when CO2.partial pressure further increases from 1.5 to 4.5 MPa,during which localized corrosion is *** the experimental temperature ranges from 60 to 12.°C,localized corrosion *** corrosion rate of all pipe lines decreases sharply when the temperature changes from 60 to 100°C,and it becomes stable after the temperature is higher than 100°*** the flow rate is in the range of 0–1.5 m/s,the corrosion rate of sample X52.remains unchanged,but localized corrosion gradually becomes very serious when the flow rate further *** analyzing the corrosion product scales of sample 13Cr,some remarkable phenomena are *** the temperature range of 60–100°C,the corrosion product scales are loose and thick,but become very compact when the temperature increases above 100°*** the later case,localized corrosion is *** main components of the corrosion product scales are FeCO3 and Cr2.3.

关键词： CO2 corrosion pipe lines weight loss SEM EDS

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Pioneer organisms after F-F mass extinction in Dushan region,Guizhou Province,and their significance in establishing new ecosystem

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science china {2. sciences 2006年第5期49卷 449-460页

作者： WANG Yue1, 2. WANG Xunlian1 & SHI Xiaoying1 1. school of earth {2.s and resources, china university of geosciences, beijing 100083, china 2. school of resources and Environment, Guizhou university, Guiyang 550003, china 1. school of earth {2.s and resources China University of Geosciences Beijing 100083 China 2. school of resources and Environment Guizhou University Guiyang 550003 China

After mass extinctions, most areas became “ecologically barren areas” lacking or even without ecosystem over an extensive region. Studying the pioneer organisms and the reconstruction process of a new ecosystem in the “ecologically barren area” is very important for revealing the evo- lution after bio-mass extinctions. In the Dushan region, Guizhou Province, china, the trace fossils appeared and flourished evidently earlier than body fossils after Frasnian-Famennian (F-F) mass extinction. The pioneer organisms and pathfinders in the “ecologically barren areas” are the trace-makers that are deposit-feeders with relatively simple structure and conformation on or near the deposit surface. The trace-makers have undergone an evolutionary process that their trace structures changed from simple to complex, and their living and moving areas and spaces enlarged from linear to planar and then to three-dimension spaces. Those characters show that the ability of the trace-makers to deposits and their efficiency of looking for food have been enhanced gradually and that those trace-makers constructed gradually a base for the new ecosystem. This process is similar to that of the trace fossils near the Precambrian-Cambrian boundary. In the Dushan area, only the recovery intervals have been identified for the Famennian body fossils, with no eminent radiation interval recognizable due to the Devonian-Carboniferous (C-D) mass ex- tinction. However, both the recovery and radiation intervals may be clearly recognized in the Famen- nian trace fossils based on their conformation and diversity. The evolution and diversification of the trace fossils in the “ecologically barren area” is considered to have played a role of necessary foun- dation for the recovery of body fossils in the ecological chain. With the gradual disappearance of the unfavourable environment factors resulting in the F-F mass extinction, a new ecosystem was reconstructed in the “ecologically barren area” through a three-

关键词： pioneer organisms, reconstruction of ecosystem, trace fossils, F-F mass extinction, Later Devonian, Dushan region, Guizhou Province, china.

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The role of aerial algae in the formation of the landscape of the Yunnan Stone Forest,Yunnan Province, china

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science china {2. sciences 2004年第9期47卷 846-864页

作者： TIAN Youping1,3, ZHANG Jie2. SONG Linhua1 & BAO Haosheng2.1. Institute of Geographic sciences and Natural resources Research, Chinese Academy of sciences, beijing 100101, china 2. Department of Geography, Nanjing university, Nanjing 2.0093, china 3. school of earth sciences and resources, china university of geosciences,{12., china Institute of Geographic sciences and Natural resources Research Chinese Academy of Sciences Beijing 100101 China Department of Geography Nanjing University Nanjing 210093 China school of earth {2.s and resources China University of Geosciences Beijing 100083 China

Aerial algae on the surface of carbonate rocks at the Stone Forest, Shilin County, Yunnan Province, china, and their bioerosion were investigated in the field and studied in the laboratory in detail. Through the observation, identification and statistics of more than one hun- dred algal samples and rock samples with the optical microscopes (stereomicroscope, biological microscope) and the scanning electronic microscope (SEM), the relationships between erosional forms on the surface of the Stone Forest and algae and/or algal communities and the genetic mechanism for the formation of erosional forms were analyzed. It is suggested that aerial algae play an active role in bioerosive processes that may affect the formation of karst erosional forms. These effects include both direct and indirect ones. The direct effect is the initiative control (algal shape-controlling role) of algae on the formation of karst forms of various scales, mostly mi- cro-scale (<10-3m) and minor-scale (10-3-10-1m) erosional forms. The algal shape-controlling roles can be divided into the algal individual shape-controlling role and the algal community shape-controlling role. The former mostly controls the formation of micro-scale erosional forms, while the latter mostly controls the formation of micro-scale and smaller minor-scale erosional forms. The indirect effect refers to the promoting role of algae in the formation of karst forms, which may affect the formation of karst forms of all types and scales. The bioerosion of algae accelerates the weathering process of the whole Stone Forest karst landforms.

关键词： aerial algae, bioerosion, the Stone Forest, Yunnan Province, china.

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The equilibrium between diagenetic calcites and dolomites and its impact on reservoir quality in the sandstone reservoir of Kela 2.gas field

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Progress in Natural science:Materials International 2007年第9期17卷 1051-1058页

作者： Gao Zhiqian1,Yu Bingsong2.3 and Lai Xingyun2.3(1.school of Energy resources,{2. university of geosciences,beijing 100083,{2. 2.State Key Laboratory of Geological Processes and mineral resources,{2. university of geosciences,beijing 100083,{2. 3.Ministry of Education Key Laboratory of Lithosphere Structure,Deep Processes and Exploration Technique,{2. university of geosciences,beijing 100083,{2.) school of Energy resources China University of Geosciences Beijing 100083 China State Key Laboratory of Geological Processes and mineral resources China University of Geosciences Beijing 100083 China Ministry of Education Key Laboratory of Lithosphere Structure Deep Processes and Exploration Technique China University of Geosciences Beijing 100083 China

Based on the equilibrium theory of chemical reactions between water and rocks,this paper establishes a thermodynamic phase relationship diagram among calcites,dolomites and water solution under the condition of diagenesis based on the thermodynamic database of related minerals and fluids and dolomite's degree of order *** has been discovered that the equilibrium between calcites and dolomites in the diagenetic environment is strongly impacted by temperature and the Ca/Mg ratios in groundwater,and that the dolomite's degree of order in the diagenetic environment is a function of crystallization temperature and time,not controlled by water ***,the authors make a further analysis of the close relationship of chemical reaction between carbonate cements and pore water in the sandstone reservoirs of Kala 2.gas field in Kuche *** can be seen that there are different impacts on sandstone reservoir quality among the equilibrium system of calcites,dolomites and pore water at different depths of reservoirs.

关键词： diagenesis equilibrium between calcites and dolomites secondary pores Kela 2.gas field

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Characteristics of Ore-Forming Fluids of Gold Deposits in Daqingshan District,Inner Mongolia,china

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International Journal of minerals,Metallurgy and Materials 1999年第2期13卷 77-82页

作者： Jiuhua Xu YulingXie Dayi Qian Rufu Dine Jianping Li (Resource Engineering school, university of {2. and Technology Beijha beijing 100083, china) (china university of geosciences, beijing 100083, china) Resource Engineering school University of Science and Technology Beijing Beijing 100083 China china university of {2. Beijing 100083 China

***-weststrikingductileshearzonewithinagreelt,***:(1)pyrite-quartz,(2.quartz-Pyrite,(3)polymetallicsulfidesand(4)***-bearingveinsarenativegold,electrum,pyrite,chalcopyriteandgalena,buttheganguemineralsaremainlyquartz,secondarilysericite,***,silicification,***-formingfluidswerelowinsalinitieandhighinCO2.ontent,MeasuredδDoffluidinclusionsinquartzfromtheoreveinsrangesfrom-65‰to-104‰,butδ18Oquartzfrom10.0‰to12.8‰.Thesedatashowthatthewaterinhydrothermalfluidprecipitatingtheorebodiescouldhavebeenmainlymagmaticwaterandmetamorphicwaterbutlocalmeteoricwatermighttakepartinthelatemineralization.δ13Cfromfl

关键词： fluid inclusions isotope composition gold deposit Daqingshan area

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