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Science china(Technological Sciences) 2009年第3期52卷 584-589页

作者： XU YePeng1 & ZHOU Ding2.1 School of Science, nanjing University of Science and technology, nanjing 2.0094, china 2.college of Civil Engineering, nanjing University of technology, nanjing 2.0009, china School of Science Nanjing University of Science and Technology Nanjing China college of Civil Engineering Nanjing University of Technology Nanjing China

This paper studies the bending of simple-supported rectangular plate on point supports, line supports and elastic foundation. On the basis of three-dimensional elasticity theory, the exact expressions of the displacement functions, which satisfy the governing differential equations and the simply supported boundary conditions at four edges of the plate, are analytically derived. The reaction forces of the in- termediate supports are regarded as the unknown external forces acting on the lower surface of the plate. The unknown coefficients are then determined by the boundary conditions on the upper and lower surfaces of the plate. Comparing the numerical results obtained from the proposed method to those obtained from Kirchhoff plate theory, Mindlin plate theory and those obtained from the commer- cial finite element software ANSYS, the high accuracy of the present method has been demonstrated.

关键词： rectangular plate point support line support elastic foundation displacement stress three-dimensional elasticity solution

Adsorption of surfactants onto acrylic ester resins with different pore size distribution

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Science china Chemistry 2006年第5期49卷 445-453页

作者： YANG Weiben1,2.3,LI Aimin1,3,CAI Jianguo1,3,MENG Guanhua1,3 & ZHANG Quanxing1,3 1. State Key Laboratory of Pollution Control and Resource Reuse,School of the Environment,nanjing University,nanjing 2.0093,{2. 2. nanjing college of chemical technology,nanjing 2.0048,{2. 3. Jiangsu Engineering & technology Research Center for Organic Toxicant Control and Resource Reuse,nanjing 2.0038,{2. State Key Laboratory of Pollution Control and Resource Reuse School of the Environment Nanjing University Nanjing China nanjing college of {2. technology Nanjing China Jiangsu Engineering & technology Research Center for Organic Toxicant Control and Resource Reuse Nanjing China

In this study, a series of acrylic ester resins with different pore size distribution were prepared successfully by varying the type and the amount of pore-forming agents. In order to inves-tigate the adsorption behavior and mechanism of surfactants on acrylic ester resins, three kinds of surfactants were utilized as adsorbates that were sodium 6-dodecyl benzenesulfonate (6-NaDBS), sodium 1-dodecyl benzene sulfonate (1-NaDBS) and sodium 1-dodecyl sulfonate, respectively. It was observed that the surface area was available in a particular pore size and an appropriate pore size of resins appeared to be more important for the adsorption of surfactants. As compared to commercial acrylic ester resins XAD-7 and HP2.G, 50# and 38# resins exhibited more excellent adsorption properties toward 1-NaDBS and 6-NaDBS. The experimental equilibrium data were fitted to the Langmuir, and double-Langmuir models. Two models provided very good fittings for all resins over the temperature range studied. The investigation indicated that electrostatic attraction and hydrogen bond between resins and surfactants were the main forces and had an obvious effect on adsorption proc-ess.

关键词： acrylic ester resin, surfactant, adsorption, pore size distribution, isotherm.

Hydroisomerization of n-heptane over bimetal-bearing H_3PW_(12.O_(40) catalysts supported on dealuminated USY zeolite

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Science china Chemistry 2008年第2期51卷 120-127页

作者： WEI RuiPing1,2. GU YanBo1 & WANG Jun1 1 State Key Laboratory of Materials-Oriented chemical Engineering, college of Chemistry and chemical Engineering, nanjing Uni- versity of technology, nanjing 2.0009, china 2.college of Chemistry and chemical Engineering, Southeast University, nanjing 2.1189, china State Key Laboratory of Materials-Oriented chemical Engineering College of Chemistry and Chemical Engineering Nanjing University of Technology Nanjing China college of Chemistry and chemical Engineering Southeast University Nanjing China

The bimetal-bearing (CePt or LaPt) 12.tungstophosphoric acid (H3PW12.40 (PW)) catalysts supported on dealuminated USY zeolite (DUSY) were prepared by impregnation and characterized by XRD, BET, IR, and H2.chemisorption. Their catalytic activities were tested in the hydroisomerization of n-heptane with a continuous atmospheric fixed-bed reactor. After the steam treatment combined with the acid leaching, as well as the supporting with PW and the bimetals, the DUSY support retains the Y zeolite porosity and the PW well keeps its Keggin structure in catalysts. The doping of Ce into the catalysts enhances the dispersion of Pt on the catalyst surface. The Pt-bearing PW catalysts doped with Ce or La, especially Ce, exhibit much higher catalytic activity and selectivity than the catalysts without dopants at lowered reaction temperatures. At the optimal reaction conditions, i.e., the reaction temperature of 2.0℃ and WHSV of 1.4 h1, the catalyst with a Pt loading of 0.4%, PW loading of 10% and a molar ratio of Ce to Pt of 15:1 shows a conversion of n-heptane of 70.3% with a high selectivity for isomerization products of 94.1%.

关键词： hydroisomerization of n-heptane bimetal catalyst heteropoly acid USY platinum

Cross-linked Polyethylenimine as Potential DNA Vector for Gene Delivery with High Efficiency and Low Cytotoxicity

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Acta Biochimica et Biophysica Sinica 2006年第11期38卷 780-787页

作者： Wei DONG~(1,2. Guang-Hui JIN~1 Shu-Feng LI~(1,3) Qi-Ming SUN~1 Ding-Yuan MA~1 Zi-Chun HUA~1 1 State Key Laboratory of Pharmaceutical Biotechnology,college of Life Science,{2. University,{2. 2.0093,china 2.School of chemical Engineering {2. University of Science and technology,{2. 2.0094,china 3 college of Basic Medical Science,Southeast University,{2. 2.0009,china State Key Laboratory of Pharmaceutical Biotechnology College of Life Science Nanjing UniversityNanjing 210093 China School of chemical Engineering Nanjing University of Science and TechnologyNanjing 210094 China college of Basic Medical Science Southeast UniversityNanjing 210009 China

Polyethylenimine (PEI) has been known as an efficient gene carrier with the highest cationiccharge *** transfection efficiency of PEI,along with its cytotoxicity,strongly depends on itsmolecular *** enhance its gene delivery efficiency and minimize cytotoxicity,we have synthesizedsmall cross-linked PEI with biodegradable linkages and evaluated their transfection efficiencies in *** study,branched PEI with a molecular weight of 800 Da was cross-linked by small diacrylate[1,4-butanediol diacrylate or ethyleneglycol dimethacrylate (EGDMA)] for 2.6 *** efficiencies of thecross-linked PEI in in vitro transfection of plasmid DNA containing enhanced green fluorescent protein(EGFP) reporter gene were assessed in melanoma B 16F10 cell line and other cell *** cytometrywas used to quantify the cellular entry efficiency of plasmid and the transgene expression *** of the cross-linked PEI in these cells were evaluated by MTT ***-PEI 800-4h,atypical cross-linked PEI reported here,mediated a more efficient expression of reporter gene than thecommercially available 2.-kDa branched PEI control,and resulted in a 9-fold increase in gene deliveryin B16F10 cells and a 16-fold increase in 2.3T cells,while no cytotoxicity was found at the optimizedcondition for gene ***,the transfection activity of polyplexes was preserved in thepresence of serum proteins.

关键词： polyethylenimine gene delivery cytotoxicity B16F10 2.3T cell line

Synthesis and Lubrication of Phosphorylcholine Derivative

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Journal of Bionic Engineering 2010年第3期7卷 254-258页

作者： Zhenliang Qiao~1, Dangsheng Xiong~1, Lude Lu~2. Pengju Jiang~2.1. Department of Materials Science and Engineering, nanjing University of Science and technology, nanjing 2.0094, P.R. china 2. School of chemical Engineering, nanjing University of Science and technology, nanjing 2.0094, P. R. china Department of Materials Science and Engineering Nanjing University of Science and Technology Nanjing P.R. China School of chemical Engineering Nanjing University of Science and Technology Nanjing P. R. China

The monomer of phosphorylcholine derivative, O-(5-（2.methacryloxy）-3, 3-dimethyl-3-azapentyl)-O’-（ω-hydroxy-octyl）-phosphatequaternary ammonium salt, was designed and synthesized successfully. It was characterized by the spectra ofHNMR and Mass spectra （ESI+）, and every signal was assigned. Then the lubricating characteristics of the phosphorylcholinederivative were investigated on the tribological setup of ball-oh-flat. The Ultra-High Molecular Weight Polyethylene（UHMWPE） flat was rotated against a stainless steel ball with 6 mm diameter. The load was 2.3 N, which corresponded to amaximal Hertz contact pressure of 2. MPa. Water, phosphorylcholine derivative, and Acrylic Acid （AA） solution were used aslubricants, respectively. Compared with AA, the phosphorylcholine derivative shows significant lubrication. It can be stronglyhydrated under water due to the charged segment in chemical structure. The thick water layers within the chains serves asboundary lubricants, and this is thought to be the molecular origins of lubricating behavior.

关键词： artificial joint articular cartilage molecular lubrication mechanism phosphorylcholine synthesis UHMWPE

Resolution method for overlapping peaks based on the fractional-order differential

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Science china Chemistry 2007年第6期50卷 797-805页

作者： LI YuanLu1, YU ShengLin2.& ZHENG Gang2.1 college of Information & Control, nanjing University of Information Science & {2., nanjing 2.0044, china 2.college of Automation Engineering, nanjing University of Aeronautics and Astronautics, nanjing 2.0016, china college of Information & Control Nanjing University of Information Science & Technology Nanjing China college of Automation Engineering Nanjing University of Aeronautics and Astronautics Nanjing China

Equations between the differential order and the maximum of the fractional-order differential for the specified peak signals are developed based on the variation of the maximum of the specified peak signals at different orders. Also, equations between the differential order and the zero-crossing of the fractional-order differential of the specified peak signals are proposed according to the variation of the zero-crossing of the specified peak signals at different orders. Characteristic paramters of the Gaus- sian peak, Lorentzian peak, and Tsallis peak can be estimated using estimator I and estimator II which are obtained by the equations above. As a result, a new method is presented to resolve the overlapped peaks signal. Firstly, a fractional-order differential of the specified peak signals is obtained with the fractional-order differentiation filter. Then, characteristic paramters of the specified peak signals can be extracted using estimator I and estimator II. Finally, the Tsallis peak is used as a model to assign the overlapping peak signals correctly. Experimental results show that the proposed method is efficient and effective for the simulated overlapping peaks and detected overlapping voltammetric peak signals.

关键词： fractional-order differentiation filter, fractional-order differential, overlapping peaks, voltammetric peak

Study on design pressure of in-service welding pipes

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Science china(Technological Sciences) 2006年第4期49卷 434-444页

作者： XUE Xiaolong1, ZHU Jiagui2.& SANG Zhifu1 1. college of Mechanical and Power Engineering, nanjing University of {2., nanjing 2.0009, china 2. nanjing Yangzi Petrochemical Maintenance and Installation Co. Ltd., nanjing 2.0048, china college of Mechanical and Power Engineering Nanjing University of Technology Nanjing China nanjing Yangzi Petrochemical Maintenance and Installation Co. Ltd. Nanjing China

A method of predicting design pressure and burn-through of in-service welding pipes was established. Temperature distributions of in-service welding under variable parameters were simulated by FEM. The effect of flowing of internal media was regarded as forced convection. Based on the numerical results, design pressure of the pipe can be obtained and burn-through can be predicted. It can be concluded that the design pressure decreases with the increasing of heat input. RSF and design pressure of the pipe increase with the increasing of flow rate. There is a range in which the increase changes greatly. For in-service welding, the range should be considered adequately to determine operating condition optimally. RSF increases with the increasing of pipe wall thickness. While the thickness increases to an extent, RSF shows little increase. Accord- ing to the curves of design pressure versus different parameters, safe working pressure can be achieved.

关键词： in-service welding, heat input, flow rate, pipe wall thickness, design pressure.

A NOVEL INTERPRETATION OF CONCENTRATION DEPENDENCE OF VISCOSITY OF DILUTE POLYMER SOLUTION

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Chinese Journal of Polymer Science 2000年第1期18卷 57-67页

作者： Yan Pan Rong-shi Cheng college of Material Science and Engineering, South china University of {2., Guangzhou 510641, china college of Chemistry and chemical Engineering, nanjing University, nanjing 2.0093, china 华南理工大学广东广州

The concentration dependence of the reduced viscosity of dilute polymer solution is interpreted in the light of a new concept of the self-association of polymer chains in dilute solution. The apparent self-association constant is defined as the molar association constant divided by the molar mass of individual polymer chain and is numerically interconvertible with the Huggins coefficient. The molar association constant is directly proportional to the effective hydrodynamic volume of the polymer chain in solution and is irrespective of the chain architecture. The effective hydrodynamic volume accounts for the non-spherical conformation of a short polymer chain in solution and is a product of a shape factor and hydrodynamic volume. The observed enhancement of Huggins coefficient for short chain and branched polymer is satisfactorily interpreted by the concept of self-association. The concept of self-association allows us to predict the existence of a boundary concentration C-s(dynamic contact concentration) which divides the dilute polymer solution into two regions.

关键词： self-association polymer solution viscosity concentration dependence

A Raw Signal Simulator for Bistatic SAR

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Chinese Journal of Aeronautics 2009年第4期22卷 434-443页

作者： Xia Weijie,Zhou Jianjiang college of Information Science and technology,{2. University of Aeronautics and Astronautics,{2. 2.0016,china college of Information Science and technology Nanjing University of Aeronautics and Astronautics Nanjing 210016 China

This article proposes a new efficient raw signal simulator for the bistatic synthetic aperture radar （SAR） based on 2. fast Fourier transform （FFT） to deal with cases of both ideal trajectory and trajectory deviation. It begins with analyzing the geometric configuration and the range history of the bistatic SAR in side-looking and squint modes of ideal trajectory as well as trajectory deviation. Then a detailed and mathematical study is conducted on the equivalence relation of bistatic-to-monostatic applications （BTMA） in the case of ideal trajectory and trajectory deviation. Also a set of formulas are derived for the equivalence relation between bistatic SAR and monostatic SAR on some reasonable assumptions. Therefore, the application of the simulation method based on the 2. FFT for the monostatic SAR can be extended to the case of bistatic SAR. Finally, the simulation results prove the validity of this method. By comparing the efficiency of the proposed method with that of the time domain method, it is shown that the former is a few orders of magnitude higher.

关键词： bistatic synthetic aperture radar raw signal simulation fast Fourier transform

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Science china Chemistry 2004年第6期47卷 466-479页

作者： SONG Huajie1,2. XIAO Heming1 & DONG Haishan2.1. Department of Chemistry, nanjing University of Science and technology, nanjing 2.0094, china 2. Institute of chemical Materials, china Academy of Engineering Physics, Mianyang 62.900, china Department of Chemistry Nanjing University of Science and Technology Nanjing China Institute of chemical Materials China Academy of Engineering Physics Mianyang China

The symmetry-adapted perturbation theory (SAPT) that has the ability in decompo- sition of the total interaction energy into physically meaningful components is used to provide a more fundamental understanding of intermolecular forces. This work was motivated by the diffi- culty of standard SAPT in computing the intermolecular interactions for large energetic dimer systems. SAPT based on Kohn-Sham orbitals (SAPT(DFT)) proves computationally efficient for these large systems, but has been shown to perform poorly for interaction energy components. The deficiencies of SAPT(DFT) result from wrong asymptotical behaviors of commonly used exchange-correlation potentials. To remove the deficiencies, two asymptotic corrections by means of van Leeuwen and Baerends (LB) model potential and Fermi-Amaldi (FA) type potential were applied into three small test systems comprising He2. HF2.and (N2.2.and a set of larger ni- tramide dimers at several separations. The results showed that when utilizing newly developed frequency-dependent density susceptibilities (FDDS) technique for computing dispersion energy, the FA asymptotic correction is very effective to circumvent these deficiencies in SAPT(DFT) and yields a good accuracy over the LB correction. The FA corrected SAPT(DFT) approach is capa- ble of correctly predicting all the quantitative trends in binding energies for all test cases and substantially reduces computational cost as compared with the standard SAPT calculations. The successful application of the approach to nitramide dimer demonstrates that it potentially pro- vides a good means to calculate accurately intermolecular forces in larger system such as en- ergetic systems.

关键词： intermolecular interaction, density functional theory (DFT), symmetry adapted perturbation theory (SAPT), asymptotic correction, frequency-dependent density susceptibilities (FDDS).