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AFM study on the adsorption and aggregation behavior of dissolved humic substances on mica

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Science china Chemistry 2006年第3期49卷 256-266页

作者： GE Xiaopeng1, ZHOU Yanmei2. Lü Chunhua1 & TANG Hongxiao1 1. State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, beijing 100085, china 2. {2. of Civil Engineering & Architecture, beijing Jiaotong University, beijing 100044, china 1. State Key Laboratory of Environmental Aquatic Chemistry Research Center for Eco-Environmental Sciences Chinese Academy of Sciences Beijing 100085 China 2. school of Civil Engineering & Architecture Beijing Jiaotong University Beijing 100044 China

Humic substances constitute the major organic fractions of soils, sediments and natural waters, and play a dominant role in the binding, mobilization, transport and ultimate fate of organic contaminants in subsurface systems. In this paper, two humic acid samples, Guanting and Tianjin, with different origin and chemical compositions have been investigated with AFM imaging for their adsorption and aggregation behaviors on mica. While the Tianjin humic sample is found to form small spheres with 2.0 to 330 nm in diameter at lower concentrations, irregular loop-chain assemblies of hundreds of nanometer in diameter with the chain width of about 40 nm are dominant for the Guanting humic sample, which may attribute to the more polar aliphatic fractions in the chemical composition in the latter. The heterogeneous and polydisperse nature of humic substances with multiple structural features, such as sponge-like structures, perforated sheets, aggregate of spheres, branches and chain-like assemblies etc., is apparent at higher concentrations for both humic samples, showing morphologically new evidence for the dominant view of the humic dual-mode sorption model. With naphthalene introduced, the assemblies of Guanting humic substances clearly become more compact with significantly narrowed branches and less porous the perforated sheet-like structures. It is indica- tive of that smaller nanometer scale rings present along the perforated assemblies could potentially represent hydrophobic domains, which may facilitate the adsorption and aggregation of naphthalene onto the natural particle surfaces and therefore lead to an important role of dissolved humic sub- stances in the sorption of environmental pollutants.

关键词： atomic force microscopy (AFM) dissolved humic substances morphology aggregation adsorption

Research on Jiuquan-Jiayuguan-Yumen Region's Dynamic Changing of Urbanization Based on Self-Organizing Model

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Chinese Journal of Population,Resources and Environment 2005年第3期3卷 22-28页

作者： Li Ming 1,2.& Fang Chuanglin 2.1 graduate school of the Chinese Academy of Sciences, {2.,china 2.Institute of Geographical Sciences and Natural Resources Research, CAS, beijing 100101, china graduate school of the Chinese Academy of Sciences Beijing 100039 China Institute of Geographical Sciences and Natural Resources Research CAS Beijing 100101 China

Based on the self-organizing modeling principle in the dissipative structure theory, the paper regards the migration coupling between the regions as the influence factor to create the model of regional urbanization simulation and prediction, which is more practical to simulate the space-time and dynamic evolvement characteristics of regional urbanization level. According to the historical data about the population and urbanization of Jiuquan, Jiayuguan andYumen cities, the past 50 years' dynamic evolvement trend is simulated and the following 50 years' dynamic evolvement trend is predicted with the urbanization dynamic evolvement model based on the self-organizing model. The analysis of effective factors such as economic increase, resources exploitation, ecosystem construction, traffic location, national policies, population migration are given, then the reasons of the dynamic evolvement differences of the three cities' urbanization are drawn. The study suggests that the self-organizing model is fit for the simulation of Jiuquan-Jiayuguan-Yumen regional urbanization level in the past 50 years, and the departure between the stimulant and the actual data is under 5%, so it can be used to predict the urbanization future of the three cities. The predicted results show that the regional population will reach 1.074 million and the regional urbanization level will be 72.56%.

关键词： self-organizing urbanization dynamic evolvement Jiuquan-Jiayuguan-Yumen region

Paleoceanographic evolution recorded in the northern South china Sea since 4 Ma

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Science china Earth Sciences 2005年第12期48卷 2166-2173页

作者： HUANG Baoqi1,2. JIAN Zhimin2.& WANG Pinxian2.1. school of Earth and Space Sciences, Peking University, beijing 100871,{2. 2. Laboratory of Marine Geology, Tongji University, Shanghai 2.0092.{2. 1. school of Earth and Space Sciences Peking University 100871 Beijing China 2. Laboratory of Marine Geology Tongji University 200092 Shanghai China

Upper water structure over the last 4 million years in the northern South china Sea (SCS) was reconstructed by sea surface temperature (SST) and primary productivity estimated by changes in the abundance of planktonic foraminifer, planktonic foraminifer transfer function, and the accumulation rate of benthic foraminifera. Results of SST and primary productivity show that SST gradually decreased since 4 Ma, but differential seasonal temperature and primary productivity increased in steps mainly at about 3.1, 2.7, 2.1, 1.6, 0.9 and 0.5 Ma. Comparison with tectonics and orbital variations indicates that phased rising of the Tibet since 3.6 Ma, closing of Panama and Indonesian seaways, and orbital changes were responsible for the changes of upper water structure in the SCS, respectively.

关键词： northern South china Sea, upper water structure, Late Pliocene, planktonic foraminifer, ODP 1146.

Temporal-spatial variations of euphotic depth of typical lake regions in Lake Taihu and its ecological environmental significance

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Science china Earth Sciences 2006年第4期49卷 431-442页

作者： ZHANG Yunlin1, 2. QIN Boqiang1, HU Weiping1, WANG Sumin1, CHEN Yuwei1 & CHEN Weimin1 1. Nanjing Institute of Geography & Limnology, Chinese Academy of Sciences, Nanjing 2.0008, china 2. graduate {2. of the Chinese Academy of Sciences, beijing 100039, china 1. Nanjing Institute of Geography & Limnology Chinese Academy of Sciences Nanjing 210008 China 2. graduate school of the Chinese Academy of Sciences Beijing 100039 China

By using the data of underwater irradiance measured in the different lakeregions of Lake Taihu during 1998—2.04 and total suspended solids (TSS), wind speeds of the total13 stations in typical lake regions during 1993—2.03, this paper analyzes the factors ofinfluencing on PAR (pho-tosynthetically available radiation) attenuation, euphotic depth, andpresents the temporal and spatial variations of euphotic depth of typical lake regions in LakeTaihu, and the spectral distributions of euphotic depth at station 2. The results show that theconcentration of TSS is the most important factor impacting PAR attenuation, followed by chlorophylla; chromophoric dissolved organic matter (CDOM) has little impact on the PAR euphotic depth. During1993—2.03, the mean yearly PAR euphotic depths of the typical lake regions ranged from 1.04 to1.95 m with a mean value of 1.35±0.2. m. The PAR euphotic depth fell into 3 spatial zone types:Type Ⅰ, the lowest, including the lake center and the inflows of rivers; Type Ⅱ, intermediate,including Meiliang Bay, Wulihu Lake and Gonghu Bay; Type Ⅲ, the greatest, including the East LakeTaihu; corresponding mean depths were approximately 1.1, 1.4, 2.0 m, respectively. The seasonalvariations of euphotic depths were not quite the same in different lake regions. In the lake center,the mean values of PAR euphotic depth in summer and autumn were significantly greater than those inwinter and spring; in the Meiliang Bay, winter means were significantly greater than in the otherthree seasons; in the East Lake Taihu, winter means were significantly less than in the other threeseasons. However, no distinct seasonal change was recorded in the Wulihu Lake, Gonghu Bay and theinflows of rivers. The spectral distributions of euphotic depth present a minimal value at the bluelight wave band of 400 nm, and a peak at the green light wave band of around 580 nm. In 1998 and1999, based on the seasonal many-day continuous measurements, the PAR euphotic depths at station 2.

关键词： lake taihu euphotic depth diffuse attenuation coefficient total suspendedsolid ecological

Formal analysis and design of multi-party fair exchange protocols

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Science in china(Series F) 2006年第2期49卷 155-174页

作者： QING Sihan1,2.3 & LI Gaicheng1,3 1. Engineering Research Center for Information Security Technology, Institute of Software, Chinese Academy of Sciences, beijing 100080, china 2. beijing Zhongke Ansheng Corporation of Information Technology, beijing 100080, china 3. graduate school of the Chinese Academy of Sciences, beijing 100039, china 1. Engineering Research Center for Information Security Technology Institute of Software Chinese Academy of Sciences Beijing 100080 China 2. beijing Zhongke Ansheng Corporation of Information Technology Beijing 100080 China 3. graduate school of the Chinese Academy of Sciences Beijing 100039 China

Based on the origin of message items and channel combination between transacting parties, and events and relations among events, this paper presents a concise, precise, and hierarchical model for general fair exchange protocols, formally specifies various security requirements which are able to reflect inherent requirements for fair exchange protocols more rigorously, and partition these security requirements with fine granularity. This work helps analyze, debug, and design multi-party fair exchange protocols more effectively and elaborately,

关键词： fair exchange logical protocol formal model security requirement.

Environmental characteristics of Mid-Holocene recorded by lacustrine sediments from Lake Daihai, north environment sensitive zone, china

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Science china Earth Sciences 2006年第9期49卷 968-981页

作者： SUN Qianli1,2. ZHOU Jie1, SHEN Ji3, CHEN Peng1,2. WU Feng1,2.& XIE Xiuping1,2.1. State Key Lab of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi’an 710075, china 2. graduate University of Chinese Academy of Sciences, {2., china 3. Nanjing Institute of Geography and Limnology, Chinese Academy of Sciences, Nanjing 2.0008, china 1. State Key Lab of Loess and Quaternary Geology Institute of Earth Environment Chinese Academy of Sciences Xi’an 710075 China 2. graduate University of Chinese Academy of Sciences Beijing 100039 China 3. Nanjing Institute of Geography and Limnology Chinese Academy of Sciences Nanjing 210008 China

Climate proxies, such as total organic carbon and nitrogen (TOC, TN), carbonate content (CaCO3), grain-size and pollen of the sediment core retrieved from enclosed Lake Daihai which lies in the north china environment sensitive zone are analyzed to reconstruct the environment evolution of the area based on high-resolution radiocarbon chronology. The results reveal that the TOC and TN contents of the sediments correlate well with pollen percentage and pollen flux variations during the Holocene, and both reach their peak values simultaneously at 6.7―3.5 ka BP (calendar age, 7.6―3.6 ka BP). Since 6.7 ka BP, both the CaCO3 and organic matter contents of the core have simultaneous variations, and their high values also occur during 6.7―3.5 ka BP. While during 9.0―6.7 ka BP (calendar age, 10―7.6 ka BP) relatively lower level of organic matter content and pollen flux corre- spond to the higher level of carbonate content. The above relations suggest that during 6.7―3.5 ka BP, the productivity and effective precipitation were greatly improved in the lake drainage area, and this would probably strengthen the hydrodynamic conditions, enhancing organic matter, pollen and carbonate inputs from terrestrial sources. Such processes would account for the enrichment of both organic matter and carbonate in the sediments. While during 9.0―6.7 ka BP, the lower level of or- ganic matter, pollen flux but high carbonate content show depressed productivity and declined vege- tation coverage. The higher carbonate content at this stage would have probably resulted from the higher evaporation ratio of the lake water under relatively drier climate conditions. Therefore, it is in- ferred that during 6.7―3.5 ka BP, the climate was more humid with abundant rainfalls and vegetation was more flourishing in the Lake Daihai area. This can be seen as Holocene Climate Optimum (HCO). As a result, this has evident discrepancies with the traditional notion that the HCO occurs at Early Holocene or early Mid

关键词： Lake Daihai, Mid-Holocene, lacustrine sediments, environmental characteristics.

Pollution characteristics of atmospheric fine particles and their secondary components in the atmosphere of Shenzhen in summer and in winter

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Science china Chemistry 2006年第5期49卷 466-474页

作者： NIU Yuwen1,2.HE Lingyan1,2.HU Min2.ZHANG Jing2.& ZHAO Yunliang2.1. Shenzhen graduate school of Peking University,Shenzhen 518055,{2. 2. State Joint Key Laboratory of Environmental Simulation and Pollution Control,College of Environmental Sciences,Peking University,beijing 100871,{2. 1. Shenzhen graduate school of Peking University Shenzhen 518055 China 2. State Joint Key Laboratory of Environmental Simulation and Pollution Control College of Environmental Sciences Peking University Beijing 100871 China

Two field measurements for atmospheric fine particles were conducted in Baoan district of Shenzhen during the summer and winter in 2.04. Totally 30 sets of 2. h samples were collected, and then the mass concentrations and chemical compositions were determined. The seasonal varia- tions and secondary pollution characteristics of fine particles during the sampling periods were dis-cussed with meteorological factors. The results show that seasonal variations of atmospheric particles are significant in Shenzhen. The average mass concentrations of PM2.5 and PM10 in summer were 35 μg·m-3 and 57 μg·m-3, respectively, and those in winter were 99 μg·m-3 and 135 μg·m-3, respec-tively. The concentrations of both PM2.5 and PM10 in winter increased 184% and 137%, respectively, compared to those in summer. PM2.5 accounted for 61% and 75% of PM10 in summer and in winter, respectively, indicating severe fine particle pollution in Shenzhen. During the summer and winter sampling periods, the mean OC/EC ratios were 3.4 and 1.6, respectively. The estimated secondary organic carbon (SOC) averagely accounted for 56% and 6% of the total OC in summer and in winter, respectively, which implies a major contribution of SOC to OC in summer. During the continuous high temperature period in summer, both the concentrations and fractions of secondary aerosol compo-nents in PM2.5 were highly elevated, suggesting severe secondary pollution again. The prevailing wind was from South china Sea in summer, and the air quality was good. The prevailing wind in winter was from china's Mainland to the north, and the polluted air mass led to poor air quality.

关键词： PM2.5, mass concentration, secondary pollution, seasonal variation, Shenzhen.

Plus cupping degrees do not form an ideal

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Science in china(Series F) 2004年第5期47卷 635-654页

作者： LI Angsheng1,2.& ZHAO Yicheng1 1. Institute of Software,Chinese Academy of Sciences,beijing 100080,china 2. {2. of Information Sciences,beijing Normal University,beijing 100871,china 1. Institute of Software Chinese Academy of Sciences 100080 Beijing China 2. school of Information Sciences Beijing Normal University 100871 Beijing China

A computably enumerable (c.e.,for short)degree a is called plus cupping,if every c.e. degree x with 0 详细信息

A computably enumerable (c.e.,for short)degree a is called plus cupping,if every c.e. degree x with 0

关键词： computably enumerable set Turing degree definability.

Evaluation of the Interfacial Adhesion between Brittle Coating and Ductile Substrate by Cross-Sectional Indention

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材料热处理学报 2004年第5B期25卷 1187-1190页

作者： SUJian-yu ZHANGKun CHENGuang-nan InstituteofMechanics ChineseAcademyofSciencesBeijingChina／／GraduateSchooloftheChineseAcademyofSciencesBeijingChina InstituteofMechanics ChineseAcademyofSciencesBeijingChina

The cross-sectional indentation method is extended to evaluate the interfacial adhesion between brittle coating and ductile substrate. The experimental results on electroplated chromium coating/steel substrate show that the interfacial separation occurs due to the edge chipping of brittle coating. The corresponding models are established to elucidate interfacial separation processes. This work further highlights the advantages and potential of this novel indentation method.

关键词：分界面附着刻痕可锻衬底应力涂层铬钢