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Science china chemistry 2006年第4期49卷 338-344页

作者： TAO Ruojie1, LI Fu’an1, ZANG Shuangquan1, CHENG Yanxiang2.& NIU Jingyang1 1. chemistry and Chemical Engineering College of Henan University, Kaifeng 475001, china 2. {2. institute of applied chemistry, chinese academy of sciences, changchun 13.02., china chemistry and Chemical Engineering College of Henan University Kaifeng China changchun institute of {2. chemistry Chinese Academy of Sciences Changchun China

Copper-zinc heterometallic 1D chain coordination polymer has been synthesized and characterized by elemental analysis, and IR spectra etc. The crystal structure was determined by single-crystal X-ray diffraction analyses. The title complex is 1D chain coordination polymer with the chemical formula {[CuLZn·CuLZn(H2.)]·H2.}n, where H4L=N-(2.hydroxybenzamido)-N’-(3-carboxy- lsalicylidene)ethylenediamine. Its structural unit is comprosed of two tetranuclear cycles formed by two dissymmetrical tetranuclear units. These units polymerized each other to form 1D chain coordi- nation polymer.

关键词： copper, zinc, heterometallic coordination polymer, crystal structure.

Meet Our New Associate Editors

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chinese Journal of chemistry 2024年第11期42卷 1319-1321页

作者： Editorial Office of chinese Journal of chemistry 不详

Associate Editor Dehui Deng Professor The State Key Laboratory of Catalysis Dalian institute of Chemical Physics,chinese {2. of sciences,china(+86)0411-82.63870,dhdeng@***,https:/***/.Education:2.03-2.07 B.S.,Light Industry Engineering and National Economy Management,Sichuan University.2.07-2.13 Ph.D.,Physical chemistry,Dalian institute of Chemical Physics,chinese {2. of sciences(Supervisor:*** Bao and *** Pan).

关键词： Dalian Economy Associate

Magnetic properties of Jiaxian red clay sequences from northern chinese Loess Plateau and its paleoclimatic significance

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Science china Earth sciences 2005年第8期48卷 1234-1245页

作者： QIANG Xiaoke, AN Zhisheng, LI Huamei, CHANG Hong & SONG Yougui 1. SKLLQG, institute of Earth Environment, chinese academy of sciences, Xi’an 710075,{2. 2. Guangzhou institute of Geochemistry, chinese academy of sciences, Guangzhou 510640,{2. chinese academy of {2. SKLLQG Institute of Earth Environment Xi’an China chinese academy of {2. Guangzhou Institute of Geochemistry Guangzhou China

Detailed rock magnetism investigation of the Jiaxian red clay sequences indicated that there are common magnetic mineralogy properties in red clay and loess-paleosol sequences from the chinese Loess Plateau as well as the marked properties of themselves, magnetic min-erals mainly with magnetite, maghemite, hematite, and possibly limonite/goethite contributing to the magnetic behavior. Meanwhile, it is found that the strong paleosol in red clay sequences has a lower coercivity and higher content of ultra-fine ferrimagnetic grains than that of the weak pa-leosol, which is similar to loess and paleosol in upper Wucheng Loess sequences, and indicates that humid conditions and relatively strong pedogenesis play a significant role in the increase of ultra-fine magnetic minerals and transformation of the magnetic minerals. This suggests that, like Quaternary loess-paleosols, the change of characteristics of paleoclimatic conditions of the late Tertiary red clay deposits is fluctuant. In addition, the results of magnetic hysteresis properties show that the applied saturated field for samples from the Jiaxian red clay sequences is higher than that of the samples from eastern and southern chinese Loess Plateau. It is obviously shown that there exist more hard magnetic minerals and relatively weak biochemical processes in the Jiaxian red clay sequences on northern chinese Loess Plateau. We conclude that the paleocli-matic environment is different between northern and eastern/southern chinese Loess Plateau, and it should be more arid in northern chinese Loess Plateau.

关键词： northern chinese Loess Plateau, red clay, magnetic property, paleoclimatic significance.

Wet-chemical synthesis and characteristics of Au nanoshell

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Science china chemistry 2005年第5期48卷 431-435页

作者： LIU Zhongxin1,2. SONG Hongwei1, YU Lixin1,2. YANG Linmei1,2.& PAN Guohui1,2.1. Key Laboratory of Excited State Physics, changchun institute of Optics, Fine Mechanics and Physics,{2., changchun 130033, china 2. Graduate School of the{2., Beijing 100039, china Key Laboratory of Excited State Physics Changchun Institute of Optics Fine Mechanics and Physics Chinese Academy of Sciences Changchun China Graduate School of the chinese academy of sciences Beijing China

Gold nanoshells were prepared by an easy wet-chemical method, with Ag nanoparticles used as the templates. Transmission electron microscopy (TEM) indicated that the shells were sphere in shape, the size was homogenous, being about 2. nm, and no hard ag-glomerates were observed. The plasma resonance absorption of gold was tuned from visible to near-infrared (NIR) with the increased volume of HAuCl4. The temperature grads (?T) of the gold nanoshell hydrosol under the exposure of an 808-nm optical fiber laser with different power den-sities were measured. The highest ?T was 30℃ (5 W/cm2. irradiation area was 2.cm2.. This kind of gold nanoshell hydrosol is a promising material to be used in biomedicine such as photo-thermal cancer therapy, and its special photothermal convert property will photothermally trigger drug release.

关键词： wet-chemical synthesis, Au, nanoshell, NIR absorption, photothermal conversion.

Principles and methods of quantitative analysis on b-axis disorder in 2.: 1 dioctahedral phyllosilicate

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chinese Science Bulletin 1997年第22期42卷 1908-1912页

作者： WANG Ling and ZHANG Zhenyu1. Changsha institute of Geotectonics, chinese academy of sciences, Changsha 410013,{2. 2. institute of Geology, chinese academy of sciences, Beijing 10002.,{2. Changsha institute of Geotectonics Chinese Academy of Sciences Changsha China institute of Geology Chinese Academy of Sciences Beijing China

IN XRD patterns of clay minerals, a phenomenon that strong peaks often have (00l) and(hkl) (k=3n) indices and show symmetric figures can be seen commonly, while a minorityof reflection peaks (hkl) (k≠3n) are comparat... 详细信息

关键词： b-axis disorder pyrophvllile 2 phyllosilicate clay minerals dioctahedral minerals orientating structure of hy-droxyls crystal structure analysis DTA-TG.

Kumada chain-growth polycondensation as a universal method for synthesis of well-defined conjugated polymers

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Science china chemistry 2010年第8期53卷 1620-1633页

作者： GENG YanHou1,HUANG Li1,2.WU ShuPeng1,2.& WANG FoSong1 1State Key Laboratory of Polymer Physics and chemistry changchun {2. of applied chemistry,chinese academy of sciences,changchun 13.02.,china 2.raduate University of chinese academy of sciences,Beijing 100049,china State Key Laboratory of Polymer Physics and chemistry changchun institute of {2. chemistry Chinese Academy of Sciences Changchun China Graduate University of chinese academy of sciences Beijing China

Kumada chain-growth polycondensation (KCGP) is a novel method for the synthesis of well-defined conjugated *** the Ni-catalyst can transfer in an intramolecular process to the propagating chain end,the polymerization follows chain-growth *** this newly developed method,various conjugated polymers,such as polythiophenes,poly(p-phenylene) (PPP),polypyrrole (PPy),and polyfluorene with controlled molecular weights and relatively narrow polydispersities (PDIs),have been ***,the polymerizations for poly(3-alkylthiophene)s (P3ATs),PPP,and PPy exhibited quasi-living characteristics,which allows preparing polymer brushes,fully-conjugated block copolymers,and macroinitiators and macro-reactants for the synthesis of rod-coil block *** the current review,the progress in this new area is summarized.

关键词： chain growth polycondensation conjugated polymers Kumada reaction block copolymers polymer brush

On some tests-based projection pursuit for elliptical symmetry of a high-dimensional distribution

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chinese Science Bulletin 1998年第6期43卷 450-458页

作者： JING Ping 1 and ZHU Lixing 2.1. Mathematics Lab, china University of Mining & Technology, Beijing 100083, china 2. Probability Lab, {2. of applied Mathematics, chinese academy of sciences, Beijing 100080, china Mathematics Lab China University of Mining & Technology Beijing China Probability Lab Institute of Applied Mathematics Chinese Academy of Sciences Beijing China

Some test statistics of Kolmogorov type and Cramér-von Mises type based on projection pursuit technique are proposed for the testing problem of sphericity of a high-dimensional distribution. The limiting distributions of the test statistics are derived under the null hypothesis and under any fixed alternative. The asymptotic properties of bootstrap approximation are investigated. Furthermore, for computational reasons, an approximation for the statistics, based on the number theoretic method, is suggested.

关键词： bootstrap approximation projection pursuit type statistic elliptical symmetry.

Parentage determination of an isolated Yangtze finless porpoise population Neophocaena phocaenoides asiaeorientalis in the Yangtze Tian-e-Zhou Baiji National Natural Reserve based on molecular data

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Progress in Natural Science:Materials International 2005年第2期15卷 54-61页

作者： XIA Junhong 1,2. ZHENG Jinsong 1,2. XU Limei 1,2.and WANG Ding1*(1. institute of Hydrobiology, chinese academy of sciences, Wuhan 430072.{2. 2. Graduate School of the chinese academy of sciences, Beijing 100039,{2.) Inst. of Hydrobiology Chinese Acad. of Sciences Wuhan 430072 China Graduate Sch. Chinese Acad. of Sciences Beijing 100039 China

Reproductive behaviors are poorly known for the Yangtze finless porpoise Neophocaena phocaenoides asiaeorientalis. In this study, the parentage of an isolated Yangtze finless porpoise population inhabiting the Yangtze Tian-e-Zhou Baiji National Natural Reserve is determined by analysis of microsatellite loci and mitochondrial DNA (mtDNA) control region sequences, and the porpoise's reproductive behaviors are studied. Overall 4 full parentage assignments and additional 3 single parentage assignments were determined for the population of 2. individuals. The analysis shows that their estimated reproductive cycle is shorter than that reported previously and there probably exists an overlapping between gestation and lactation period. The study also shows that the female does not show fidelity to a particular male for breeding and vice versa, the oldest males did not monopolize mating and the dominance rank could not be so strict for the porpoise society. Moreover, the porpoise's mating pattern and relatedness among candidate parents are discussed here. These results provide important information for making guidelines of management and conservation for this protected population.

关键词： Yangtze finless porpoise isolated population reproductive behavior parentage

MELTING CRYSTALLIZATION BEHAVIOR OF NYLON 66

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chinese Journal of Polymer Science 2001年第3期19卷 237-246页

作者： Qing-xin Zhang Zhi-shen Mo State Key Laboratory of Polymer Physics & chemistry changchun {2. of applied chemistry chinese academy of sciences, changchun 13.02., china 中科院长春应用化学所高分子物理与化学国家重点实验室吉林长春

Analysis of isothermal and nonisothermal crystallization kinetics of nylon 66 was carried out using differential scanning calorimetry (DSC). The commonly used Avrami equation and that modified by Jeziorny were used, respectively, to fit the primary stage of isothermal and nonisothermal crystallizations of nylon 66. In the isothermal crystallization process, mechanisms of spherulitic nucleation and growth were discussed. The lateral and folding surface free energies determined from the Lauritzen-Hoffman treatment are sigma = 9.77 erg/cm(2. and sigma (e) = 155.48 erg/cm(2., respectively; and the work of chain folding is q = 33.14 kJ/mol. The nonisothermal crystallization kinetics of nylon 66 was analyzed by using the Mo method combined with the Avrami and Ozawa equations. The average Avrami exponent (n) over bar was determined to be 3.45. The activation energies (DeltaE) were determined to be -485.45 kJ/mol and -331.2. kJ/mol, respectively, for the isothermal and nonisothermal crystallization processes by the Arrhenius and the Kissinger methods.

关键词： nylon 66 crystallization kinetics activation energy

Some key technics of drop tower experiment device of National Microgravity Laboratory (china) (NMLC)

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Science china(Technological sciences) 2005年第3期48卷 305-316页

作者： ZHANG Xiaoqian 1 , YUAN Longgen 1 , WU Wendong 1 , TIAN Lanqiao 2.& YAO Kangzhuang 2.1. institute of Engineering Thermophysics, chinese academy of sciences, Beijing 100080,{2. 2. institute of Mechanics, chinese academy of sciences, Beijing 100080,{2. institute of Engineering Thermophysics Chinese Academy of Sciences Beijing China institute of Mechanics Chinese Academy of Sciences Beijing China

Drop tower is an important ground based facility for microgravity science experiment. The technical performances of the drop tower NMLC are advanced compared with similar facilities in the US, Germany and Japan. The main components such as drop capsule, deceleration devices, release mechanism present its advantages and creativities.

关键词： drop tower facility,drop capsule,deceleration devices,release mechanism.