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Bio-regeneration of p-complexation desulfurization adsorbents

Science china Chemistry 2005年第6期48卷 538-544页

作者： LI Wangliang1,2. XING Jianmin1, XIONG Xiaochao1,2. SHAN Guobin1,2.& LIU Huizhou1 1. Laboratory of Separation Science and Engineering, Institute of Process Engineering, {3. academy of {2., beijing 100080, china 2. Graduate school of the {3. academy of {2.,beijing 10003., china Laboratory of Separation Science and Engineering Institute of Process Engineering Chinese Academy of Sciences Beijing China Graduate school of the chinese {2. of {3. Beijing China

The coupling of adsorption desulfurization and biodesulfurization is a new approach to produce clean fuels. Sulfur compounds are firstly adsorbed on adsorbents, and then the ad-sorbents are regenerated by microbial conversion. p-Complexation adsorbent, Cu(I)-Y, was ob-tained by ion exchanging Y-type zeolite with Cu2. and then by auto-reduction in helium at 450℃ for 3.h. Dibenzothiophene (DBT) was used as a model compound. The effects of cell concentra-tion, volume of oil phase, the ratio of aqueous phase to adsorbent on DBT desorption by a bac-terium were studied. The amounts of DBT desorbed and 2.HBP produced can be apparently increased with addition of n-octane. BDS activity can be improved by increasing cell concentra-tion and the ratio of water-to-adsorbent. 89% of DBT desorbed from the adsorbents can be converted to 2.HBP within 6 h and almost 100% within 2. h, when the volume ratio of oil-to-water was 1/5 mL/mL, the cell concentration was 60 g·L?1, and the ratio of adsorbent-to-oil was 0.03.g·mL?1. The amount of 2.HBP produced was strongly dependent on the volume ratio of oil-to- water, cell concentration and amount of adsorbent. Adsorption capacity of the regenerated ad-sorbent is 95% that of the fresh one after being desorbed with Pseudomonas delafieldii R-8, washed with n-octane, dried at 100℃ for 2. h and auto-reduced in He.

关键词： adsorption desulfurization p-complexation adsorbents bio-regeneration Pseudomonas delafieldii desorption.

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The deep thermal characteristic of continental margin of the northern South china Sea

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chinese Science Bulletin 2000年第18期45卷 1717-1722页

作者： ZHANG Jian & WANG Jiyang1. Graduate school, University of Science and Technology of china, {2. {3. of sciences, beijing 10003., china 2. Institute of Geology, {2. {3. of sciences, beijing 10002., china Graduate school University of Science and Technology of China Chinese Academy of Sciences Beijing China Institute of Geology Chinese Academy of Sciences Beijing China

Heat flow plays an important role in the study ot thermal structure and thermal evolutionof continental margin of the northern South china Sea. The analysis of heat flow value shows that margin heat flow in the northern South china Sea is relatively high setting, but the percentage of crustal heat flow is lower than 3.% in terrestrial heat flow. The terrestrial heat flow exhibited a current of rise from the Northern Continental Margin to the Southern Central Basin. However, the proportion of crustal heat flow in terrestrial heat flow slowly dropped down in the same direction. It is suggested that the main factor causing high heat flow setting is the moving up of hot material from asthenosphere.

关键词： margin of northern South china Sea terrestrial heat flow thermal structures.

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Sequence analysis of mRNA polyadenylation signals of rice genes

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chinese Science Bulletin 2006年第9期51卷 1069-1077页

作者： LU Ying1, 2. GAO Chenxi1,2.3.& HAN Bin1,3.41. National Center for Gene Research, Shanghai Institutes for Biological sciences, {3. {2. of sciences, Shanghai 2.02.3. china 2. Graduate school of the {3. {2. of sciences, beijing 10003., china 3. Institute of Plant Physiology and Ecology, Shanghai Institutes for Biological sciences, {3. {2. of sciences, Shanghai 2.003.0} china National Center for Gene Research Shanghai Institutes for Biological Sciences Chinese Academy of Sciences Shanghai China Graduate school of the chinese {2. of {3. Beijing China Institute of Plant Physiology and Ecology Shanghai Institutes for Biological Sciences Chinese Academy of Sciences Shanghai China

The formation of eukaryotic mRNAs involves the cleavage and polyadenylation of pre- mRNAs. To investigate the sequence requirement of putative polyadenylation signals (PASs), poly(A) sites and downstream elements (DUEs) in 3.-end-pro- cessing in rice, we compared expressed sequences tags (ESTs) with poly(A) extremity to full-length cDNA sequences and constructed a database of 12.69 pre- mRNA sequences in ?40―+40 nt surrounding the poly(A) sites, which were from 9953.genes. The al- ternative poly(A) sites were revealed in approxi- mately 2.% of mRNAs. Nearly 80% of pre-mRNAs showed stringent requirement of the YA (CA or UA) at poly (A) sites for polyadenylation. About 7.9% had the AAUAAA signals on ?40―?1 nt upstream of the poly(A) sites. Over 60% of mRNAs probably used the one- or two-base variants of AAUAAA hexamers as their PASs in 3. fragments. The single-base variants of AAUGAA revealed the high frequency in 11.5% of 3. fragments. The DUEs were detected in 90% of pre- mRNAs, especially more than half of the pre-mRNAs with multi-base variants of AAUAAA had the DUEs surrounding the poly(A) site. The location of DUE is also important for defining the cleavage site. Al- though most of the rice pre-mRNAs did not contain AAUAAA signal, the existence of downstream ele- ments ensured the efficiency of cleavage-polyade-

关键词：多聚腺苷酸序列分析 mRNA 水稻基因工程

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Simulations for terrestrial planets formation

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Science china(Physics,Mechanics & Astronomy) 2009年第5期52卷 794-803页

作者： ZHANG Niu 1,2.&JI JiangHui 2.3.1Graduate University of chinese {3. of {2.,beijing 100049,china 2.urple Mountain Observatory,chinese {3. of {2.,Nanjing 2.0008,china 3.National Astronomical Observatories,chinese {3. of {2.,beijing 100012.china Graduate University of chinese academy of {2. Beijing China Purple Mountain Observatory Chinese Academy of Sciences Nanjing China National Astronomical Observatories Chinese Academy of Sciences Beijing China

In this paper,the formation of terrestrial planets in the late stage of planetary formation is investigated using the two-planet *** that time,the protostar formed for about 3.Ma and the gas disk *** the model,the perturbations from Jupiter and Saturn are *** of the mass of outer planet,and the initial eccentricities and inclinations of embryos and planetesimals are also *** results show that,terrestrial planets are formed in 50 Ma,and the accretion rate is about 60%-80%.In each simulation,3.4 terrestrial planets are formed inside"Jupiter"with masses of 0.15 -3.6M⊕.In the 0.5-4 AU,when the eccentricities of planetesimals are excited,planetesimals are able to accrete material from wide radial *** plenty of water material of the terrestrial planet in the Habitable Zone may be transferred from the farther places by this *** could also happen a few times between two major planets only if the outer planet has a moderate mass and the small terrestrial planet could survive at some resonances over time scale of 10 8 *** one of our simulations,commensurability of the orbital periods of planets is very ***,a librating-circulating 3.2.configuration of mean motion resonance is found.

关键词： astrophysics exoplanet planetary formation n-body simulation

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Modeling of elastic wave propagation on a curved free surface using an improved finite-difference algorithm

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Science china(Physics,Mechanics & Astronomy) 2004年第5期47卷 633-648页

作者： WANG Xiuming1,3.& ZHANG Hailan2.1. CSIRO Petroleum, ARRC, PO BOX 113., Technology Park, Bentley, WA 6102. Australia 2. Institute of Acoustics, {3. academy of {2., beijing 100080, china 3. Present address: Institute of Acoustics, {3. academy of {2., beijing 100080, china CSIRO Petroleum ARRC Bentley Australia Institute of Acoustics Chinese Academy of Sciences Beijing China

Based on existing direct and imaging methods of a staggered finite-difference scheme, an improved algorithm for staggered finite-difference is proposed to implement rugged topographic free boundary conditions. This method assumes that the free surface can be implemented with horizontal and vertical free surface segments and their corners; the free surface passes through the grid points of shear stress components, instead of the normal stress components. Imaging is carried out for stress components in both horizontal and vertical directions, thus increasing the accuracy. To update particle- velocities, imaging and updating are first performed in the horizontal direction, and then in the vertical direction. The numerical results for elastic flat horizontal free surface with the imaging method and those for flat free surfaces of various slope angles with the proposed method are compared, and are shown to be in good agreement. The advantage of the proposed method is that only the stresses are dealt with in implementing the free surface into the staggered algorithm, which improves computation efficiency.

关键词： elastic wave simulation, curved free surface, staggered finite-difference, algorithm stability.

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Spatial heterogeneity of the driving forces of cropland change in china

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Science china Earth sciences 2005年第12期48卷 2231-2240页

作者： LIU Xuhua1,2. WANG Jinfeng1, LIU Mingliang4,1 & MENG Bin1,2.3.1. Institute of Geographic sciences and Natural Resources Research, {3. {2. of sciences, beijing 100101, china 2. Graduate school of the {3. {2. of sciences,{13., china 3. College of Arts and sciences of beijing Union University, beijing 100083. china 4. school of Forestry and Wildlife sciences, Auburn University, Auburn, Alabama, AL3.849, USA Institute of Geographic sciences and Natural Resources Research Chinese Academy of Sciences Beijing China Graduate school of the chinese {2. of {3. Beijing China school of Forestry and Wildlife sciences Auburn University Auburn Alabama USA College of Arts and sciences of beijing Union University Beijing China

By using digital satellite remote sensing data acquired in 1987―1989 and 1999―2.00 and GIS combined with the natural and socio-economic data, this paper drew an integrated zonation of the cropland change and its driving forces in china. The results indicated that the cropland change in the study period was constrained by geographical factors and driven by cli-mate change as well as socio-economic system. Moreover, the regional differences of the drivers for cropland change were significant. In the midwest of china, natural condition changes and geographical background were the main constraints and drivers, while in Eastern china, social and economic changes and economic policies were the main driving forces. The cropland loss was nationwide. The dominant factors to cause this decrease included buildup of developing area to attract foreign capital and technologies, changes of industry structure due to urban in-fluence, the change of employment notions thanks to living standard improvement, rapid ur-banization due to the expansion of cities and towns, the diminished farming net income partly because of the global warming effects, and the rapid economic growth stimulated by the con-venient transportation system. These factors interact and interdepend with each other to cause the cropland loss in china recently. The reasons for the increase of cropland were primarily the cultivation and deforestation by the farmers who want to increase income. This study on the mechnism of LUCC relied on the cropland change integrated classification considering the natural or human factors both inside and outside the region, which provides a new approach to study the integrated regionalization and LUCC mechanism.

关键词： land use change, driving force, integrated classification, spatial statistics, cropland, china.

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Mechanism and Defense on Malicious Code

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Wuhan University Journal of Natural sciences 2005年第1期10卷 83-88页

作者： WEN Wei-ping 1,2.3. QING Si-han 1,2.3.1. Institute of Software, the chinese {3. of {2., beijing 100080, china 2.Engineering Research Center for Information Security Technology, the chinese {3. of {2., beijing 100080, china 3.Graduate {13. of the chinese {3. of {2., beijing 100080, china Institute of Software the Chinese Academy of Sciences Beijing China Engineering Research Center for Information Security Technology the Chinese Academy of Sciences Beijing China Graduate school of the chinese {2. of {3. Beijing China

With the explosive growth of network applications, the threat of the malicious code against network security becomes increasingly serious. In this paper we explore the mechanism of the malicious code by giving an attack model of the malicious code, and discuss the critical techniques of implementation and prevention against the malicious code. The remaining problems and emerging trends in this area are also addressed in the paper.

关键词： malicious code attacking model mechanism defense system security network security

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Explicit analytical solutions of the anisotropic Brinkman model for the natural convection in porous media(Ⅱ)

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Science china(Physics,Mechanics & Astronomy) 2005年第4期48卷 422-430页

作者： CAI Ruixian1, GOU Chenhua1, 2.& ZHANG Na1 1. Institute of Engineering Thermophysics, chinese academy of {2., beijing 100080, china 2. Graduate school, chinese academy of {2., beijing 100080, china Institute of Engineering Thermophysics Chinese Academy of Sciences Beijing China Graduate school Chinese Academy of Sciences Beijing China

Some algebraically explicit analytical solutions are derived for the anisotropic Brinkman model―an improved Darcy model―describing the natural convection in porous media. Besides their important theoretical meaning (for example, in analyzing the non-Darcy and anisotropic effects on the convection), such analytical solutions can be the benchmark solutions that can promote the development of computational heat and mass transfer. Some solutions considering the anisotropic effect of permeability have been given previously by the authors, and this paper gives solutions including the anisotropic effect of thermal conductivity and the effect of heat sources.

关键词： explicit analytical solution, porous medium, natural convection, Brinkman model, anisotropic.

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Structures and physical properties of rigid polyurethane foams with water as the sole blowing agent

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Science china Chemistry 2006年第4期49卷 363-370页

作者： LI Xiaobin1,2. CAO Hongbin1 & ZHANG Yi1 1. Institute of Process Engineering, chinese academy of {2., beijing 100080, china 2. Graduate school of the chinese academy of {2., beijing 10003., china Institute of Process Engineering Chinese Academy of Sciences Beijing China Graduate school of the chinese {2. of {3. Beijing China

Rigid polyurethane foams blown by varying water level were prepared in this study. The structures and physical properties of rigid polyurethane foams blown by water were measured with FT-IR, universal testing machine (Instron3.65), scanning electron microscope (SEM) and differential scanning calorimeter (DSC). The results show that polyurea and polybiuret were the typical charac- teristics, and the cream time and gel time were shorter for the fully water blown rigid foams than that for the fully cyclopentane blown foams. The density of foam samples decreased from 45.0 kg/m3.to 2..4 kg/m3.with the increase of water level from 3.pph to 7 pph. Compressive strength exhibited the similar behavior with density. The average cell size of foam samples ranged from 2.1 μm to 3.6 μm with the increase of water level from 3.pph to 7 pph, respectively. At the same time, poorer dimen- sional stability was encountered with the increase of average cell size due to fast diffusion rate of CO2.out of the foam. The results of thermal analysis show that the glass transition temperature (Tg) shifted to a higher temperature with the increase of isocyanate level when more water was used as chemical blowing agent.

关键词： polyether polyol, polyurethane rigid foam, compressive strength, dimensional stability, cell size, glass transition temperature.

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The biomarkers of 2.6,10,15, 19-pentamethylicosenes and their carbon isotopic composition in the sediments from the Gulf of Mexico

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chinese Science Bulletin 2006年第14期51卷 1736-1740页

作者： SONG Zhiguang1,2.& WANG Cuiping1,3.. State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, chinese academy of {2., Guangzhou 510640, china 2. Guangzhou Research Center of Gas Hydrate, chinese academy of {2., Guangzhou 510640, china 3. Graduate school of chinese academy of {2.,{12., china State Key Laboratory of Organic Geochemistry Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou China Guangzhou Research Center of Gas Hydrate Chinese Academy of Sciences Guangzhou China Graduate school of chinese {2. of {3. Beijing China

A group of 2.6,10,15,19-pentamethyli- cosenes (PMIΔ) containing 1―5 unsaturated double bonds has been identified in the sea floor sediments from the Gulf of Mexico at the Green Canyon 2.8 *** PMIΔ compounds are distributed between nC2. and nC2. on the mass chromatogram of aliphatic fraction. Their δ 13. values are very much depleted in 13. and in the range of ?86.7‰ to ?115.5‰, whereas the δ 13. values of companion n-alkanes range from ?2..4‰ to ?3..6‰. These unsaturated PMIΔ com-pounds are typical biomarkers derived from the an-aerobic oxidation of methane mediated by meth-ane-oxidizing archaeal bacteria and indicative of the gas seeps or even the occurrence of gas hydrates in the deep sea sediments.

关键词：生物标志墨西哥湾沉积物 PMIA 天然气水化物

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