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Process optimization of reaction of acid leaching residue of asbestos tailing and sodium hydroxide aqueous solution

Science china(Technological Sciences) 2009年第1期52卷 204-209页

作者： DU GaoXiang1,3, ZHENG ShuiLin2 & DING Hao1 1 school of Materials Science and technology, china university of Geosciences (beijing), beijing, 100083. china 2 school of chemical and environment engineering, china university of mining and technology (beijing), beijing 100083. china 3 Hebei Qinghe Refractory Group Co. Ltd., Xingtai 054804, china 1. school of Materials Science and technology China University of Geosciences (Beijing) Beijing 100083 China 3. Hebei Qinghe Refractory Group Co. Ltd. Xingtai 054804 China 2. school of chemical and environment engineering China University of Mining and Technology (Beijing) Beijing 100083 China

Silica is the major component of the acid leaching residue of asbestos tailing. The waterglass solution can be prepared by the reaction of the residue with sodium hydroxide aqueous solution. Compared to the high temperature reaction method, this process is environmental friendly and low cost. In this paper, the reaction process of the residue and the sodium hydroxide aqueous solution is optimized. The optimum reaction process parameters are as follows: the usage of sodium hydroxide is 26.4 g/100 g acid leaching residue, the reaction temperature is 90℃, the reaction time is 1 h, and the ratio of the liquid/solid is 2.0. The significance sequence of the process parameters to the alkali leaching reaction effect is the usage of sodium hydroxide > the ratio of the liquid/solid > the reaction time > the reaction temperature. The significance sequence to the leaching ratio of SiO2 is the ratio of the liquid/solid > the usage of sodium hydroxide > the reaction time > the reaction temperature. The significance sequence to the modulus of the sodium silicate is the ratio of the liquid/solid > the usage of sodium hydroxide > the reaction time > the reaction temperature. Under the optimum conditions, the leaching ratio of the SiO2 is 77.5%, and the modulus of the sodium silicate is 3.15. The XRD analysis result indicates that the major components of the alkali leaching residue are serpentine, talc, quartz and some albite.

关键词： asbestos tailing acid leaching residue sodium hydroxide process optimization

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Effect of activation agents on the surface chemical properties and desulphurization performance of activated carbon

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Science china(Technological Sciences) 2010年第9期53卷 2515-2520页

作者： ZHANG XiangLan,ZHANG Yan,WANG ShuangSheng,ZHANG JingJing & ZHOU Wei school of chemical and environmental engineering,china university of mining and technology (beijing),beijing 100083.china 1. school of chemical and environmental engineering China University of Mining and Technology (Beijing) Beijing 100083 China

Flue gas pollution is a serious environmental problem that needs to be solved for the sustainable development of *** surface chemical properties of carbon have great influence on its desulphurization performance.A series of activated carbons (ACs) were prepared using HNO3,H2O2,NH3·H2O and steam as activation agents with the aim to introduce functional groups to carbon surface in the ACs preparation *** ACs were physically and chemically characterized by iodine and SO2 adsorption,ultimate analysis,Boehm titration,and temperature-programmed reduction (TPR).Results showed that the iodine number and desulphurization capacity of NH3·H2O activated carbon (AC-NH3) increase with both activation time,and its desulphurization capacity also increases with the concentration of activation ***,HNO3 activated carbon (AC-HNO3) and H2O2 activated carbon (AC-H2O2) exhibit more complex *** their iodine numbers increase monotonously with activation *** with steam activated AC (AC-H2O),the nitrogen content increases 0.232% in AC-NH3 and 0.077% in *** amount of total basic site on AC-HNO3 is 0.19 mmol·g-1 higher than that on AC-H2O.H2O2 activation introduces an additional 0.08 mmol·g-1 carboxyl groups to AC surface than that introduced by steam *** desulphurization capacity of ACs in simulate flue gas desulphurization decreases as follows: AC-NH3 > AC-HNO3 > AC-H2O2 > *** sequence is in accord with the SO2 catalytic oxidation/oxidation ratio in the absence of oxygen and the oxidation property reflected by *** the presence of oxygen,all adsorbed SO2 on ACs can be oxidized into *** desulphurization capacity increases differently according to the activation agents;the desulphurization capacity of AC-NH3 and AC-HNO3 improves by 4.8 times,yet AC-H2O increases only by 2.62 as compared with the desulphurization of corresponding ACs in absence of oxygen.

关键词： activated carbon activation agent surface chemical property desulphurization TPR

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Molecular mechanism of dehydrin in response to environmental stress in plant

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Progress in Natural Science:Materials International 2007年第3期17卷 237-246页

作者： ZHANG Yuxiu , WANG Zi and XU Jin (Department of Bioengineering, school of chemical and environmental engineering, china university of mining and technology (beijing), beijing 100083. china Department of Biology, Graduate university of Chinese Academy of Sciences, beijing 100049, china) [a]Department of Bioengineering School of Chemical and Environmental Engineering China University of Mining and Technology (Beiing) Beijing China [b]Department of Biology Graduate University of Chinese Academy of Sciences Beijing China

Dehydrins, known as the D-11 subgroup of late embryogenesis abundant (LEA) protein, are an immunologically distinct family of proteins, which typically accumulate in desiccation-tolerant seed embryo or in vegetative tissues in response to various environmental stresses such as drought, salinity and freezing. The existence of conservative sequences designated as K, S, and Y segments is a structural feature of dehydrins, and the K segment found in all dehydrins represents a highly conserved 15 amino acid motif (EKKGIMDKIKEKLPG) and forms an amphiphilicα-helix. According to the arrangement of these domains and clustering analysis, dehydrins are subdivided into 5 subtypes: YnSK, Kn, KnS, SKn and YnK. Different types of dehydrins are induced by different environmental stress in plants. Study results showed that dehydrins might play important protective roles under abiotic stress via a number of different mechanisms, including improving or protecting enzyme activities by the cryoprotective activity in responding to freeze/thaw or dehydration; stabilizing vesicles or other endomembrane structures by function as the membrane stabilizer during freeze induced dehydration, and preventing the membrane system from the oxidative damage induced by reactive oxygen radicals as the radical scavenger. Here, the gene expression and molecular mechanisms of dehydrin in response to stress in plants are discussed.

关键词： dehydrin stress mechanism.

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Preparation, characterization and salt-resistance of a coal based super absorbent composite

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mining Science and technology 2010年第6期20卷 864-871页

作者： CHU Mo, HUANG Zhanbin, XU Bang, FANG Tao, DUAN Hui school of chemical and environmental engineering, china university of mining & technology, beijing 100083. china [a] school of chemical environmental engineering China University of Mining & Technology Beijing 100083 China

Potassium humate was extracted from brown coal. A novel super absorbent composite, poly （acrylic acid-co-acryla- mide）/potassium humate （PAA-AM/KHA）, was prepared by graft polymerization of acrylic acid, acrylamide and coal based potassium humate using N, N＇-methylenebisacrylamide as a crosslinker and potassium peroxydisulfate as an initiator. The effects of reaction temperature, degree of neutralization of the poly （acrylic acid） and the amounts of crosslinker, initiator and potassium humate were investigated. Salt resistance tests were also carded out. The composite prepared under optimal conditions had a potassium bumate content of 10% and exhibited a water absorption of 770 g/g in distilled water, and 349, 286 and 41 gig in 0.5 mol/L KC1, MgC12 and A1CI3 solutions respectively. The results indicate that the salt resistance of PAA-AM/KHA was superior to that of poly （acrylic acid-co-acrylamide） because of the collaborative effect of functional groups of the coal based potassium humate. The PAA-AM/KHA micro powder was characterized by IR spectroscopy and the micrographic surface was characterized by scanning electron microscopy. Introduction of potassium humate into the poly （acrylic acid-co-acrylamide） structure creates a composite more suitable for use as a water-managing material in the renewal of arid and desert environments. The salt resisting property of the composite is improved, production costs are reduced and the growth stimulant effect is still present.

关键词： brown coal coal based potassium humate superabsorbent salt-resistant property

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Future Trends of Deep Sea Bed mining technology

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International Journal of Minerals,Metallurgy and Materials 1999年第1期13卷 4-7页

作者： Yan Feng Haoran Li Wenming Zhang (Resources engineering school, university of Science and technology beijing, beijing 100083. china) Resources engineering school University of Science and Technology Beijing Beijing 100083 China

The present status of deep sea bed mining technology for polymetallic nodules has been critically examined in light of its history of development the UNCLoS (the United Nation Convention on the Law of the Sea) regime and the current trends in *** critical technologies have been highlighted and the need for system integration underscored. The deep sea bed environment and the engineering challenge were presented and the necessary features of the deep sea bed mining system for commercial mining was analyzed. The key accomplishments, problems and future bends in research in the development of the mining system are also discussed. Finally, it points out that the technology gaps can be filled by the bine commercial mining is undertaken as a result of market conditions in its favor.

关键词： deep sea bed mining, UNCLoS TIS (Total Integrated System), polymetallic nodules mining system

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A new method for mining deformation monitoring with GPS-RTK

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中国有色金属学会会刊：英文版 2011年第S3期21卷 659-664页

作者： GAO Jing-xiang1, 2, LIU Chao2, WANG Jian1, 2, LI Zeng-ke2, MENG Xiang-chao2 1. Key Laboratory for Land environment and Disaster Monitoring of State Bureau of Surveying and Mapping, china university of mining and technology, Xuzhou 221116, china 2. school of environment and Spatial Informatics, china university of mining and technology, Xuzhou 221116, china [a] Key Laboratory for Land environment and Disaster Monitoring of State Bureau of Surveying and Mapping China University of Mining and Technology Xuzhou 221116 China [b] school of environment and Spatial Informatics China University of Mining and Technology Xuzhou 221116 China

Based on ranging intersection theory, a new method which is simple and easy to operate was proposed for data collection in the mine surface deformation monitoring with GPS-RTK centering rod measurements. It can fully eliminate the inevitable shaking error and the vertical deflection, and to some extent weaken the multipath effect on the estimates of coordinates in a relatively short period of time, using high-frequency observations. The results show that three-dimensional coordinates with a height accuracy better than 1 cm, horizontal accuracy better than 2-4 cm can be achieved through only 15-30 s continuous observation by 20 Hz high-frequency and effectively improve the measurement accuracy and efficiency of RTK, fully satisfying the high-speed and high-precision data acquisition in mine surface subsidence deformation monitoring.

关键词： GPS rover pole multipath delay deformation monitoring

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Adsorption of oil from waste water by coal:characteristics and mechanism

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mining Science and technology 2010年第5期20卷 778-781页

作者： LI Xiaobing,ZHANG Chunjuan,LIU Jiongtian school of chemical engineering and technology,china university of mining & technology,Xuzhou 221116,china [a] school of chemical engineering technology China University of Mining&Technology Xuzhou 221116 China

The work described here was focused on exploring the potential application of coal to purification of oily waste *** was added to oily waste water as an adsorbent and then removed through a flotation *** allowed economical and highly efficient separation of oil from the waste *** absorption time,coal type,coal particle size distribution,pH value and oil concentration were *** results indicate that oil absorption by a coal increases for a period of 1.5 h and then gradually tends toward an equilibrium *** appears that the absorption capacity of anthracite is more than that of lean coal or lignite,given the same coal particle size *** absorption capacity of a coarse coal fraction is less than that of finer coal,given the same of coal *** absorption capacity of anthracite decreases slightly as the pH increases from 4 to *** adsorption of oil on anthracite follows the Freundlich isothermal adsorption law:given initial oil concentrations of 160.5 or 1023.6 mg/L the absorption capacity was 23.8 or 840.0 mg/*** absorption mechanism consists of two kinds of absorption,a physical process assisted by a chemical one.

关键词： oily wastewater waste water separation coal oil adsorption mechanism

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An efficient chiral synthesis of (R)-N-[3-acetyl-4-(2-hydroxy-3-isopropylamino-propoxy)phenyl]-butanamide with high enantioselectivity

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Science china Chemistry 2009年第8期52卷 1216-1219页

作者： WANG NaiXing1,2 & TANG XinLiang1,3 1 Technical Institute of Physics and Chemistry,Chinese Academy of Sciences,beijing 100080,china 2 College of Chemistry and chemical engineering,Graduate university of Chinese Academy of Sciences,beijing 100049,china 3 school of chemical engineering and environment,beijing Institute of technology,beijing 100081,china 1. Technical Institute of Physics and Chemistry Chinese Academy of Sciences Beijing 100080 China 2. College of Chemistry and chemical engineering Graduate University of Chinese Academy of Sciences Beijing 100049 China 3. school of chemical engineering and environment Beijing Institute of Technology Beijing 100081 China

R-Enantiomer of the β-receptor antagonist N-[3-acetyl-4-(2-hydroxy-3-isopropylamino-propoxy)phenyl] butanamide with high enantioselectivity was synthesized from cheap starting materials and enantiopure chiral reagent through an efficient,convenient and practical synthetic *** product was detected by 1H NMR,13C NMR,and MS,and the enatiomeric excess was determined by chiral HPLC analysis using a chiracel AD-H column.

关键词： chiral synthesis enantioselectivity enatiomeric excess chiral HPLC analysis

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Degradation of lignite model compounds by the action of white rot fungi

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mining Science and technology 2010年第1期20卷 76-81页

作者： DU Ying, TAO Xiuxiang, SHI Kaiyi, LI Yang school of chemical engineering and technology, china university of mining & technology, Xuzhou 221000, china [a] school of chemical engineering technology China University of Mining & Technology Xuzhou 221000 China

Three compounds modeled on the lignite structure were chosen for experimental degradation by different fungi strains. Culture conditions and extracellular enzyme activities were optimized. The growth curves of the strains were determined to study mycelium dry weight and protein content changes. Gas chromatography and infrared spectroscopy were used to detect changes of functional groups before and after the action of the fungi on the model compounds. Possible decomposition products and degrada-tion mechanisms were proposed. The research findings show that C. Versicolor and Golden Mushroom can grow in presence of the model compounds. The optimum culture conditions were a pH of 6.0, a carbon-nitrogen ratio of five and a Tween-80 concentration of 0.1%. Newly produced substances were found by gas chromatography. Infrared analysis showed that the model compounds degraded under the action of the microorganisms.

关键词： coal biotransformation white rot fungi mechanism model compound

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Friction-reducing and antiwear behavior of metal halide-stabilized linear phosphazene derivatives as lubricants for a steel-on-steel contact

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Science china(Technological Sciences) 2005年第3期48卷 282-291页

作者： ZHU Jiamei 1,2 , LIU Weimin 2 & LIANG Yongmin 2 1. school of chemical engineering and technology, china university of mining and technology, Xuzhou 221008, china 2. State Key Laboratory of Solid Lubrication, Lanzhou Institute of chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, china 1. school of chemical engineering and technology China University of Mining and Technology 221008 Xuzhou China 2. State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical Physics Chinese Academy of Sciences 730000 Lanzhou China

A series of novel metal halide-stabilized linear phosphazene derivatives were synthesized. The friction-reducing and antiwear abilities of the resulting products as the lubricants for a steel-on-steel contact were comparatively investigated on an Optimol SRV oscillating friction and wear tester. The morphology of the worn steel surface was observed on a scanning electron microscope, while the chemical states of some typical elements on the worn steel surface were examined by means of X-ray photoelectron spectroscopy. It was found that both the side branch structures and central metals influenced the friction-reducing and antiwear behaviors of the synthetic derivatives as the lubricants, which was related to the different adsorption activities of the organic compounds composed of different organic ingredients and metallic ions on a nascent metal surface. All the synthetic lubricants except for the iron (III) derivative showed increased antiwear abilities with increasing metallic ionic radius. A protective layer originated from the tribochemical reaction together with the adsorbed boundary lubricating layer containing organic fluorine compounds, nitrogen oxide, and Fe 3 (PO 4 ) 2 plays an important role in improving the friction and wear behavior of the steel-on-steel system.

关键词： metal halide-stabilized linear phosphazene derivatives,lubricant,steel,tribological properties.

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