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Transient species and its properties of melatonin

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science china Chemistry 2006年第4期49卷 308-314页

作者： ZHU Hongping1,2, ZHANG Zhaoxia1,2, ZHAO Hongwei1, WANG Wenfeng1 & YAO Side1 1. Shanghai Institute of Applied Physics, chinese academy of sciences, Shanghai 201800, china 2. graduate university of the chinese academy of sciences, beijing 100049, china Shanghai Institute of Applied Physics Chinese Academy of Sciences Shanghai China graduate university of the chinese academy of sciences Beijing China

The photo-physical and photo-chemical properties of melatonin (ML) werestudied by 266 nm laser flash photolysis (LFP). ML undergoes photo-ionization to produce radicalcation of ML (ML^(·+))and hydrated electrons (e_(aq)^-), while excited triplet state ~3ML~* is alsoformed during photolysis. The oxidation via one electron transfer from ML to SO_4^(·+) and thetriplet state of riboflavin (~3RF~*) has been also investigated and the rate constants for theprocess have been determined to be 8.0x10^9 and 1.4x10^9 L·mol^(-1)·s^(-1) respectively. Theradical cation of 2,2''-azinobis(3-ethylbenzothiazoline-6-sulfonic acid)(ABTS^(·+)) scavengingcapacities of melatonin and other antioxidants are compared in this paper.

关键词： melatonin, laser flash photolysis, photoionization, triplet state.

Bioreducible crosslinked low molecular weight branched PEI-PBLG as an efficient gene carrier

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science china Chemistry 2010年第12期53卷 2490-2496页

作者： GUO ZhaoPei 1,TIAN HuaYu 1,XIA JiaLiang 1,2,CHEN Jie 1,LIN Lin 1 & CHEN XueSi 1 1 Key Laboratory of Polymer Ecomaterials Changchun Institute of Applied Chemistry,chinese academy of sciences,Changchun 130022,china 2 graduate university of chinese academy of sciences,beijing 100049,china Key Laboratory of Polymer Ecomaterials Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun China graduate university of chinese academy of sciences Beijing China

Low molecular weight polyethylenimine-poly(gamma-benzyl L-glutamate) (PEI-PBLG) was crosslinked by N,N'-cystaminebisacrylamide (CBA) to get the polymer named as CBA-PEI-PBLG (CPP).CPP not only inherits PEI-PBLG's amphiphilic advantages,but also possesses reducible *** can complex with DNA to form ***/DNA complex particles were characterized by particle size and zeta potential *** result showed that the complex particles have suitable size and surface charges for gene *** gel retardation assay also prove CBA-PEI-PBLG has proper condensing ability for *** has good reducible property,and also has good biocompatibility because of introducing PBLG *** cytotoxicity of CPP was evaluated using MTT assay,and the results showed CPP has lower cytotoxicity compared with PEI 25 *** transfection properties were characterized in different cells by using plasmid DNA as a *** showed higher transfection efficiencies and lower cytotoxicity in HeLa *** was attributed to bioreducible and biocompatibility properties of the *** results suggested that CPP is a promising low-toxic,highly effective non-viral gene carrier.

关键词： gene carrier transfection cytotoxicity crosslinked

Trend of urban system structure under the restriction of water and land resources in Xinjiang

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chinese science Bulletin 2006年第A01期51卷 179-188页

作者： ZHANG Xiaolei & LEIJun Xinjiang Institute of Ecology and Geography, chinese academy of sciences, Urumqi 830011, china Institute of Geographical science and Natural Resources Research, chinese academy of sciences, beijing 100101, china graduate School, chinese academy of sciences, beijing 100039, china Xinjiang Institute of Ecology and Geography Chinese Academy of Sciences Urumqi 830011 China Institute of Geographical science and Natural Resources Research Chinese Academy of Sciences Beijing 100101 China graduate School Chinese Academy of Sciences Beijing 100039 China

根据在 Xinjiang 影响城市的开发和城市的系统结构的水和陆地资源上的研究，这篇论文分析利用地位和城市的水资源的缺乏。城市的水资源的消费和浪费在一个增加趋势，这被考虑。然而，在 Xinjiang 的大多数城市和镇在水资源的缺乏水资源... 详细信息

根据在 Xinjiang 影响城市的开发和城市的系统结构的水和陆地资源上的研究，这篇论文分析利用地位和城市的水资源的缺乏。城市的水资源的消费和浪费在一个增加趋势，这被考虑。然而，在 Xinjiang 的大多数城市和镇在水资源的缺乏水资源的废物是严肃的，特别在小镇上。megapolis 和中等城市的发展被有限陆地资源显然限制。尽管有扩展小城市和镇的相对大的空格，水和陆地资源的输出好处是低的。为了完成城市的系统的顺序的扩大，在 Xinjiang 组织，在都市化的快速的发展拿一个圆和三条带和节俭资源的策略的城市的空间发展模式被建议。

关键词：城镇体系结构水资源土地资源供水能力新疆

A statistical study of the relation between soft X-ray excess and accretion disk

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science china(Physics,Mechanics & Astronomy) 2010年第S1期53卷 102-105页

作者： LIU JieYing1,2,3 & QIAO ErLin1,2 1 National Astronomical Observatories/Yunnan Observatory,chinese academy of science,Kunming 650011,china 2 Key Laboratory for the Structure and Evolution of Celestial Objects,chinese academy of sciences,Kunming 650011,china 3 graduate university of chinese academy of sciences,beijing 100049,china National Astronomical Observatories/Yunnan Observatory Chinese Academy of Science Kunming China Key Laboratory for the Structure and Evolution of Celestial Objects Chinese Academy of Sciences Kunming China graduate university of chinese academy of sciences Beijing China

To study the origin of the soft X-ray excess,we compile a sample of 94 unobscured,radio-quiet QSOs and Seyfert galaxies with available data from GALEX and *** find that 50 sources show strong soft X-ray excess and the other 44 show weak/no soft X-ray *** analyses of the data indicate that the difference in soft X-rays is mainly but not only resulting from different accretion rates(in units of Eddington rate).The statistical study of the sources with soft X-ray excess shows that the strength of soft X-ray excess weakly and positively correlates with the Eddington ratio and increases with the increase of the strength of UV radiations relative to the *** that the UV emissions are from the thin disk,the correlations imply that the origin of soft X-ray excess is associated with the thin disk,either by means of Comptonization of the disk photons or in some other ways.

关键词： accretion:accretion disks ultraviolet:galaxies X-rays:galaxies

Simulation of freezing and melting of soil on the northeast Tibetan Plateau

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chinese science Bulletin 2011年第20期56卷 2145-2155页

作者： XIA Kun 1,2,3,LUO Yong 2,4,5 & LI WeiPing 2 1 Institute of Atmospheric Physics,chinese academy of sciences,beijing 100029,china 2National Climate Center,china Meteorological Administration,beijing 100081,china 3graduate university of chinese academy of sciences,beijing 100049,china 4 Center for Earth System science,Tsinghua university,beijing 100084,china 5Key Laboratory of Earth System Numerical Simulation,Ministry of Education,beijing 100084,china Institute of Atmospheric Physics Chinese Academy of Sciences National Climate Center China Meteorological Administration graduate university of chinese academy of sciences Center for Earth System science Tsinghua University Key Laboratory of Earth

Using observational data spanning the period from February to December 2009 and recorded at the Suli station in Qinghai Province,the land-surface model CLM3.0 was employed to simulate the freezing and melting of *** results indicate that the simulated soil temperature is higher than the observed soil temperature and the ultimate thawing date is earlier than the observed date during the melting *** the freezing period,the simulated soil temperature is lower than the observed soil temperature and the ultimate freezing of the deep soil is earlier than that ***,the simulation of freezing is better than that of melting,and the simulation of a shallow layer is better than that of a deeper *** the original CLM3.0,it is assumed that frozen soil begins to melt when the soil temperature exceeds 0C,which is inconsistent with *** critical freeze-thaw temperature was calculated according to thermodynamics equations and the freeze-thaw condition was *** this work,the melting rate for frozen soil was reduced using the modified scheme,and the simulated soil temperature was lowered. Meanwhile,the refreezing of soil during the melting season was well simulated and more closely matched ***,it was found that the rates of melting and freezing differ,with the former being slower than the latter,but refreezing during the melting season is rather quick.

关键词：土壤温度冻结期青藏高原东北部模拟融化观测数据热力学方程表面模型

Synchronous estimation of DTM and fractional vegetation cover in forested area from airborne LIDAR height and intensity data

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science china(Technological sciences) 2008年第S2期51卷 176-187页

作者： BAO YunFei1,2,CAO ChunXiang1,ZHANG Hao1,CHEN ErXue3,HE QiSheng1,2,HUANG HuaBing1,LI ZengYuan3,LI XiaoWen1,4 & GONG Peng1 1 State Key Laboratory of Remote Sensing science,jointly sponsored by the Institute for Remote Sensing Applications of chinese academy of sciences and beijing Normal university,beijing 100101,china 2 graduate university of the chinese academy of sciences,beijing 100049,china 3 Institute of Forest Resource Information Technique,the chinese academy of Forestry,beijing 100091,china 4 Research Center for Remote Sensing and GIS,Department of Geography and beijing Key Laboratory for Remote Sensing of Environment and Digital Sites,beijing Normal university,beijing 100875,china State Key Laboratory of Remote Sensing science jointly sponsored by the Institute for Remote Sensing Applications of Chinese Academy of Sciences and Beijing Normal University Beijing China graduate university of the chinese academy of sciences Beijing China Institute of Forest Resource Information Technique the Chinese Academy of Forestry Beijing China Research Center for Remote Sensing and GIS Department of Geography and Beijing Key Laboratory for Remote Sensing of Environment and Digital Sites Beijing Normal University Beijing China

We proposed a method to separate ground points and vegetation points from discrete return,small footprint airborne laser scanner data,called skewness change *** method,which makes use of intensity of laser scanner data,is especially applicable in steep,and forested *** does not take slope of forested area into account,while other algorithms consider the change of slope in steep forested *** ground points and vegetation points can be used to estimate digital terrain model(DTM) and fractional vegetation cover,respectively.A few vegetation points which were classified into the ground points were removed as noise before the generation of *** method was tested in a test area of 10000 square meters.A LiteMapper -5600 laser system was used and a flight was carried out over a ground of 700―800 *** this tested area,a total number of 1546 field measurement ground points were measured with a total station TOPCON GTS-602 and TOPCON GTS -7002 for validation of DTM and the mean error value is -18.5 cm and the RMSE(root mean square error) is ±20.9 cm.A data trap sizes of 4m in diameter from airborne laser scanner data was selected to compute vegetation fraction *** of fractional vegetation cover was carried out using 15 hemispherical photographs,which are georeferenced to centimeter accuracy by differential *** gap fraction was computed over a range of zenith angles 10° using the gap light analyzer(GLA) from each hemispherical *** R2 for the regression of fractional vegetation cover from these ALS data and the respective field measurements is *** this study presents a method for synchronous estimation of DTM and fractional vegetation cover in forested area from airborne LIDAR height and intensity data.

关键词： LIDAR intensity skewness synchronous DTM fractional vegetation cover

Impact of the Wenchuan Earthquake on Tourism in Sichuan,china

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Journal of Mountain science 2008年第3期5卷 194-208页

作者： YANG Weiqiong CHEN Guojie WANG Daojie Institute of Mountain Hazard and Environment Chinese Academy of Sciences Chengdu 610041 China graduate university of chinese academy of sciences Beijing 100049 China

An intensive earthquake, the Wenchuan Earthquake of 8.0 on the Richter scale, struck western Sichuan, china on May 12, 2008. The earthquake has tremendously affected all industries in the quake-hit areas, with no exception of the local tourism. The study of the effect of the earthquake on tourism enriches the theory of tourism, and more importantly, it well serves as the foundation for policy making. The objective of this study is to outline for readers the empirical findings on the various ways that the earthquake affected the operations and viability of tourism in the quake-hit areas. This paper is mainly divided into 3 parts. The first part is to discuss the importance of tourism in the quake-hit areas. The second is to analyze the influencing factors of tourism. The third is to assess the impact of the earthquake on tourism in Sichuan in different seasons.

关键词： Wenchuan Earthquake Tourism Impact factors of Tourism Economic Loss

Relationship between Surface Pollen and Modern Vegetation in Southwestern china

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Journal of Mountain science 2010年第2期7卷 176-186页

作者： PAN Tao DAI Erfu and WU Shaohong Institute of Geographic sciences and Natural Resources Research Chinese Academy of Sciences Beijing 100101 China graduate university of chinese academy of sciences BeO'ing 100049 China Institute of Tibetan Plateau Research Chinese Academy of Sciences Beijing 100085 China

Based on the pollen data obtained from thirty-five surface soil samples and investigated vegetation data from seven plant quadrats,the quantitative relationship between surface soil pollen and modern vegetation are studied in the longitudinal range-gorge region (LRGR) in Southwestern china.R-values (referring to pollen assemblages) are calculated with pollen percentage and plant *** coefficients of similarity between pollen and vegetation are *** results show that the pollen assemblages on surface soil of all vegetation zones can basically represent the native vegetation,but the pollen assemblages are not fully according with the *** is due to the influencing factors including pollen preservation ability,pollen production,amount of exotic pollen and pollen *** pollen representation in surface soil is different in families and *** pollen of woody plants such as Pinus,Tsuga,Alnus,Fagus and Castanopsis are over-representative,but those of Quercus,Carpinus Myrica,Elaeocarpaceae,Ericaceae,Theaceae and Llex are underrepresentative;the pollen of herbaceous plants such as Artemisia and Rubiaceae are over-representative,while those of others including Gramineae and Araliaceae are *** R-values of the same taxon pollen in different vegetation zones are different,depending on their distances from the pollen *** coefficients of the similarity between plant communities and pollen assemblages are mostly over 70%,which indicate again that the surface soil pollen and spores assemblages can represent the *** is concluded that there is a good corresponding relationship between surface pollen assemblages and native vegetation in LRGR,and it is of great significance for reconstructing the past vegetation and paleoclimate using quantitative fossil pollen data in this region.

关键词： Longitudinal range-gorge region (LRGR) Pollen assemblage Vegetation R-value Coefficient of similarity

Responses of soil respiration in non-growing seasons to environmental factors in a maize agroecosystem,Northeast china

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chinese science Bulletin 2010年第24期55卷 2723-2730页

作者： LI RongPing1,2,3, ZHOU GuangSheng1,4 & WANG Yu1,3 1 State Key Laboratory of Vegetation and Environmental Change, Institute of Botany, chinese academy of sciences, beijing 100093, china 2 Institute of Atmospheric Environment, china Meteorological Administration, Shenyang 110016, china 3 graduate university of chinese academy of sciences, beijing 100049, china 4 chinese academy of Meteorological sciences, beijing 100081, china State Key Laboratory of Vegetation and Environmental Change Institute of Botany Chinese Academy of Sciences Beijing 100093 China Institute of Atmospheric Environment China Meteorological Administration Shenyang 110016 China graduate university of chinese academy of sciences Beijing 100049 China chinese academy of Meteorological sciences Beijing 100081 China

Based on continuous three-year measurements (from 2004 to 2007) of eddy covariance and related environmental factors, environmental controls on variation in soil respiration (Rs) during non-growing season were explored in a maize agroecosystem in Northeast china. Our results indicated that during non-growing seasons, daily Rs was 1.08-4.08 g CO2 m-2 d-1, and the lowest occurred in late November. The average Rs of non-growing season was 456.06 ± 20.01 g CO2 m-2, accounting for 11% of the gross primary production (GPP) of the growing season. Additionally, at monthly scale, the lowest value of Rs appeared in January or February. From the beginning to the end of non-growing season, daily Rs tended to decrease first, and then increase to the highest. There was a significant quadratic curve relationship between Rs and soil temperature at 10 cm depth when soil temperature was more than 0°C (P2.7%-11.8%. Rs in non-growing season can account for 22.4% of Rs in growing season, indicating that it plays a critical role in assessing the carbon budget in maize agroecosystem, Northeast china.

关键词：中国东北地区农田生态系统生长季节土壤呼吸环境因素玉米土壤含水量反应