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Study on the atmospheric photochemical reaction of CF_3 radicals using ultraviolet photoelectron and photoionization mass spectrometer

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Science china Chemistry 2008年第4期51卷 316-321页

作者： YAO Li1,2, DU Lin1,2, YIN Shi1,2 & GE MaoFa1 1 beijing National Laboratory for Molecular sciences (BNLMS), State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, chinese academy of sciences, beijing 100080, china 2 graduate University of chinese academy of sciences, beijing 100080, china 1. beijing National Laboratory for Molecular sciences (BNLMS) State Key Laboratory for Structural Chemistry of Unstable and Stable Species Institute of Chemistry Chinese Academy of Sciences Beijing 100080 China 2. graduate University of chinese academy of sciences Beijing 100080 China

A study of the atmospheric photochemical reaction of CF3 radical with CO and O2 was performed by using a homemade ultraviolet photoelectron spectrometer-photoionization mass spectrometer (PES- PIMS). The electronic structures and mechanism of ionization and dissociation of CF3OC(O)OOC(O)- OCF3 were investigated. It was indicated that the two bands on the photoelectron spectrum of CF3OC(O)OOC(O)OCF3 are the result of ionization of an electron from a lone pair of oxygen and a fluo- rine lone pair of CF3 group. The outermost electrons reside in the oxygen lone pair. The experimental and theoretical first vertical ionization energy is 13.21 and 13.178 eV, respectively, with the PES and OVGF method. They are in good agreement. The photo ionization and dissociation processes were discussed with the help of theoretical calculations and PES-PIMS experiment. After ionization, the parent ions prefer the dissociation of the C-O bond and giving the fragments CF3OCO+ and CF3+. It demonstrated that the ultraviolet photoelectron and photoionization mass spectrometer could be ap- plied widely in the study of atmospheric photochemical reaction.

关键词： photochemical reaction CF3 radical ultraviolet photoelectron and photoionization mass spectroscopy transient species

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A mixed method for measuring low-frequency acoustic properties of macromolecular materials

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Science china(Physics,Mechanics & Astronomy) 2006年第6期49卷 729-739页

作者： LIU Hongwei1,YAO Lei1,3,ZHAO Hong1,3,ZHANG Jichuan2,3 & XUE Zhaohong2 1. National Key Laboratory of Acoustics,Institute of Acoustics,chinese academy of sciences,beijing 100080,china 2. Institute of Chemistry,chinese academy of sciences,beijing 100080,china 3. graduate University of chinese academy of sciences,beijing 100049,china National Key Laboratory of Acoustics Institute of Acoustics Chinese Academy of Sciences Beijing 100080 China Institute of Chemistry Chinese Academy of Sciences Beijing 100080 China graduate University of chinese academy of sciences Beijing 100049 China

A mixed method for measuring low-frequency acoustic properties of macro-molecular materials is presented. The dynamic mechanical parameters of materials are first measured by using Dynamic Mechanical Thermal Apparatus(DMTA) at low frequen-cies,usually less than 100 Hz; then based on the Principles of Time-Temperature Super-position (TTS),these parameters are extended to the frequency range that acousticians are concerned about,usually from hundreds to thousands of hertz; finally the extended dynamic mechanical parameters are transformed into acoustic parameters with the help of acoustic measurement and inverse analysis. To test the feasibility and accuracy,we measure a kind of rubber sample in DMTA and acquire the basic acoustic parameters of the sample by using this method. While applying the basic parameters to calculating characteristics of the sample in acoustic pipe,a reasonable agreement of sound absorp-tion coefficients is obtained between the calculations and measurements in the acoustic pipe.

关键词： low-frequency acoustic properties,dynamic mechanical properties,Principles of Time-Temperature Superposition,acoustic pipe,sound absorption coefficient.

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Evidence of a two-component jet in the afterglow of GRB 070419A

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Science china(Physics,Mechanics & Astronomy) 2010年第S1期53卷 265-266页

作者： ZHENG WeiKang1,2 & DENG JinSong1 1 National Astronomical Observatories,chinese academy of sciences,beijing 100012,china 2 graduate University of chinese academy of Science,beijing 100049,china 1. National Astronomical Observatories Chinese Academy of Sciences Beijing 100012 China 2. graduate University of chinese academy of Science Beijing 100049 China

A two-component jet model is proposed to explain the unusual afterglow of GRB *** the optical light curve,a wide "jet" with an opening angle of >30-40 degrees is assumed to produce the late shallow decay,while the three early power-law segments must be caused by a narrow jet with an opening angle of-2-4 *** energy injections to both components are *** X-ray emission may come from either the wide jet or the narrow *** the latter is correct,the jets may run into an ISM environment and the temporal index of the late energy injection may be q-0.65.

关键词： gamma-rays:bursts gamma-rays:observations

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Optimization of mathematical models for thematic maps

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Science china(Technological sciences) 2010年第S1期53卷 15-24页

作者： QI QingWen1,ZHANG An1,JIANG LiLi1,ZOU XiuPing2,XU Li3 & CHENG Xi1,4 1 Institute of Geographical sciences and Natural Resources Research,chinese academy of sciences,beijing 100101,china 2 Institute of Policy and Management,chinese academy of sciences,beijing 100080,china 3 Taishan University,Taian 271021,china 4 graduate University of chinese academy of sciences,beijing 100049,china chinese Acad Sci Inst Geog Sci & Nat Resources Res Beijing 100101 Peoples R China chinese Acad Sci Inst Policy & Management Beijing 100080 Peoples R China Taishan Univ Tai An 271021 Shandong Peoples R China chinese Acad Sci Grad Univ Beijing 100049 Peoples R China

The thematic map is a major class of maps designed to demonstrate particular features or concepts,functioning as an indispensable tool in geographical *** process of thematic mapping is one into which geographical research goes deeply and *** key activity and course of thematic map production is the use of mathematical models to create thematic data ***,the selection and optimization of mathematical models is in the forefront of thematic map *** theoretical foundations,mechanisms and methods of mathematical model optimization are expounded in this paper,including two approaches,the phase by phase mode and the multi-aim scheme balance *** studies in eco-environment mapping and emergency mapping are described and analyzed,with a hierarchical analysis method being used in the model optimization for eco-environment fragility and sensitivity assessment mapping in Beibuwan (Guangxi) District,the dynamic system (DS) method being used in the model optimization for ecological security adjustment mapping in Xishuang Banna,Yunnan province,and the multi-phase mode being used in the models for forest fire and infectious diseases mapping.

关键词： thematic map mathematic model optimization

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Existence of unbiased estimate of regression parameters in simple linear EV models

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Science china Mathematics 2005年第7期48卷 915-928页

作者： LIU Jixue & CHEN Xiru Department of Statistics and Finance, University of Science and Technology of china, Hefei 230026, china Department of Mathematics, graduate School of chinese academy of sciences, beijing 100049, china Department of Statistics and Finance University of Science and Technology of China Hefei 230026 China Department of Mathematics Graduate School Chinese Academy of Sciences Beijing 100049 China

It is well known that for one-dimensional normal EV regression model X = x+ u,Y =α+βx+e, where x, u, e are mutually independent normal variables and Eu=Ee=0, the regression parameters a and β are not identifiable without some restriction imposed on the parameters. This paper discusses the problem of existence of unbiased estimate for a and β under some restrictions commonly used in practice. It is proved that the unbiased estimate does not exist under many such restrictions. We also point out one important case in which the unbiased estimates of a and β exist, and the form of the MVUE of a and β are also given.

关键词： EV regression model unbiased estimate identiflability.

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Bio-regeneration of p-complexation desulfurization adsorbents

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Science china Chemistry 2005年第6期48卷 538-544页

作者： LI Wangliang1,2, XING Jianmin1, XIONG Xiaochao1,2, SHAN Guobin1,2 & LIU Huizhou1 1. Laboratory of Separation Science and Engineering, Institute of Process Engineering, chinese academy of sciences, beijing 100080, china 2. graduate School of the chinese academy of sciences,beijing 100039, china 1. Laboratory of Separation Science and Engineering Institute of Process Engineering Chinese Academy of Sciences 100080 Beijing China 2. graduate School of the chinese academy of sciences 100039 Beijing China

The coupling of adsorption desulfurization and biodesulfurization is a new approach to produce clean fuels. Sulfur compounds are firstly adsorbed on adsorbents, and then the ad-sorbents are regenerated by microbial conversion. p-Complexation adsorbent, Cu(I)-Y, was ob-tained by ion exchanging Y-type zeolite with Cu2+ and then by auto-reduction in helium at 450℃ for 3 h. Dibenzothiophene (DBT) was used as a model compound. The effects of cell concentra-tion, volume of oil phase, the ratio of aqueous phase to adsorbent on DBT desorption by a bac-terium were studied. The amounts of DBT desorbed and 2-HBP produced can be apparently increased with addition of n-octane. BDS activity can be improved by increasing cell concentra-tion and the ratio of water-to-adsorbent. 89% of DBT desorbed from the adsorbents can be converted to 2-HBP within 6 h and almost 100% within 24 h, when the volume ratio of oil-to-water was 1/5 mL/mL, the cell concentration was 60 g·L?1, and the ratio of adsorbent-to-oil was 0.03 g·mL?1. The amount of 2-HBP produced was strongly dependent on the volume ratio of oil-to- water, cell concentration and amount of adsorbent. Adsorption capacity of the regenerated ad-sorbent is 95% that of the fresh one after being desorbed with Pseudomonas delafieldii R-8, washed with n-octane, dried at 100℃ for 24 h and auto-reduced in He.

关键词： adsorption desulfurization p-complexation adsorbents bio-regeneration Pseudomonas delafieldii desorption.

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Explicit analytical solutions of the anisotropic Brinkman model for the natural convection in porous media(Ⅱ)

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Science china(Physics,Mechanics & Astronomy) 2005年第4期48卷 422-430页

作者： CAI Ruixian1, GOU Chenhua1, 2 & ZHANG Na1 1. Institute of Engineering Thermophysics, chinese academy of sciences, beijing 100080, china 2. graduate School, chinese academy of sciences, beijing 100080, china 1. Institute of Engineering Thermophysics Chinese Academy of Sciences 100080 Beijing China 2. graduate School Chinese Academy of Sciences 10080 Beijing China

Some algebraically explicit analytical solutions are derived for the anisotropic Brinkman model―an improved Darcy model―describing the natural convection in porous media. Besides their important theoretical meaning (for example, in analyzing the non-Darcy and anisotropic effects on the convection), such analytical solutions can be the benchmark solutions that can promote the development of computational heat and mass transfer. Some solutions considering the anisotropic effect of permeability have been given previously by the authors, and this paper gives solutions including the anisotropic effect of thermal conductivity and the effect of heat sources.

关键词： explicit analytical solution, porous medium, natural convection, Brinkman model, anisotropic.

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New research progress on the ultrastructure of tectonically deformed coals

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Progress in Natural Science:Materials International 2009年第11期19卷 1455-1466页

作者： Yiwen Ju,Xiaoshi Li Laboratory of Computational Geodynamics,College of Earth Science,graduate University of chinese academy of sciences,beijing 100049,china [a]Laboratory of Computational Geodynamics College of Earth Science Graduate University of Chinese Academy of Sciences Beijing 100049 China

The structure of tectonically deformed coals shows some characteristics and regulations on the ultra-scale when influenced by different factors such as temperature,pressure and directional *** of the macromolecular structure may induce changes in the nano-scale pore structure,which are very important for gas adsorption and *** geological impact of different mechanisms of deformation on different types of ultrastructure of tectonically deformed coals is not only of significance as a topic for scientific research, but also in studying environments of metamorphism-deformation at differing metamorphic *** research is also very important in studying the accumulation and occurrence conditions of coalbed methane gas,mechanisms of coal and gas outbursts,predictions of coalbed methane resources and dangers of coal and gas *** paper analyzes current research,within china and other countries, in the ultrastructure of tectonically deformed *** research includes(1) structural models of tectonically deformed coals;(2) the relationship between ultrastructure and stress;(3) the structure of tectonically deformed coals and its strain *** results are also based on our own experiments including vitirnite reflectance(Ro,max),X-ray diffraction(XRD) and nuclear magnetic resonance (NMR(CP/MAS + TOSS)).We discuss the important effects of the structure of tectonically deformed coals and their physical properties,and then point out some problems concerning the research progress of tectonically deformed coals.

关键词： Tectonically deformed coals Ultrastructure Pore structure Tectonic stress Strain environment

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Improvement of a 3D radar backscattering model using matrix-doubling method

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Science china Earth sciences 2010年第7期53卷 1029-1035页

作者： NI WenJian1,2, GUO ZhiFeng1 & SUN GuoQing3 1 State Key Laboratory of Remote Sensing Science, jointly sponsored by the Institute of Remote Sensing Applications of chinese academy of sciences and beijing Normal University, beijing 100101, china 2 graduate University of chinese academy of sciences, beijing 100049, china 3 Department of Geography, University of Maryland, College Park, MD 27042, USA 1. State Key Laboratory of Remote Sensing Science jointly sponsored by the Institute of Remote Sensing Applications of Chinese Academy of Sciences and Beijing Normal University Beijing 100101 China2. Graduate University of Chinese Academy of Sciences Beijing 100049 China3. Department of Geography University of Maryland College Park MD 27042 USA

Radiative transfer models have been widely used to simulate the radar backscattering from forested areas. A three-dimensional radar backscatter model of forest canopy developed in previous studies takes full account of spatial position of trees in a forest stand, and the interactions among crown, trunk and ground surface. The model predicted well for the co-polarized backscatter measurements, but underestimated the backscattering for cross-polarization, primarily because only the first-order scattering within tree crowns was considered in the model. The backscattering at cross-polarization depends strongly on multiple scatter- ing within tree crowns. To produce good estimations for cross-polarized component, the matrix-doubling method is employed here to compute multiple-scattering within the crown. The modified model is compared with the original model, and the field forest measurements and AIRSAR data are used for validation of the modified model. The cross-polarization backscattering is improved in different degrees for different crown structures and at different bands.

关键词： remote sensing forestry electromagnetic propagation radar backscattering model matrix-doubling

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Relationship between Surface Pollen and Modern Vegetation in Southwestern china

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Journal of Mountain Science 2010年第2期7卷 176-186页

作者： PAN Tao DAI Erfu and WU Shaohong Institute of Geographic sciences and Natural Resources Research Chinese Academy of Sciences Beijing 100101 China graduate University of chinese academy of sciences BeO'ing 100049 China Institute of Tibetan Plateau Research Chinese Academy of Sciences Beijing 100085 China

Based on the pollen data obtained from thirty-five surface soil samples and investigated vegetation data from seven plant quadrats,the quantitative relationship between surface soil pollen and modern vegetation are studied in the longitudinal range-gorge region (LRGR) in Southwestern china.R-values (referring to pollen assemblages) are calculated with pollen percentage and plant *** coefficients of similarity between pollen and vegetation are *** results show that the pollen assemblages on surface soil of all vegetation zones can basically represent the native vegetation,but the pollen assemblages are not fully according with the *** is due to the influencing factors including pollen preservation ability,pollen production,amount of exotic pollen and pollen *** pollen representation in surface soil is different in families and *** pollen of woody plants such as Pinus,Tsuga,Alnus,Fagus and Castanopsis are over-representative,but those of Quercus,Carpinus Myrica,Elaeocarpaceae,Ericaceae,Theaceae and Llex are underrepresentative;the pollen of herbaceous plants such as Artemisia and Rubiaceae are over-representative,while those of others including Gramineae and Araliaceae are *** R-values of the same taxon pollen in different vegetation zones are different,depending on their distances from the pollen *** coefficients of the similarity between plant communities and pollen assemblages are mostly over 70%,which indicate again that the surface soil pollen and spores assemblages can represent the *** is concluded that there is a good corresponding relationship between surface pollen assemblages and native vegetation in LRGR,and it is of great significance for reconstructing the past vegetation and paleoclimate using quantitative fossil pollen data in this region.

关键词： Longitudinal range-gorge region (LRGR) Pollen assemblage Vegetation R-value Coefficient of similarity

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