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MnS–MnO heterogeneous nanocube@N,S-doped carbon as a highly efficient bifunctional water splitting electrocatalyst

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Rare Metals 2024年第5期43卷 1977-1988页

作者： Xue-Qian Wang Xiang-Ying Ma Wang-Zhi Wu Hui-Bing He nan-nan Wang Ren-ji Zheng Shao-jian Ma Yan-Qiu Zhu Pei-Kang Shen jin-Liang Zhu School of Resources Environment and MaterialsState Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite StructuresCollege of Chemistry and Chemical EngineeringGuangxi UniversityNanning 530004China School of Chemistry and Chemical Engineering Guangxi MinzuUniversity Nanning 530006 China School of Minerals Processing and bioengineering Central South UniversityChangsha 410083China

A stable,efficient,and economical bifunctional electrolytic catalyst would be incredibly beneficial for the development of hydrogen production by electrocatalytic water *** this study,we synthesized a novel MnS–MnO heterogeneous nanocube@N,S-doped carbon(MnS–MnO@NSC).MnS–MnO nanocubes possess rich heterogeneous interfaces and plentiful catalytic active sites to promote electrochemical reactions,while the N,S-doped carbon shell possesses excellent conductivity and catalytic properties and protects the ***–MnO@NSC exhibited excellent electrochemical properties as an effective bifunctional electrocatalyst for the hydrogen evolution reaction(HER)and oxygen evolution reaction(OER)in KOH *** the HER,the overpotential was as low as 124 mV at a current density of 10 mA·cm^(-2)while in the OER,it was only 340 mV at 100 mA·cm^(-2)under the same *** addition,a MnS–MnO@NSC||MnS–MnO@NSC electrolyzer exhibited almost comparable activity and higher steadiness than those exhibited by the state-of-the-art Pt/C||RuO_(2)/C system for full water splitting in KOH solution.

关键词： Manganese sulfide Manganese oxide Doped carbon Heterogeneous nanocube Water splitting

Enhancement of binding activity of soluble human CD40 to CD40 ligand through incorporation of an isoleucine zipper motif

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Acta Pharmacologica Sinica 2006年第3期27卷 333-338页

作者： Xian-hui HE~(2,3) Li-hui XU~4 Yi LIU~(2,5) ~2Key Laboratory of Ministry of Education for Tissue Transplantation and Immunology,jinan university,guangzhou 510632,china.~4 institute of bioengineering,jinan university,guangzhou 510632.china Key Laboratory of Ministry of Education for Tissue Transplantation and Immunology Jinan University Guangzhou China institute of bioengineering Jinan University Guangzhou China

Aim:To investigate the effect of incorporation of an isoleucine zipper(IZ)motifinto CD40 on binding activity of CD40 for the CD40 ligand(CD40L).Methods:Prokaryotic expression vectors for 2 soluble CD40 derivatives,shCD40His andshCD40IZ containing an IZ dowain,were constructed and expressed in Escheri-chia *** recombinant proteins were purified to homogeneity after refoldingfrom inclusion *** molecular weights in solution of shCD40His andshCD40IZ were compared by size-exclusion chromatography,and their bindingactivity for CD40L on Jurkat T cells was determined by flow ***:shCD40His and shCD40IZ were *** of them possessed significantbinding activity for the cognate ligand CD40L expressed on the cell ***40IZ had much higher binding activity to its ligand(CD40L)than ***,size-exclusion chromatography demonstrated thatshCD40IZ existed in high molecular mass forms that were most likely to be trimersin ***:Incorporation of an IZ motif into CD40 enhances itsbinding activity for CD40L through trimerization of the CD40 derivative.

关键词： soluble CD40 isoleucine zipper trimerization binding activity CD40L

Prediction of suitable water content in granulation of sintering mixture based on Litster's model

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Journal of Iron and Steel Research(International) 2024年第3期31卷 552-560页

作者： Fang-lei Dai Xiao-hui Fan Xiao-xian Huang Xu-ling Chen Min Gan Zhi-yun ji Zeng-qing Sun School of Minerals Processing and bioengineering Central South UniversityChangsha 410083HunanChina

Suitable water content plays a decisive role in the granulation of sintering ***,a method was proposed to predict the suitable water content for effective granulation on the basis of Litster's granulation *** granulation effectiveness of a sintering mixture was predicted by the model,with the allowance error of±10%.The effects of the water absorption properties,particle size composition and content of adhesive particles on the suitable water content were *** results showed that the allowable error of prediction was within±0.5%compared to the experimentally determined suitable water *** an increase in adhesive powder content of mixtures with higher water absorption,the suitable water content increased to achieve similar granulation ***,as the amount of concentrates increased,the suitable water content first increased and then remained *** influence of the water absorption characteristics of the adhesive particles on the suitable water content was less than that of their particle size composition in the mixture.

关键词： Adhesive particle Sintering mixture Granulation effectiveness Suitable water content

Interfacial/bulk synergetic effects accelerating charge transferring for advanced lithium-ion capacitors

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Chinese Chemical Letters 2024年第6期35卷 168-175页

作者： Chang Liu Zirui Song Xinglan Deng Shihong Xu Renji Zheng Wentao Deng Hongshuai Hou Guoqiang Zou Xiaobo ji School of Chemistry and Chemical Engineering Hunan Institute of EngineeringXiangtan 411104China College of Chemistry and Chemical Engineering Central South UniversityChangsha 410083China Key Laboratory of Hunan Province for Clean and Efficient Utilization of Strategic Calcium-Containing Mineral Resources School of Minerals Processing and BioengineeringCentral South UniversityChangsha 410083China

The exploration of advanced materials through rational structure/phase design is the key to develop highperformance lithium-ion capacitors(LICs).However,high complexity of material preparation and difficulty in quantity production largely hinder the further ***,Cu_(5)FeS_(4-x)/C(CFS@C)heterojunction with rich sulfur vacancies has successfully achieved from natural bornite,presenting low costeffective and bulk-production *** functional theory(DFT)calculations indicate that rich vacancies in bulk phase can decrease band gap of bornite and thus improve its intrinsic electron conductivity,as well as the heterojunction spontaneously evokes a built-in electric field between its interfacial region,largely reducing the migration barrier from 1.27 e V to 0.75 e *** from these merits,the CFS@C electrodes deliver outperformed lithium storage performance,e.g.,high reversible capacity(822.4m Ah/g at 0.1 A/g),excellent cycling stability(up to 820 cycles at 2 A/g and 540 cycles at 5 A/g with respective capacity retention of over or nearly 100%).With CFS@C as anode and porous carbon nanosheets(PCS)as cathode,the assembled CFS@C//PCS LIC full cells exhibit high energy/power density characteristics of 139.2 Wh/kg at 2500 W/*** work is expected to offer significant insights into structure modifications/devising toward natural minerals for advanced energy-storage systems.

关键词： Bulk/interfacial modification Heterostructure Sulfur vacancies Lithium ion capacitors Capacitors

作为姜黄素递送载体的黄原胶-β乳球蛋白纤维复合凝胶的制备

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食品与发酵工业 2024年第10期50卷 55-61页

作者：高超杨楠湖北工业大学菲利普斯胶体研究中心湖北工业大学生物工程与食品学院湖北武汉430068 湖北省亲水胶体国际合作基地湖北武汉430068

该研究旨在用黄原胶(xanthan gum,XG)和β-乳球蛋白纤维(β-lactoglobulin fiber,Fblg)制备多糖-蛋白纤维复合水凝胶作为生物活性物质姜黄素(curcumin,Cur)的递送载体。电位、浊度和原子力显微镜证实了XG与Fblg分子之间发生了络合作用,... 详细信息

该研究旨在用黄原胶(xanthan gum,XG)和β-乳球蛋白纤维(β-lactoglobulin fiber,Fblg)制备多糖-蛋白纤维复合水凝胶作为生物活性物质姜黄素(curcumin,Cur)的递送载体。电位、浊度和原子力显微镜证实了XG与Fblg分子之间发生了络合作用,静电相互作用是XG和Fblg络合的主要驱动力。通过用葡萄糖酸内酯(glucono delta-lactone,GDL)调控复合体系pH至4.0,成功得到稳定的XG-Fblg凝胶。扫描电子显微镜显示,XG-Fblg凝胶形成三维网孔结构并随Fblg的增加而变得更致密。流变和质构测试显示,XG-Fblg凝胶的机械强度随Fblg的含量增加而增强。采用体外胃肠道释放实验研究Cur的释放行为,XG-Fblg凝胶比XG凝胶和Fblg更适合作为Cur肠道递送的载体,在肠道的Cur释放量最多,Cur的释放主要通过凝胶降解控制。该研究结果可为多糖-蛋白纤维复合凝胶的制备以及合理设计水凝胶作为营养物质递送载体提供新的思路。

关键词： β-乳球蛋白纤维黄原胶复合凝胶静电相互作用营养物质递送

Highly Sensitive Fluorescent-labeled Probes and Glass Slide Hybridization for the Detection of Plant RNA Viruses and a Viroid

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Acta Biochimica et Biophysica Sinica 2007年第5期39卷 326-334页

作者： Zhiyou DU~(1,2), Bo jiN~3, Wenhong LIU~4, Liang CHEN~1, and jishuang CHEN~(2,1*) 1 College of Life Sciences, Zhejiang university, Hangzhou 310029, china 2 institute of bioengineering, Zhejiang Sci-Tech university, Hangzhou 310018, china 3 College of Life Sciences, Zhejiang Chinese Medical university, Hangzhou 310053, china 4 College of bioengineering, Zhejiang Chinese Medical university, Hangzhou 310053, china College of Life Sciences Zhejiang UniversityHangzhou 310029 China institute of bioengineering Zhejiang Sci-Tech UniversityHangzhou 310018 China College of Life Sciences Zhejiang Chinese Medical UniversityHangzhou 310053 China College of bioengineering Zhejiang Chinese Medical UniversityHangzhou 310053 China

In this study, a modified method of the conventional RNA dot-blot hybridization was established, by replacing32p labels with CY5 labels and replacing nylon membranes with positive-charged glass slides, for detecting plant RNA viruses and a viroid. The modified RNA dot-blot hybridization method was named glass slide hybridization. The optimum efficiency of RNA binding onto the surfaces of activated glass slide was achieved using aminosilane-coated glass slide as a solid matrix and 5×saline sodium citrate （SSC） as a spotting solution. Using a CY5-labeled DNA probe prepared through PCR amplification, the optimized glass slide hybridization could detect as little as 1.71 pg of tobacco mosaic virus （TMV） RNA. The sensitivity of the modified method was four times that of dot-blot hybridization on nylon membrane with a32P-labeled probe. The absence of false positive within the genus Potyvirus [potato virus A, potato virus Y （PVY） and zucchini yellow mosaic virus] showed that this method was highly specific. Furthermore, potato spindle tuber viroid （PSTVd） was also detected specifically. A test of 40 field potato samples showed that this method was equivalent to the conventional dot-blot hybridization for detecting PVY and PSTVd. To our knowledge, this is the first report of using dot-blot hybridization on glass slides with fluorescent-labeled probes for detecting plant RNA viruses and a viroid.

关键词： glass slide hybridization fluorescent labeling dot-blot hybridization virus viroid

Quantitative Determination of Cucumber Mosaic Virus Genome RNAs in Virions by Real-Time Reverse Transcription-Polymerase Chain Reaction

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Acta Biochimica et Biophysica Sinica 2006年第10期38卷 669-676页

作者： Jun-Li FENG~1 Shao-Ning CHEN~1 Xiang-Shan TANG~1 Xian-Feng DING~1 Zhi-You DU~2 ji-Shuang CHEN~(1,2*) 1 institute of bioengineering,Zhejiang Sci-Tech university,Hangzhou 310018,china 2 College of Life Sciences,Zhejiang university,Hangzhou 310029,china institute of bioengineering Zhejiang Sci-Tech UniversityHangzhou 310018 China College of Life Sciences Zhejiang UniversityHangzhou 310029 China

A real-time RT-PCR procedure using the green fluorescent dye SYBR Green Ⅰ was developedfor determining the absolute and relative copies of cucumber mosaic virus （CMV） genomic RNAs containedin purified *** specific to each CMV ORF were designed and *** were thenamplified with length varying from 61 to 153 *** dilution series of CMV genome RNAs prepared by invitro transcription as the standard samples,a good linear correlation was observed between their thresholdcycle （C_t） values and the logarithms of the initial template *** copies of genomic RNA 1,RNA 2,RNA 3 and the subgenomic RNA 4 in CMV virions were quantified by this method,and the ratios were about1.00:1.17:3.58:*** results were confirmed by Lab-on-a-Chip and Northern blot hybridization *** work is the first report concerning the relative amounts of different RNA fragments in CMV virions asa virus with tripartite genome.

关键词： real-time reverse transcription-polymerase chain reaction cucumber mosaic virus genomic RNA quantitative determination

Self-Assembled Protein Hybrid nanofibrils for Photosynthetic Hydrogen Evolution

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CCS Chemistry 2024年第3期6卷 812-823页

作者： Weijian Chen Xiantao Hu Andi Hu Luyang ji Yiming Huang Hao Heng Fude Feng Shu Wang Department of Polymer Science and Engineering School of Chemistry and Chemical EngineeringNanjing UniversityJiangsuNanjing 210023 Beijing National Laboratory for Molecular Sciences Key Laboratory of Organic SolidsInstitute of ChemistryChinese Academy of SciencesBeijing 100190

In artificial photosynthesis systems,synthetic diiron complexes are popular[FeFe]-hydrogenase mimics,which are attractive for the fabrication of photocatalyst-protein hybrid structures to amplify hydrogen(H2)generation ***,constructing a highly bionic and efficient catalytic hybrid system is a major ***,we designed an ideal hybrid nanofibrils system that incorporates the crucial components:(1)a[FeFe]-H2ase mimic,which has a three-arm architecture(named triFeFe)for more interaction sites and higher catalytic activity and(2)uniform hybrid nanofibrils as the biological environment in which cysteine-catalyst coordination and the hydrogen-bonding network play a vital role in both catalyst binding and hydrogen evolution reaction *** assembled hybrid nanofibrils achieve efficient H2 generation with a turnover number of 2.3×103,outperforming previously reported diiron catalyst-protein hybrid ***,the hybrid nanofibrils work with photosynthetic thylakoids to produce H2,without extra photosensitizers or electron shuttle proteins,which advances the bioengineering of living systems for solar-driven biofuel production.

关键词： hybrid photocatalyst in situ assembly amyloid fibrils photosynthetic hydrogen evolution thylakoid

DUCTILE CRACK INITIATION AND STEADY-STATE PROPAGATION OF HIGH STRENGTH STRUCTURAL STEEL

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Acta Metallurgica Sinica(English Letters) 1990年第3期3卷 194-198页

作者： CHEN huangpu DENG Zengjie Xi’an jiaotong university,Xi’an,china CHEN huangpu,Lectuer,Research institute for Strength of Metals,Xi’an jiaotong university,Xi’an 710049,china

The resistance to crack propagation at earlier stage for a high strength structural steel with certain ductility and its correlation to microstructures,stress states,deformation history and strain characteristics have been *** resistance to crack propagation is mainly de- termined by the plastic constrain ahead of the crack tip,the elastic energy and plastic work absorbed in the stress-strain *** are connected with the state function of triaxial *** deformation history and strain characteristic during deformation of material are described by the flow line in which the deformation history and strain characteristic restrain the crack initiation at stage Ⅱ and the crack propagation at stage Ⅲ.The strain hardening rate may sensitively reflect the stress distribution and micro-fracture mechanism in the interi- or of material.

关键词： high strength structural steel microstructure stress state strain characteristic