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Boosting energy-storage capability in carbon-based supercapacitors using low-temperature water-in-salt electrolytes

Journal of Energy Chemistry 2022年第7期31卷 521-530,I0013页

作者： Joao Pedro a.santos Manuel J.Pinzón érick a.santos Rafael Vicentini Cesar J.B.Pagan Leonardo M.Da Silva Hudson Zanin Brazilian Renewable Energies Center for Innovation on New EnergiesSchool of Electrical and Computer EngineeringUniversity of CampinasSao Paulo 13083-852Brazil Department of Semiconductors Instruments and PhotonicsSchool of Electrical and Computer EngineeringUniversity of CampinasSao Paulo 13083-852Brazil Laboratory of Fundamental and Applied Electrochemistry Department of ChemistryFederal University of Jequitinhonha e Mucuri’s ValleyMinas Gerais 39100-000Brazil

Supercapacitors(SCs) are high-power energy storage devices with ultra-fast charge/discharge *** using concentrated aqueous-based electrolytes can work at low temperatures due to their intrinsic properties, such as higher freezing point depression(FPD) and robustness. Besides the traditional organic-and aqueous-based(salt-in-water) electrolytes used in SCs, water-in-salt(WISE) sodium perchlorate electrolytes offer high FPD, non-flammability, and low-toxicity conditions, allowing the fabrication of safer, environmentally friendly, and more robust devices. For the first time, this work reports a comprehensive study regarding WISE system’s charge-storage capabilities and physicochemical properties under low-temperature conditions(T < 0 ℃) using mesoporous carbon-based electrodes. The effect of temperature reduction on the electrolyte viscosity and electrical properties was investigated using different techniques and the in-situ(or operando) Raman spectroscopy under dynamic polarization *** cell voltage, equivalent series resistance, and specific capacitance were investigated as a function of the temperature. The cell voltage(U) increased ~ 50%, while the specific capacitance decreased ~20%when the temperature was reduced from 25 ℃ to -10 ℃. As a result, the maximum specific energy(E = CU^(2)/2) increased ~ 100%. Therefore, low-temperature WISEs are promising candidates to improve the energy-storage characteristics in SCs.

关键词： Carbon supercapacitors Water-in-salt electrolytes Low-temperature charge-storage Specific energy improvement at low temperatures

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Operando FTIR study on water additive in lithium-sulfur batteries to mitigate shuttle effect

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Journal of Energy Chemistry 2024年第11期98卷 702-713页

作者： érick a.santos Martim C.Policano Manuel J.Pinzón Isabela Galantini Vanessa A.Goncalves Francisco C.B.Maia Lucyano J.A.Macedo Gustavo Doubek Renato G.Freitas Hudson Zanin Advanced Energy Storage Division Center for Innovation on New EnergiesSchool of Electrical and Computer EngineeringUniversity of CampinasAv Albert Einstein 400CampinasSP 13083-852Brazil Catalytic Processes and Materials Group Department of Chemical EngineeringFaculty of Science and TechnologyMESA+Institute for NanotechnologyUniversity of TwentePO Box 2177500 AE EnschedeThe Netherlands Centre for Cooperative Research on Alternative Energies(CIC EnergiGUNE) Basque Research and Technology Alliance(BRTA)Vitoria-Gasteiz 01510Spain Institute of Physics&Institute of Chemistry Laboratory of Computational MaterialsFederal University of Mato GrossoCuiabá78060-900MTBrazil Brazilian Synchrotron Light Laboratory Brazilian Center for Research in Energy and MaterialsCampinas 13083-970SPBrazil Advanced Energy Storage Division LABCenter for Innovation on New EnergiesSchool of Chemical EngineeringUniversity of CampinasAv Albert Einstein 500Campinas 13083-852SPBrazil

Additives in the electrolytes of Li-S batteries aim to increase overall capacity,improve Li ion conductivity,enhance cyclability,and mitigate the shuttle effect,which is one of the major issues of this ***,the use of water as an additive in the commonly used electrolyte,1.0 M LiTFSI/1.0%(w/w) LiNO_(3) and a 1:1 mixture of 1,3-dioxolane(DOL) and 1,2-dimethoxyethane(DME) was *** used Co_(2)Mn_(0.5)Al_(0.5)O_(4)(CMA) as an electrocatalyst anchored on an activated carbon(AC) electrode with added sulfur via a melt-diffusion *** structural analysis of CMA via Rietveld refinement showed interatomic spaces that can promote ionic conductivity,facilitating Li^(+) ion *** tests determined 1600 ppm as the optimal water concentration,significantly reducing the shuttle ***-mortem XPS analysis focused on the lithium metal anode revealed the formation of Li_(2)O layers in dry samples and LiOH in wet *** capacity was observed in wet samples,which can be attributed to the superior ionic conductivity of LiOH at the electrode/electrolyte interface,surpassing that of Li_(2)O by 12 ***,Operando FTIR experiments provided real-time insights into electrolyte degradation and SEI formation,elucidating the activity mechanisms of water and Li_(2)CO_(3) over the *** work presents results that could aid future advancements in Li-S battery technology,offering possibilities to mitigate its challenges with inexpensive and scalable additives.

关键词： Diffusion Li-S Ionic conductivity Operando FTIR

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Cataracting-centrifuging transition investigation using nonspherical and spherical particles in a rotary drum through CFD simulations

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Particuology 2022年第1期20卷 48-60页

作者： Wanessa M.Benedito Claudio R.Duarte Marcos A.S.Barrozo Dyrney a.santos Institute of Chemistry Federal University of Goias-UFGCampus SamambaiaGoianiaGO74690-900Brazil School of Chemical Engineering Federal University of Uberlandia-UFUCampus Santa MonicaUberlandiaMG38408-144Brazil

This paper aims to systematically investigate the cataracting-centrifuging transition in a rotary drum involving spherical and nonspherical particles by using the Multiphase Granular Eulerian Model(MGEM).The effects of drum length and particle shape on the cataracting-centrifuging transition behavior were *** results showed that drum length plays an important role in the cataracting-centrifuging transition,although most related works in the literature do not consider *** particle shape also significantly affects the cataracting-centrifuging transition *** particles required lower rotation speeds than spherical particles to reach the centrifuging *** particle shape was shown to be related to the critical solid fraction(asc)from Schaeffer’s model,although further investigations are required to completely correlate particle spherecity with critical solid volume fractions.

关键词： Frictional viscosity MGEM model Particle shape Drum length Drum flow regimes

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A deep learned nanowire segmentation model using synthetic data augmentation

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npj Computational Materials 2022年第1期8卷 845-856页

作者： Binbin Lin Nima Emami David a.santos Yuting Luo Sarbajit Banerjee Bai-Xiang Xu Mechanics of Functional Materials Division Institute of Materials ScienceTechnische Universität Darmstadt64287DarmstadtGermany Department of Chemistry Texas A&M UniversityCollege StationTX77843USA

Automated particle segmentation and feature analysis of experimental image data are indispensable for data-driven material *** learning-based image segmentation algorithms are promising techniques to achieve this goal but are challenging to use due to the acquisition of a large number of training *** the present work,synthetic images are applied,resembling the experimental images in terms of geometrical and visual features,to train the state-of-art Mask region-based convolutional neural networks to segment vanadium pentoxide nanowires,a cathode material within optical density-based images acquired using *** results demonstrate the instance segmentation power in real optical intensity-based spectromicroscopy images of complex nanowires in overlapped networks and provide reliable statistical *** model can further be used to segment nanowires in scanning electron microscopy images,which are fundamentally different from the training dataset known to the *** proposed methodology can be extended to any optical intensity-based images of variable particle morphology,material class,and beyond.

关键词： nanowires networks particle

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Nanoparticles-based phototherapy systems for cancer treatment: Current status and clinical potential

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Bioactive Materials 2023年第5期23卷 471-507页

作者： Jiachen Li Shiqi Wang Flavia Fontana Christos Tapeinos Mohammad-Ali Shahbazi Huijie Han Helder a.santos Department of Biomedical Engineering W.J.Kolff Institute for Biomedical Engineering and Materials ScienceUniversity Medical Center GroningenUniversity of GroningenAnt.Deusinglaan 1Groningen9713 AVthe Netherlands W.J.Kolff Institute for Biomedical Engineering and Materials Science University Medical Center GroningenUniversity of GroningenUniversity of GroningenAntonius Deusinglaan 19713 AVGroningenthe Netherlands Drug Research Program Division of Pharmaceutical Chemistry and Technology Faculty of PharmacyUniversity of HelsinkiHelsinkiFI-00014Finland

Remarkable progress in phototherapy has been made in recent decades,due to its non-invasiveness and instant therapeutic *** addition,with the rapid development of nanoscience and nanotechnology,phototherapy systems based on nanoparticles or nanocomposites also evolved as an emerging hotspot in nanomedicine research,especially in *** this review,first we briefly introduce the history of phototherapy,and the mechanisms of phototherapy in cancer ***,we summarize the representative development over the past three to five years in nanoparticle-based phototherapy and highlight the design of the innovative nanoparticles ***,we discuss the feasibility and the potential of the nanoparticle-based phototherapy systems in clinical anticancer therapeutic applications,aiming to predict future research directions in this *** review is a tutorial work,aiming at providing useful insights to researchers in the field of nanotechnology,nanoscience and cancer.

关键词： Phototherapy Cancer Nanoparticles Therapeutic effect Clinical potential

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Mussel-Inspired and Bioclickable Peptide Engineered Surface to Combat Thrombosis and Infection

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Research 2022年第3期2022卷 91-104页

作者： Xiaohui Mou Hongbo Zhang Hua Qiu Wentai Zhang Ying Wang Kaiqin Xiong Nan Huang Hélder a.santos Zhilu Yang Affiliated Dongguan Hospital Southern Medical UniversityDongguanGuangdong 523059China Guangdong Provincial Key Laboratory of Shock and Microcirculation GuangzhouGuangdong 510080China Key Laboratory of Advanced Technologies of Materials Ministry of EducationSchool of Materials Science and EngineeringSouthwest Jiaotong UniversityChengdu 610031China Pharmaceutical Sciences Laboratory Åbo Akademi UniversityTurku Biosciences CenterUniversity of Turku andÅbo Akademi University20520 TurkuFinland State Key Laboratory of Molecular Engineering of Polymers Fudan UniversityShanghai 200438China Department of Biomedical Engineering and W.J.Kolff Institute for Biomedical Engineering and Materials Science University Medical Center Groningen/University of GroningenAnt.Deusinglaan 19713 AV GroningenNetherlands Drug Research Program Division of Pharmaceutical Chemistry and TechnologyFaculty of PharmacyUniversity of HelsinkiFI-00014 HelsinkiFinland

Thrombosis and infections are the two major complications associated with extracorporeal circuits and indwelling medical devices,leading to significant mortality in *** address this issue,here,we report a biomimetic surface engineering strategy by the integration of mussel-inspired adhesive peptide,with bio-orthogonal click chemistry,to tailor the surface functionalities of tubing and *** by mussel adhesive foot protein,a bioclickable peptide mimic(DOPA)4-azidebased structure is designed and grafted on an aminated tubing robustly based on catechol-amine ***,the dibenzylcyclooctyne(DBCO)modified nitric oxide generating species of 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid(DOTA)chelated copper ions and the DBCO-modified antimicrobial peptide(DBCO-AMP)are clicked onto the grafted surfaces via bio-orthogonal *** combination of the robustly grafted AMP and Cu-DOTA endows the modified tubing with durable antimicrobial properties and ability in long-term catalytically generating NO from endogenous snitrosothiols to resist adhesion/activation of platelets,thus preventing the formation of ***,this biomimetic surface engineering technology provides a promising solution for multicomponent surface functionalization and the surface bioengineering of biomedical devices with enhanced clinical performance.

关键词： DOTA generating Engine

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Development of a novel electrospun nanofibrous delivery system for poorly water-soluble β-sitosterol

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Asian Journal of Pharmaceutical Sciences 2016年第4期11卷 500-506页

作者： Urve Paaver Ivo Laidmae Hélder a.santos Jouko Yliruusi Jaan Aruvali Karin Kogermann Jyrki Heinamaki Faculty of Medicine Department of PharmacyUniversity of TartuNooruse150411 TartuEstonia Faculty of Pharmacy Division of Pharmaceutical Chemistry and TechnologyUniversity of HelsinkiViikinkaari 5EFI-00014HelsinkiFinland Institute of Ecology and Earth Sciences University of TartuRavila 14a50411 TartuEstonia

Electrospinning was used as a novel technique for fabricating polymeric nanofibers of a serum cholesterol lowering and poorly water-soluble plant sterol, β-sitosterol. Chitosan was used as a stabilizer/carrier polymer. The mean diameters of nanofibers ranged from 150 nm to218 nm. β-sitosterol was in an amorphous form and homogeneously dispersed in the nanofibers. The β-sitosterol-loaded nanofibers were freely water-soluble and exhibited very short lag-time in releasing the plant sterol. The dissolution was associated with an immediate recrystallization of β-sitosterol in submicron level. In conclusion, electrospinning is a promising future technology for the formulation of poorly water-soluble plant sterols.

关键词： Electrospinning Plant sterol β-sitosterol Nanofibers Solid-state properties Dissolution

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Programmable immune activating electrospun fibers for skin regeneration

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Bioactive Materials 2021年第10期6卷 3218-3230页

作者： Lu Chen Liucheng Zhang Hongbo Zhang Xiaoming Sun Dan Liu Jianming Zhang Yuguang Zhang Liying Cheng Hélder a.santos Wenguo Cui Department of Plastic and Reconstructive Surgery Shanghai Ninth People’s HospitalShanghai Jiao Tong University School of Medicine639 Zhi Zao Ju RoadShanghai 200011PR China Shanghai Key Laboratory for Prevention and Treatment of Bone and Joint Diseases Shanghai Institute of Traumatology and OrthopaedicsRuijin HospitalShanghai Jiao Tong University School of Medicine197 Ruijin 2nd RoadShanghai 200025PR China National Research Center for Translational Medicine Ruijin HospitalShanghai JiaoTong University School of Medicine197 Ruijin 2nd RoadShanghai 200025PR China Department of Pharmaceutical Sciences Laboratory and Turku Center for Biotechnology Åbo Akademi UniversityTurku FI-20520Finland Drug Research Program Division of Pharmaceutical Chemistry and TechnologyFaculty of PharmacyUniversity of HelsinkiHelsinki FI-00014Finland Helsinki Institute of Life Science(HiLIFE) University of HelsinkiHelsinki FI-00014Finland

Immune cells play a crucial regulatory role in inflammatory phase and proliferative phase during skin *** to programmatically activate sequential immune responses is the key for scarless skin *** this study,an“Inner-Outer”IL-10-loaded electrospun fiber with cascade release behavior was *** the inflammatory phase,the electrospun fiber released a lower concentration of IL-10 within the wound,inhibiting excessive recruitment of inflammatory cells and polarizing macrophages into anti-inflammatory phenotype“M2c”to suppress excessive inflammation *** the proliferative phase,a higher concentration of IL-10 released by the fiber and the anti-fibrotic cytokines secreted by polarized“M2c”directly acted on dermal fibroblasts to simultaneously inhibit extracellular matrix overdeposition and promote fibroblast ***“Inner-Outer”IL-10-loaded electrospun fiber programmatically activated the sequential immune responses during wound healing and led to scarless skin regeneration,which is a promising immunomodulatory biomaterial with great potential for promoting complete tissue regeneration.

关键词： Electrospun fiber Drug release Skin regeneration Immune response Macrophages

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Randomized controlled trial comparing open anterograde anatomic radical retropubic prostatectomy with retrograde technique

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Asian Journal of Urology 2023年第2期10卷 151-157页

作者： Fabricio B.Carrerette Daniela B.Rodeiro Rui T.F.Filho Paulo a.santos Celso C.Lara Ronaldo Damiao Department of Surgery(Urology) Pedro Ernesto University Hospital of State University of Rio de JaneiroRio de JaneiroBrazil

Objective:Radical prostatectomy is the recommended treatment for localized prostate cancer;however,it is an invasive procedure that can leave serious ***-assisted radical prostatectomy was introduced with the aim of reducing postoperative morbidity and facilitating rapid recovery compared to the traditional Walsh’s open radical retropubic ***,a protocol was developed to perform an open prostatectomy comparable to that performed by robotics,but without involving novel ***:A total of 220 patients diagnosed with localized prostate cancer underwent radical *** were divided into two groups:anterograde technique(115 patients)and the retrograde method(105 patients).The study outcomes were observed 3 months after ***:No differences were found in terms of surgical time,hospital stay,and suction ***,reduced bleeding was observed in the anterograde technique(p=0.0003),with rapid anastomosis duration(p=0.005).Among the patients,60.9% undergoing the anterograde technique were continent 3 months after surgery compared to 42.9%treated by the retrograde method(p=0.007).Additionally,fewer complications in terms of the number(p=0.007)and severity(p=0.0006)were observed in the anterograde ***:The anterograde method displayed increased efficiency in reducing complications,compared to the retrograde technique.

关键词： Prostatectomy Localized prostate cancer Vesicourethral anastomosis Continence

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An unsettling explanation for the failure of skatole-baited ovitraps to capture Culex mosquitoes

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Insect Science 2019年第5期26卷 873-880页

作者： Marcelo H.S.Paiva Rosangela M.R.Barbosa Suzane a.santos Norma M.Silva Marcia B.Paula Constancia F.J.Ayres Walter S.Leal Depariamento de Entomologia Instituto Aggeu MagalhaesFundagao Oswaldo CruzAv. Professor Moraes RegoRecifePEBrazil CentroAcademicodoAgreste Universidade Federalde Pernambuco CaruaruPEBrazil Departamentode Biologia Celular Embriologia e GeneticaCentro de Ciencias Biologicas Universidade Federal de Santa CatarinaFlorianopolisSC.Brazil Faculdade de Saude PCiblica Departamento de Epidemiologia Universidade de Sao PauloSao PauloSPBrazil Department of Molecular and Cellular Biology University of California-DavisDavisCaliforniaUSA

Culex mosquitoes are primarily found in temperate and tropical regions worldwide where they play a crucial role as main vectors of filarial worms and arboviruses. In Recife, a northeast city in Brazil, high densities of Culex quinquefasciatus are often found in association with human populated areas. In marked contrast to another part of the city, field tests conducted in the neighborhood of Sitio dos Pintos showed that trapping of mosquitoes in skatole-baited ovitraps did not differ significantly from captures in control (water) traps. Thus, classical and molecular taxonomic approaches were used to analyze the Culex species circulating in Sitio dos Pintos. Results obtained from both approaches agreed on the cocirculation of Culex quinquefasciatus and Culex nigripalpus in three different areas of this neighborhood. What was initially considered as an unexpected failure of this lure turned out to be a more unsettling problem, that is, the first report in Recife of Culex nigripalpus, a vector of Venezuelan equine encephalitis virus and West Nile virus. Unplanned urbanization processes close to remnants of the Atlantic forest, such as observed in Sitio dos Pintos, may have contributed to the introduction of Cx. nigripalpus in urban areas.

关键词： Culex quinquefasciatus Culex nigripalpus dengue oviposition attractant skatole West Nile virus Zika

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