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Bio-regeneration of p-complexation desulfurization adsorbents

Science china Chemistry 2005年第6期48卷 538-544页

作者： LI Wangliang1,2. XING Jianmin1, XIONG Xiaochao1,2. SHAN Guobin1,2.& LIU Huizhou1 1. Laboratory of Separation Science and Engineering, Institute of Process Engineering, chinese academy of sciences, beijing 100080,{2. 2. Graduate school of the chinese academy of sciences,beijing 10003.,{2. 1. Laboratory of Separation Science and Engineering Institute of Process Engineering Chinese Academy of Sciences 100080 Beijing China 2. Graduate school of the chinese academy of sciences 100039 Beijing China

The coupling of adsorption desulfurization and biodesulfurization is a new approach to produce clean fuels. Sulfur compounds are firstly adsorbed on adsorbents, and then the ad-sorbents are regenerated by microbial conversion. p-Complexation adsorbent, Cu(I)-Y, was ob-tained by ion exchanging Y-type zeolite with Cu2. and then by auto-reduction in helium at 450℃ for 3 h. Dibenzothiophene (DBT) was used as a model compound. The effects of cell concentra-tion, volume of oil phase, the ratio of aqueous phase to adsorbent on DBT desorption by a bac-terium were studied. The amounts of DBT desorbed and 2.HBP produced can be apparently increased with addition of n-octane. BDS activity can be improved by increasing cell concentra-tion and the ratio of water-to-adsorbent. 89% of DBT desorbed from the adsorbents can be converted to 2.HBP within 6 h and almost 100% within 2. h, when the volume ratio of oil-to-water was 1/5 mL/mL, the cell concentration was 60 g·L?1, and the ratio of adsorbent-to-oil was 0.03 g·mL?1. The amount of 2.HBP produced was strongly dependent on the volume ratio of oil-to- water, cell concentration and amount of adsorbent. Adsorption capacity of the regenerated ad-sorbent is 95% that of the fresh one after being desorbed with Pseudomonas delafieldii R-8, washed with n-octane, dried at 100℃ for 2. h and auto-reduced in He.

关键词： adsorption desulfurization p-complexation adsorbents bio-regeneration Pseudomonas delafieldii desorption.

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The deep thermal characteristic of continental margin of the northern South china Sea

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chinese Science Bulletin 2000年第18期45卷 1717-1722页

作者： ZHANG Jian & WANG Jiyang1. Graduate school, University of Science and Technology of china,{2., beijing 10003., china 2. Institute of Geology,{2., beijing 10002., china Graduate school University of Science and Technology of China Chinese Academy of Sciences Beijing China Institute of Geology Chinese Academy of Sciences Beijing China

Heat flow plays an important role in the study ot thermal structure and thermal evolutionof continental margin of the northern South china Sea. The analysis of heat flow value shows that margin heat flow in the northern South china Sea is relatively high setting, but the percentage of crustal heat flow is lower than 35% in terrestrial heat flow. The terrestrial heat flow exhibited a current of rise from the Northern Continental Margin to the Southern Central Basin. However, the proportion of crustal heat flow in terrestrial heat flow slowly dropped down in the same direction. It is suggested that the main factor causing high heat flow setting is the moving up of hot material from asthenosphere.

关键词： margin of northern South china Sea terrestrial heat flow thermal structures.

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Biologically effective ultraviolet radiation in beijing area

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Journal of Environmental sciences 1993年第2期5卷 216-223页

作者： Wang Shaobin Su WeihanResearch Center for Eco-Environmental sciences, chinese academy of sciences, {2. 100085, china Research Center for Eco-Environmental sciences Chinese Academy of Sciences Beijing 100085 China. China

Ozone layer depletion implies the enhancement of solar ultraviolet radiation at the earth's surface. However, aerosol contributes to the scattering of solar radiation and leads to the reduction of UV-B radiation on the ground. In this paper, the model calculation shows that due to effects of atmospheric ozone and aerosol UV-B radiation in beijing in the past decade has decreased with the annual change rate of 0.7%, which is probably approximate to the measured values. The effects of three scenarios for long-term changes in atmospheric ozone and aerosol concentrations on UV-B radiation reaching the ground in are also discussed.

关键词： UV-B biological efftent zone aerosol beijing.

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Explicit analytical solutions of the anisotropic Brinkman model for the natural convection in porous media(Ⅱ)

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Science china(Physics,Mechanics & Astronomy) 2005年第4期48卷 422-430页

作者： CAI Ruixian1, GOU Chenhua1, 2.& ZHANG Na1 1. Institute of Engineering Thermophysics, chinese academy of sciences, beijing 100080,{2. 2. Graduate school, chinese academy of sciences, beijing 100080,{2. 1. Institute of Engineering Thermophysics Chinese Academy of Sciences 100080 Beijing China 2. Graduate school Chinese Academy of Sciences 10080 Beijing China

Some algebraically explicit analytical solutions are derived for the anisotropic Brinkman model―an improved Darcy model―describing the natural convection in porous media. Besides their important theoretical meaning (for example, in analyzing the non-Darcy and anisotropic effects on the convection), such analytical solutions can be the benchmark solutions that can promote the development of computational heat and mass transfer. Some solutions considering the anisotropic effect of permeability have been given previously by the authors, and this paper gives solutions including the anisotropic effect of thermal conductivity and the effect of heat sources.

关键词： explicit analytical solution, porous medium, natural convection, Brinkman model, anisotropic.

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Structures and physical properties of rigid polyurethane foams with water as the sole blowing agent

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Science china Chemistry 2006年第4期49卷 363-370页

作者： LI Xiaobin1,2. CAO Hongbin1 & ZHANG Yi1 1. Institute of Process Engineering, chinese academy of sciences, beijing 100080,{2. 2. Graduate school of the chinese academy of sciences, beijing 10003.,{2. 1. Institute of Process Engineering Chinese Academy of Sciences Beijing 100080 China 2. Graduate school of the chinese academy of sciences Beijing 100039 China

Rigid polyurethane foams blown by varying water level were prepared in this study. The structures and physical properties of rigid polyurethane foams blown by water were measured with FT-IR, universal testing machine (Instron3365), scanning electron microscope (SEM) and differential scanning calorimeter (DSC). The results show that polyurea and polybiuret were the typical charac- teristics, and the cream time and gel time were shorter for the fully water blown rigid foams than that for the fully cyclopentane blown foams. The density of foam samples decreased from 45.0 kg/m3 to 2..4 kg/m3 with the increase of water level from 3 pph to 7 pph. Compressive strength exhibited the similar behavior with density. The average cell size of foam samples ranged from 2.1 μm to 356 μm with the increase of water level from 3 pph to 7 pph, respectively. At the same time, poorer dimen- sional stability was encountered with the increase of average cell size due to fast diffusion rate of CO2.out of the foam. The results of thermal analysis show that the glass transition temperature (Tg) shifted to a higher temperature with the increase of isocyanate level when more water was used as chemical blowing agent.

关键词： polyether polyol, polyurethane rigid foam, compressive strength, dimensional stability, cell size, glass transition temperature.

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Determination of atmospheric concentrations of halocarbons in beijing area

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Journal of Environmental sciences 1993年第1期5卷 76-82页

作者： Wang ShaobinResearch Center for Eco-Environmental sciences, chinese academy of sciences, {2. 100085, chinaPeng Lixin and Tang XiaoyanResearch Center of Environmental sciences, Peking University, {2. 100871, china Research Center for Eco-Environmental sciences Chinese Academy of Sciences Beijing 100085 China. China

Gas chromatography with ambient temperature injection and frozen-trapped techniques was used to determine the atmospheric concentrations of halocarbons over beijing. Halogenated compounds such as CFC-11, CFC-12. CHCl_3, CCl_4, CH_3CCl_3, CHCl =CCl_2. and CCl2.CCl2.were measured and their concentrations are 109±8, 2.4±13, 47±2., 97±2., 88±2., 11±1 and 17±3 (pptv), respectively.

关键词： GC-ECD atmospheric halocarbons beijing.

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Assessing the Carrying Capacity of Tourist Resorts: An Application of Tourists’ Spatial Behavior Simulator Based on GIS and Multi-Agent System

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Wuhan University Journal of Natural sciences 2005年第4期10卷 779-784页

作者： ZHANG Ren-jun 1,2.1. Institute of Mountain Hazards and Environment, chinese academy of sciences, Chengdu 610041, Sichuan, china 2. Graduated {2. of the chinese academy of sciences, beijing 10003., china chinese academy of {2. Institute of Mountain Hazards and Environment Chengdu Sichuan China (GRID:grid.9227.e) (ISNI:***) Graduated school of the chinese academy of sciences Beijing China (GRID:grid.9227.e) (ISNI:***)

Based on the study of visitors' individual spatial behaviors, a tourists'spatial behavior simulator (TSBS) to assess the carrying capacity of tourist resorts was developed,TSBS employs GIS (Geographic Information System) to manage the spatial data,and Multi-Agent systemto simulate the actions of individual visitors. By utilizing TSBS, visitors' travel patterns such aslocation, cost, and state can be analyzed and predicted. Based on this analysis and prediction, themodel of assessing the carrying capacity of resorts is built. Our results show that TSBS will be aneffective tool to accurately assess the carrying capacity of tourist resorts.

关键词： tourist resort carrying capacity TSBS GIS Multi-Agent simulator

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SHRIMP ages of detrital zircons from the Changcheng System in the Ming Tombs area,beijing:Constraints on the protolith nature and maximum depositional age of the Mesoproterozoic cover of the North china Craton

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chinese Science Bulletin 2003年第22期48卷 2500-2506页

作者： WAN Yusheng1,2. ZHANG Qiaoda1 & SONG Tianrui1 1. Institute of Geology, chinese academy of Geological {2., beijing 10003., china 2. beijing SHRIMP Laboratory, beijing 10003., china Correspondence should be addressed to Wan Yusheng (e-mail: wanyusheng@***) Institute of Geology Chinese Academy of Geological Sciences Beijing 100037 China

The Mesoproterozoic Changcheng System is widely distributed in the North china Craton. Determining its time of deposition and sources is important to understand the Precambrian crustal evolution of the North china Craton. This paper suggests age distribution patterns for detrital zircons from clastic sediments of the Changcheng System in the Ming Tombs area, {2.. Samples of feldspar-bearing sandstone (CHc-2. and pure sandstone (CHc-9) were collected from the Changzhougou Formation, which constitutes the basal part of the Changcheng System. Detrital zircons show an age range from 2.35 to 2.60 Ga. However, sample CHc-9 in the upper Changzhougou Formation also contains some zircons with ages of 1.9-1.8 Ga and 2.3-2.1 Ga. The age patterns lead to the following conclusions: (1) Most of the detrital material came from a source area composed predominantly of ~2.5 Ga continental crust of the North china Craton; (2. 1.9-1.8 Ga reflects the age record of Palaeoproterozoic continent-continent collisional event in the North china Craton; and (3) the oldest age for deposition of the Changcheng System is 1.8 Ga.

关键词：锆石原岩中国北部地区地壳演变

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Molecular cloning of growth hormone receptor (GHR) from common carp(Cyprinus carpio L.)and identification of its two forms of mRNA transcripts

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Progress in Natural Science:Materials International 2006年第11期16卷 1156-1163页

作者： SUN Xiaofeng~ 1,2., GUO Qionglin~1**, HU Wei~1, WANG Yaping~1 and ZHU Zuoyan~1(1. State Key Laboratory of Freshwater Ecology and Biotechnology, Institute of Hydrobiology, chinese academy of sciences, Wuhan 430072. china 2. Graduate {2. of chinese academy of sciences, beijing 10003., china) [a]State key Laboratory of Freshwater Ecology and Biotechnology Institute of Hydrobiology Chinese Academy of Sciences Wuhan China China [b]Graduate school of chinese academy of sciences Beijing China

The cDNA of growth hormone receptor (GHR) was cloned from the liver of 2.year common carp (Cyprinus carpio L.) by reverse transcription-polymerase chain reaction (RT-PCR) and rapid amplification of cDNA end (RACE). Its open reading frame (ORF) of 1806 nucleotides is translated into a putative peptide of 602.amino acids, including an extracellular ligand-binding domain of 2.4 amino acids (aa), a single transmembrane domain of 2. aa and an intracellular signal-transduction domain of 334 aa. Sequence analysis indicated that common carp GHR is highly homologous to goldfish (Carassius auratus) GHR at both gene and protein levels. Using a pair of gene-specific primers, a GHR fragment was amplified from the cDNA of 2.year common carp, a 2.4 bp product was identified in liver and a 32. bp product in other tissues. The sequencing of the products and the partial genomic DNA indicated that the difference in product size was the result of a 97 bp intron that alternatively spliced. In addition, the 32. bp fragment could be amplified from all the tissues of 4-month common carp including liver, demonstrating the occurrence of the alternative splicing of this intron during the development of common carp. Moreover, a semi-quantitative RT-PCR was performed to analyze the expression level of GHR in tissues of 2.year common carp and 4-month common carp. The result revealed that in the tissues of gill, thymus and brain, the expression level of GHR in 2.year common carp was significantly lower than that of 4-month common carp.

关键词： growth hormone receptor (GHR) molecular cloning transcript expression analysis common carp.

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Wind vector retrieval using dual polarization imagery of ASAR

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Progress in Natural Science:Materials International 2006年第11期16卷 1183-1187页

作者： SONG Guiting~ 1,2., HOU Yijun~1** and QI Peng~1(1. Institute of Oceanology, chinese academy of sciences, Qingdao 2.6071, china 2. Graduate {2., chinese academy of sciences, beijing 10003., china) [a]Institute of Oceanology Chinese Academy of Science Qingdao China [b]Graduate school Chinese Academy of Sciences Beijing China

A new algorithm for retrieving wind vector using dual polarization imagery of advanced synthetic aperture radar (ASAR) is developed and tested. Based on the combination of co-polarization and cross-polarization, this new algorithm effectively eliminates the 180° ambiguity which occurs when using single imagery of the ASAR to retrieve wind vector. This algorithm also solves the problem that the retrieval results will break down on very small spatial scales. The results retrieved from dual polarization imagery of ASAR show that the wind speed and direction are in agreement with the data from Quikscat and buoy measurements. The root mean square errors of wind direction and speed between the retrieved results and data from Quikscat are 2.2.° and 0.53 m/s, respectively. Comparisons between the new method and the traditional method show that the new methods fit the buoy data and Quikscat data a little better than the traditional method in this image.

关键词： wind vector retrieval ASAR dual polarization.

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