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Pressure-induced Elastic Anomaly in a Polyamorphous Metallic...

Pressure-induced Elastic Anomaly in a Polyamorphous Metallic Glass

作     者:Zeng Qiaoshi Zeng Zhidan Lou Hongbo Kono Yoshio Zhang Bo Curtis Kenney-Benson Park Changyong Mao Wendy L. 

作者单位:Center for High Pressure Science and Technology Advanced Research (HPSTAR) HPCAT Geophysical Laboratory Carnegie Institution of Washington Institute of Amorphous Matter Science School of Materials Science and Engineering & Anhui Provincial Key Lab of Functional Materials and Devices Hefei University of Technology Geological Sciences Stanford University Stanford Institute for Materials and Energy Sciences SLAC National Accelerator Laboratory 

会议名称:《第十一届中国钢铁年会》

会议日期:2017年

学科分类:08[工学] 080502[工学-材料学] 0805[工学-材料科学与工程(可授工学、理学学位)] 

摘      要:The pressure-induced transitions discovered in metallic glasses(MGs) have attracted considerable research interest offering an exciting opportunity to study polyamorphism in densely packed *** the large body of work on these systems, the elastic properties of the MGs during polyamorphic transitions remain *** this work, using an in situ high-pressure ultrasonic sound velocity technique integrated with synchrotron radiation x-ray radiography and x-ray diffraction in a Paris-Edinburgh cell, we precisely determined both the compressional and shear wave sound velocities of a CeAlCuCo metallic glass up to 5.8 GPa through its polyamorphic ***, its elastic moduli and Poisson’s ratio versus pressure were all *** the first time, we observed elastic anomalies with minima(at .5 GPa) in the sound velocities, bulk modulus, and Poisson’s ratio of a metallic *** with the compression behaviors of the silica glass and the crystalline Ce in detail, we conclude that the elastic anomaly is closely associated with the pressure-induced *** addition, sound velocities have been extensively used to calculate the density of glasses under *** found that the density of CeAlCuCo metallic glass calculated from sound velocities obviously deviated from the directly measured density when a polyamorphic transition *** results suggest that the density-sound velocity relationship may be invalid in glasses with a polyamorphic transition, although the transition is continuous.

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