Optical Properties,Electronic Energy Level Structure and Electroluminescent Characteristics of a new electroluminescent materials:(N,N'-bis(salicylidene)-ethylenediamine) zinc

作     者：HAO Yu-ying~1 GUO Hai-bo~1 WANG Hua~2 LIU Xuguang~3 XU Bing-she~2 1.Department of Physics,Taiyuan University of Technology Taiyuan 030024,China 2.Key Laboratory of Interface Science and Engineering in Advanced Materials of Taiyuan University of Technology,Ministry of Education 3.College of Materials Science and Engineering,Taiyuan University of Technology Taiyuan,West Yingze Street No.79,Taiyuan 030024,China 

会议名称：《第11届全国发光学学术会议》

会议日期：2007年

学科分类：0809[工学-电子科学与技术（可授工学、理学学位）] 07[理学] 070205[理学-凝聚态物理] 08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 0702[理学-物理学] 

摘      要：A new EL material,(N,N’-bis(salicylidene)-ethylenediamine)zinc (Zn(salen))was synthesized and ***(salen)exhibited high thermal stability,excellent thin film forming *** HOMO,LUMO and electrochemical band gap were estimated to be -5.87 eV, -3.41 eV,and 2.46 eV by cyclic voltammetry,***(salen)powder exhibited bright blue emitting,but Zn(salen)film exhibited yellow emitting under radiation of 365 *** device ITO/CuPc/NPDIZn(salen)/Al could emit yellow *** EL peak was at about 555 nm with CIE coordinates ofx=0.504,y=*** device had a turn-on voltage of about 7.5 V and a brightness of about 301 cd/m at 30 *** current efficiency is about 1.6 cd/A.