Fabrication of copper (Ⅰ) nitride nanorods within SBA-15 by metal organic chemical vapor deposition

作     者：ZHANG Ying1,2, Frank Leung-Yuk Lam2, YAN ZiFeng1 & HU XiJun2 1 School of Chemistry & Chemical Engineering, China University of Petroleum, Dongying 257061, China 2 Department of Chemical Engineering, Hong Kong University of Science and Technology, Hong Kong, China 

作者机构：School of Chemistry & Chemical Engineering China University of Petroleum Dongying China Department of Chemical Engineering Hong Kong University of Science and Technology Hong Kong China 

出 版 物：《Science China(Technological Sciences)》 (中国科学（技术科学英文版）)

年 卷 期：2009年第52卷第2期

页      面：352-356页

核心收录：

学科分类：0810[工学-信息与通信工程] 07[理学] 070205[理学-凝聚态物理] 08[工学] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0702[理学-物理学] 0812[工学-计算机科学与技术（可授工学、理学学位）] 

基　　金：Supported by the Research Grants Council (RGC) of Hong Kong under the Central Allocation Vote scheme (Grant No.CA04/05.SC02) the CERG scheme (Grant No.600707) 

主　　题：nanorods copper nitride CVD SBA-15 

摘      要：Copper (Ⅰ) nitride nanorods grown in channels of mesoporous silica SBA-15 by chemical vapor deposition method has been synthesized. The morphology and microstructure of the resulting product were characterized by XRD patters, TEM images, EDS analysis and Raman spectra. The XRD and TEM revealed that the Cu3N phase was confined in channels of SBA-15 forming continuous nanowires with 6 nm around and hundreds of nanometers in length. Raman spectra of the final product and pure Cu3N showed peaks shift due to the quantum confinement effect of the nanowires. This preparation methodology only requires a mild working condition and is capable of template synthesis of other binary nitride nanostructures with controlled morphology inside the channels of mesoporous materials.