Recent Progress on Metal–Organic Framework and Its Derivatives as Novel Fire Retardants to Polymeric Materials

作     者：Jing Zhang Zhi Li Xiao‑Lin Qi De‑Yi Wang Jing Zhang;Zhi Li;Xiao?Lin Qi;De?Yi Wang

作者机构：IMDEA Materials InstituteC/Eric Kandel 228906 GetafeMadridSpain Universidad Politécnica de MadridE.T.S.de Ingenieros de Caminos28040 MadridSpain China‑Spain Collaborative Research Center for Advanced MaterialsSchool of Materials Science and EngineeringChongqing Jiaotong UniversityChongqing 400074People’s Republic of China 

出 版 物：《Nano-Micro Letters》 (纳微快报（英文版）)

年 卷 期：2020年第12卷第12期

页      面：173-193页

核心收录：

学科分类：0808[工学-电气工程] 0809[工学-电子科学与技术（可授工学、理学学位）] 08[工学] 0817[工学-化学工程与技术] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 0702[理学-物理学] 

基　　金：This research is partly supported by the scholarship from China Scholarship Council under the Grant CSC(201608060071). 

主　　题：Metal–organic frameworks Hybrids Polymers Composites Fire retardancy 

摘      要：High flammability of polymers has become a major issue which has restricted its applications.Recently,highly crystalline materials and metal–organic frameworks(MOFs),which consisted of metal ions and organic linkers,have been intensively employed as novel fire retardants(FRs)for a variety of polymers(MOF/polymer).The MOFs possessed abundant transition metal species,fire-retardant elements and potential carbon source accompanied with the facile tuning of the structure and property,making MOF,its derivatives and MOF hybrids promising for fire retardancy research.The recent progress and strategies to prepare MOF-based FRs are emphasized and summarized.The fire retardancy mechanisms of MOF/polymer composites are explained,which may guide the future design for efficient MOF-based FRs.Finally,the challenges and prospects related to different MOFbased FRs are also discussed and aim to provide a fast and holistic overview,which is beneficial for researchers to quickly get up to speed with the latest development in this field.