Frustrated Lewis Pairs:Discovery and Overviews in Catalysis

作     者：Nan Li Wen-Xiong Zhang Nan Li;Wen-Xiong Zhang

作者机构：Beijing National Laboratory for Molecular Sciences(BNLMS)Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of EducationCollege of ChemistryPeking UniversityBeijing 100871China Henan Key Laboratory of Function-Oriented Porous MaterialsCollege of Chemistry and Chemical EngineeringLuoyang Normal UniversityLuoyangHenan 471934China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2020年第38卷第11期

页      面：1360-1370页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：This work was supported by the National Natural Science Foundation of China(Nos.21725201 and 21890721).We thank Mr.Zhubao Yin for his early writing 

主　　题：processes. chemistry bases 

摘      要：Frustrated Lewis Pairs(FLPs)are derived from simple combinations of Lewis acids(electron acceptors)and Lewis bases(electron donors),in which steric demands prevent from forming classical Lewis acid-base *** 2006,FLP chemistry has emerged as a novel strategy for the design and application of main-group chemistry and development of new metal-free catalytic *** strategy has been applied to stoichiometric reactivity and then extended to *** this review,we briefly summarize the representative discoveries and developments of FLP chemistry in the field of catalysis,including hydrogenation,hydrosilylation,reduction of C 02/transformations of alkynes to organic derivatives,C—H bond borylation and polymerization.