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Catalytic oxidation of low concentration formaldehyde over Pt/TiO_(2) catalyst

Catalytic oxidation of low concentration formaldehyde over Pt/TiO2 catalyst

作     者:Yuan Su Keming Ji Jiayao Xun Kan Zhang Ping Liu Liang Zhao Yuan Su;Keming Ji;Jiayao Xun;Kan Zhang;Ping Liu;Liang Zhao

作者机构:State Key Laboratory of Coal ConversionInstitute of Coal ChemistryChinese Academy of SciencesTaiyuan 030001China State Key Laboratory of Heavy Oil ProcessingChina University of PetroleumBeijing 102249China 

出 版 物:《Chinese Journal of Chemical Engineering》 (中国化学工程学报(英文版))

年 卷 期:2021年第34卷第1期

页      面:190-195页

核心收录:

学科分类:083002[工学-环境工程] 0830[工学-环境科学与工程(可授工学、理学、农学学位)] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 080502[工学-材料学] 0805[工学-材料科学与工程(可授工学、理学学位)] 

基  金:supported by the CAS (Chinese Academy of Sciences) Strategic Priority Research Program (XDA-21020500) 

主  题:Catalyst support Catalysis Fixed-bed Pt/TiO_(2) 

摘      要:Formaldehyde(HCHO) is an important indoor *** oxidize low concentration HCHO is an effective way to eliminate indoor *** this study,a series of Pt/TiO_(2) catalysts are prepared by impregnation and reduced by NaBH_*** effects of loading amount of Pt and cry stal type of TiO_(2) on the physical and chemical properties and the catalytic performance in HCHO oxidation reaction are *** results show that the quantity of active site and the oxygen vacancy of catalysts increa sed with increasing Pt content,which is beneficial to promote the further performance of ***,with the further rises of Pt content,the specific surface area further decreases,and the proportion of Pt^(2+) species on the catalyst surface which is significant to catalytic properties also decreases,causing catalytic performance *** with the catalyst supporting on rutile,the Pt/α-TiO_(2) catalyst supporting on anatase has larger specific surface area,more Pt^(2+) phase and easier to form oxygen vacancy in the support,which cause better catalytic *** catalyst with Pt content of0.1 wt% and supported by anatase TiO_(2) has the best catalytic *** HCHO conversion efficiency reaches 98% and 100% at 50℃ and 100 ℃, and the stabilization time is longer than 140 h.

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