Synthesis and Characterization of One-dimensional and Two-Dimensional Porphyrin Polymers (Ⅰ)

作     者：LI Xiang-qing, WANG Xing-qiao, GUO Jing-fu, MENG He and LJU Guo-fa (Department of Chemistry, Jilin University, Changchun 130023, P. R. China) 

作者机构：吉林大学 吉林 长春 130023 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)

年 卷 期：2001年第17卷第2期

页      面：226-227页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：the National Natural Science Foundation of China 

主　　题：Synthesis Porphyrin polymer Bipyridine Imidazole 

摘      要：A procedure for the synthesis of one-dimensional tetraaminophenylporphyrin (TAPP) was described. Quantitative infrared (IR) spectrum analysis of the monomer showed that it exhibited strong absorption at 1,621 cm-1. Results also indicated that the interaction between porphyrin macrocycles was enhanced after the metalloporphyrin linked up with the axial ligand. The degree of polymerization in [Mn(TPP)(pyz)]n was assessed using the ligand absorption rate.