Effects of In-situ Generated Coinage Nanometals on Crystallization and Microstructure of Fluorophlogopite Mica Containing Glass-Ceramics

作     者：Mrinmoy Garai Nibedita Sasmal Atiar Rahaman Molla Anal Tarafder Basudeb Karmakar 

作者机构：Glass Science & Technology SectionGlass DivisionCSIR-Central Glass & Ceramic Research Institute 

出 版 物：《Journal of Materials Science & Technology》 (材料科学技术（英文版）)

年 卷 期：2015年第31卷第1期

页      面：110-119页

核心收录：

学科分类：07[理学] 070205[理学-凝聚态物理] 08[工学] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 0702[理学-物理学] 

基　　金：Dr.R.N.Basu Fuel Cell and Battery Division of CSIR-CGCRI for financial support through NMITLI-CSIR sponsored project on solid oxide fuel cell(TLP 0005) 

主　　题：Glass Crystallization X-ray diffraction Microstruc 

摘      要：The effects of in-situ generated coinage nanometals（Cu,Ag and Au） on crystallization behavior,microstructure,thermal and mechanical properties of SiO2-MgO-Al2O3-B2O3-K2O-MgF2（BMAPS） glassceramics were systematically *** addition of coinage nanometai,the glass transition temperature（Tg） is increased by 20-30 ℃,crystallization temperature（Tc） by 30-50 ℃ and dilatometric softening temperature（Td） by 10-25 ℃.It was found that the density of Cu-containing glass was 2.59 g cm-3and for other glasses it was in the range of 2.56-2.57 g *** the non-isothermal differential scanning calorimetry study,the activation energy of crystallization for BMAPS base glass was calculated as 344 kJ/mol,and changed to 406,334 and 274 kJ/mol on addition of Cu,Ag and Au-nanometals,*** evolved in the opaque BMAPS glass-ceramics derived by controlled heat treatment,were identified as fluorophlogopite mica(KMg3(AlSi3O10)F2) by X-ray diffraction（XRD） technique and confirmed by Fourier transformed infrared *** of copper,silver and gold nanometals were also identified by XRD *** is found from field emission scanning electron microscopy that the interlocked grain like microstructure developed in BMAPS glass-ceramics（being heat-treated at 1050 ℃ for 4 h） changed to denser house-of-cards like microstructure（containing smaller sized mica crystals） on addition of coinage *** of BMAPS base glass-ceramic was 2.60 g cm-3and marginally changed to 2.61-2.62 g cm-3on addition of Cu,Ag and *** change in microstructure resulted in the decrease of Vickers micro hardness value from 5.37 to 4.12,4.20 and 4.58 GPa on addition of Cu,Ag and Au,*** nanometai doped mica glass-ceramics containing interlocked microstructure with higher thermal expansion coefficient,hence,is suitable for high temperature sealing application（like solid oxide fuel cell）.