Liquid phase in-situ synthesis of LiF coated boron powder composite and performance study

作     者：Yang Xu Qing-zhong Cui Cheng-wen Zhao Yang Xu;Qing-zhong Cui;Cheng-wen Zhao

作者机构：State Key Laboratory of Explosion Science and TechnologyBeijing Institute of TechnologyBeijing 100081China Shanxi Jiangyang Chemical FactoryShanxi 030000China 

出 版 物：《Defence Technology（防务技术）》 (Defence Technology)

年 卷 期：2020年第16卷第3期

页      面：635-641页

核心收录：

学科分类：08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 

基　　金：This work was supported by the National Natural Science Foundation of China(Grant No.:3020050321328) 

主　　题：Boron LiF Coating Thermal decomposition properties Energy efficiency 

摘      要：Among practical metal additives,boron(B) has a high volumetric heating value,making it a promising choice as a fuel *** B can theoretically yield a large amount of energy upon complete combustion,its combustion is retarded by the initial presence of B oxide,which coats the surfaces of B *** improve the ignition and combustion properties of B powder,LiOH and NH4F were used as precursors to synthesize uniformly LiF-coated B composites(LiF-B) in *** LiF-B mixture was also prepared for comparison using a physical method.X-ray diffraction(XRD),Fourier-transform infrared(FTIR),scanning electron microscope(SEM),and energy-dispersive X-ray spectroscopy(EDS) were used to characterize the morphologies and compositions of the *** thermal and combustion properties of the samples were characterized by thermal gravity-differential thermal gravity(TG-DTG),differential scanning calo rimetry(DSC) and closed bomb *** XRD,FTIR,SEM and EDS results demonstrated the successful preparation of the coated LiF-B *** TG-DTG and closed bomb experiment results indicated that the addition of LiF decreased the ignition temperature of B powder,and increasing its reaction *** results show that when LiF-B was added,the released heat of underwater explosive increased by 6727.2,7280.4 and 3109.6 J/g at heating rates of 5,10,and 15℃/min,***,LiF-B decreased the activation energy of secondary combustion reaction of explosive system as calculated through Kissinger’s method by 28.9%,which indicated an excellent catalytic effect for the thermal decomposition of underwater *** results reveal that LiF can improve the combustion efficiency of B powder,thereby increasing the total energy of *** mechanical sensitivity increased slightly after adding LiF-B to the underwater *** mpared to the underwater explosive with added B,the mechanical sensitivity of the explosive with added LiF-B was significantly