MOF derived Co3O4/N-doped carbon nanotubes hybrids as efficient catalysts for sensitive detection of H2O2 and glucose

作     者：Yingnan Qin Yingjun Sun Yingjie Li Chunji Li Lei Wang Shaojun Guo Yingnan Qina;Yingjun Sun;Yingjie Li;Chunji Li;Lei Wang;Shaojun Guo

作者机构：College of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdao 266042China Department of Materials Science and EngineeringDepartment of Biomedical EngineeringCollege of EngineeringPeking UniversityBeijing 100871China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2020年第31卷第3期

页      面：774-778页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070205[理学-凝聚态物理] 08[工学] 0817[工学-化学工程与技术] 080501[工学-材料物理与化学] 070302[理学-分析化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 0702[理学-物理学] 

基　　金：financially supported by the National Natural Science Foundation of China(NSFC)(Nos.51671003,21802003,21571112) Natural Science Foundation of Shandong Province(ZR2018BB031) the Shandong Taishan Scholar Program(H.W.) the China Postdoctoral Science Foundation(No.2017M610022) the start-up supports from Peking University Young Thousand Talented Program 

主　　题：ZIF-67 Co3O4/NCNTs hybrids Enzyme-free sensor H2O2 Glucose 

摘      要：Developing enzyme-free sensors with high sensitivity and selectivity for H2O2 and glucose is highly desirable for biological ***,it is attractive to exploit noble-metal-free nanomaterials with large surface area and good conductivity as highly active and selective catalysts for molecular detection in enzyme-free ***,we successfully fabricate hollow frameworks of Co3O4/N-doped carbon nanotubes(Co3O4/NCNTs)hybrids by the pyrolysis of metal-organic frameworks followed by calcination in the *** as-prepared novel hollow Co3O4/NCNTs hybrids exhibit excellent electrochemical performance for H2O2 reduction in neutral solutions and glucose oxidation in alkaline *** sensor electrode,the Co3O4/NCNTs show excellent non-enzymatic sensing ability towards H2O2 response with a sensitivity of 87.40μA(mmol/L)^-1 cm^-2,a linear range of 5.00μmol/L-11.00 mmol/L,and a detection limitation of 1μmol/L in H2O2 detection,and a good glucose detection performance with 5μmol/*** excellent electrochemical performances endow the hollow Co3O4/NCNTs as promising alternative to enzymes in the biological applications.