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Iron-catalyzed benzylation of 1,3-dicarbonyl compounds by simple toluene derivatives

Iron-catalyzed benzylation of 1,3-dicarbonyl compounds by simple toluene derivatives

作     者:PAN ShiGuang LIU JinHua LI YuanMing LI ZhiPing 

作者机构:Department of ChemistryRenmin University of ChinaBeijing 100872China 

出 版 物:《Chinese Science Bulletin》 (中国科学通报)

年 卷 期:2012年第57卷第19期

页      面:2382-2386页

核心收录:

学科分类:081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基  金:supported by the National Natural Science Foundation of China (20832002 and 21072223) the Fundamental Research Funds for the Central Universities the Research Funds of Renmin University of China (10XNL017) 

主  题:二羰基化合物 苯衍生物 催化氧化 苄基  自由基 

摘      要:An iron-catalyzed oxidative C-C bond formation by the reactions of simple toluene derivatives with 1,3-dicarbonyl compounds is developed.A benzylic radical addition to a benzoylmethanato iron species is proposed for the transformation.

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