Iron-catalyzed benzylation of 1,3-dicarbonyl compounds by simple toluene derivatives
Iron-catalyzed benzylation of 1,3-dicarbonyl compounds by simple toluene derivatives作者机构:Department of ChemistryRenmin University of ChinaBeijing 100872China
出 版 物:《Chinese Science Bulletin》 (中国科学通报)
年 卷 期:2012年第57卷第19期
页 面:2382-2386页
核心收录:
学科分类:081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术]
基 金:supported by the National Natural Science Foundation of China (20832002 and 21072223) the Fundamental Research Funds for the Central Universities the Research Funds of Renmin University of China (10XNL017)
摘 要:An iron-catalyzed oxidative C-C bond formation by the reactions of simple toluene derivatives with 1,3-dicarbonyl compounds is developed.A benzylic radical addition to a benzoylmethanato iron species is proposed for the transformation.