Effects of Increasing Tungsten on Structural,Elastic and Optical Properties of xWO_3-(40-x)Ag_2O-60Te_2O Glass System

作     者：MM.Umair A.K.Yahya M.K.Halimah H.A.A.Sidek 

作者机构：School of Physics and Materials StudiesUniversiti Teknologi MARA Department of PhysicsFaculty of ScienceUniversiti Putra Malaysia 

出 版 物：《Journal of Materials Science & Technology》 (材料科学技术（英文版）)

年 卷 期：2015年第31卷第1期

页      面：83-90页

核心收录：

学科分类：08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 

基　　金：Financial support from Ministry of Education of Malaysia in the form of RACE under grant No. 600 e RMI/RACE/16/6/2 (1/ 2013) is gratefully acknowledged 

主　　题：Elastic moduli Optical absorption Raman spectrosco 

摘      要：Ternary teiiurite glasses with composition of xWO3（40-x）Ag2O-60TeO2（x=0-40 mol%） have been prepared by melt-quenching *** and optical properties of the glass system were obtained by ultrasonic velocity measurements and UV-vis spectroscopy,respectively,while structural investigation was carried out by using Raman *** longitudinal and shear velocities,vLand vsshowed large increase at x from 0 to 20 mol%before decrease with further addition of *** longitudinal modulus CLand shear modulus μ bulk modulus KeYoung’s modulus Vand Debye temperature θDshowed similar behaviors to both *** large increase of the elastic moduli at x from 0 to 20 mol%is suggested to be due to the increase in WO6octahedral unit structure indicating the increase of bridging oxygen（BO） and formation of stronger Te-O-W bonds compared to Te-O-Te *** the other hand,forx 20 mol%,the decrease in the elastic moduli was due to the increase of non-bridging oxygen（NBO） as a result of formation of WO4tetrahedral via breaking Te-O-W *** analysis by using bulk compression and ring deformation models showed a slight decrease in the ratio of ideal bulk modulus Kbcto the experimental bulk modulus Keand average atomic ring size,/ for× 20 mol%.Our analysis also indicates that limited ring deformation took place and the main compression mechanism in this glass system was mainly ideal isotropic *** the other hand,optical band gap Eoptshowed small variation for x=0-20 mol%but decreased upon higher WO3content while refractive index n showed the opposite *** optical behavior is suggested to be related to the changes in cross link density and NBO concentration in the glass system.