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Synthesis of the 3D porous carbon-manganese oxide (3D-C@MnO) nanocomposite and its supercapacitor behavior study

Synthesis of the 3D porous carbon-manganese oxide (3D-C@MnO) nanocomposite and its supercapacitor behavior study

作     者:Rakesh K.Sahoo Arya Das Saurabh Singh Damin Lee Saroj K.Singh Rajaram S.Mane Je Moon Yun Kwang Ho Kim 

作者机构:Global Frontier R&D Center for Hybrid Interface Materials Pusan National University School of Materials Science & Engineering Pusan National University CSIR-Institute of Minerals and Materials Technology 

出 版 物:《Progress in Natural Science:Materials International》 (自然科学进展·国际材料(英文))

年 卷 期:2019年第29卷第4期

页      面:410-415页

核心收录:

学科分类:080801[工学-电机与电器] 0808[工学-电气工程] 08[工学] 0805[工学-材料科学与工程(可授工学、理学学位)] 080502[工学-材料学] 0702[理学-物理学] 

基  金:Council of Scientific and Industrial Research,New Delhi and CSIR-Institute of Minerals and Materials Technology, Bhubaneswar the Global Frontier Program through the Global Frontier Hybrid Interface Materials (GFHIM) of the National Research Foundation of Korea funded by the Ministry of Science, ICT and Future Planning (2013 M3A6B1078874) National Children’s Research Centre (NCRC) grant 2015M3A6B1065262 

主  题:Nanocomposites 3D-carbon Manganese monoxide Cathode material Supercapacitor 

摘      要:A 3D porous carbon-manganese oxide(3D-C@MnO) nanocomposite is successfully synthesized via a thermal plasma deposition *** chemical bonds and compositions,phase structures,surface morphologies,*** as-obtained 3D-C@MnO nanocomposite were characterized by the various equipment,such as X-ray diffractometer,X-ray photoelectron spectroscopy,and electron *** electrochemical performances of the 3D-C@MnO nanocomposite electrode showed a specific capacitance of 780 Fg;at a current density of 2Ag;and a capacitance retention rate of 99% after 5000 charge-discharge cycles at a high current density of 10Ag;.These excellent capacitive performances may be attributed to the encapsulation of MnO nanoparticles by porous carbon sheets in the 3D-C@MnO nanocomposite *** is believed that the carbon-encapsulated MnO nanoparticles can be protected from a volume deformation during the charge adsorption/desorption cycle and can be electrically improved by the encapsulated carbon sheets,resulting in better overall capacitive *** addition,this study also demonstrates the practical applicability by assembling a supercapacitor using the as-obtained 3D-C@MnO nanocomposite to glow a light emitting diode.

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