Electrochemical Studies of Eight New Divalent Transition Metal Benzenesulphonate Ternary Complexes with 1,10-Phenanthroline

作     者：LUYao GUOLi-ping MAJian-fang YANGJin WUDong-mei 

作者机构：FacultyofChemistryNortheastNormalUniversityChangchun130024China CollegeofChemistry＆PharmocologyJiamusiUniversityJiamusi154002China 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)

年 卷 期：2004年第20卷第6期

页      面：694-697页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学] 

主　　题：Benzenesulphonate 1,10-Phenanthroline Transition metal complex Cyclic voltammetry 

摘      要：The electrochemical properties of eight new divalent transition metal benzenesulphonate complexes with 1,10-phenanthroline in different solvents and supporting electrolytes were investigated by means of cyclic voltammetry(CV). Based on the CV data the influences of various coordination modes on the electrochemical behavior of the complexes were discussed. The diffusion coefficient D c and rate constant k s of those complexes in DMF systems were estimated according to CV and the results show that these processes were all quasi-reversible.