Thermoregulated Organic Biphasic Hydrogenation of 1-Octene Catalyzed by Ru/PETPP Complex

作     者：Ya Dong LU Yan Hua WANG Zi Lin JIN 

作者机构：State Key Laboratory of Fine Chemicals Dalian University of Technology Dalian 116012 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2006年第17卷第2期

页      面：255-257页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：the financial support from the National Natural Science Foundation of China (Grant no. 20376013) the Fok Ying Tung Education Foundation (Grant no. 91071) the Doctorate Program Foundation of Higher Education (Grant no. 20020141004) 

主　　题：Thermoregulated organic biphasic system hydrogenation 1-octene ruthenium. 

摘      要：Thermoregulated organic biphasic system composed of triethylene glycol monomethyl ether （TGME） and n-heptane was first applied to the hydrogenation of 1-octene. Under the optimal conditions： P（H2）=5.0MPa, T=80℃, t=3h, 1-octene/Ru=1000 （molar ratio）, the yield of n-octane reached up to 99.6%. Furthermore, the simply decanted catalyst could be reused for 10 times without apparent loss of catalytic activity.